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Online since: December 2014
Authors: Pei Song Tang, Chao Wan Tang, Zhe Hao Wang, Jia Ni Ying, Qian Yang
One-step Preparation of Nanoparticulate TbFeO3 by Microwave Process and Its Visible-light Photocatalytic Activity Peisong Tanga, Zhehao Wangb, Jiani Yingc, Chaowan Tangd, Qian Yange Department of Material Chemistry, Huzhou University, Huzhou 313000, P.
The single phase structure of TbFeO3 was yet maintained after calcination at 800 ℃.
The TbFeO3 was a kind of typical rare earth perovskite type oxides, with its unique electronic properties and structure [7-8].
The all diffraction peaks of as-prepared TbFeO3 and TbFeO3 products after calcination at 300℃, 400℃, 600℃and 800℃ match well with the standard sample of perovskite structure TbFeO3 (JCPDS: 47-0068), without other impurity phase peaks, which indicates the successful synthesis of single phase perovskite TbFeO3 by a one-step microwave process.
The single phase structure and optical properties of TbFeO3 nanoparticles were not significant change after calcination at 800 ℃.
Online since: February 2024
Authors: Zi Yu He
Multiple pseudocapacitive effects along with the large surface area originating from the 2D structure of Ti3C2 may contribute to higher specific capacitance and increase the energy density of the device.
A Reflection on Lithium-ion Battery Cathode Chemistry.
The Journal of Physical Chemistry C 111, 40: 14925–14931. https://doi.org/10.1021/jp074464w [39] Martin Winter and Ralph J.
Effect of Treated Temperature on Structure and Performance of LiCoO2 Coated by Li4Ti5O12.
Journal of Energy Chemistry 59: 276–291. https://doi.org/10.1016/j.jechem.2020.11.013 [45] Wenhua Zuo, Ruizhi Li, Cheng Zhou, Yuanyuan Li, Jianlong Xia, and Jinping Liu. 2017.
Online since: September 2007
Authors: Mu Sen Li, Jian Hong Gong, Bin Xu, Li Li
Based on known crystal structure, the valence electron structure (VES) of solids and molecules can be calculated according to the empirical electron theory of solids and molecules (EET) which suggests that all covalent electrons in a structure unit should be distributed on its all covalent bonds, and the number of covalent electrons on some crystal plane should be equal to all covalent electrons of covalent bonds on this plane.
The smaller ∆ρmin and the larger σ, the lower energy structure transformation needs.
In addition to Co3C, (FeNi)3C is the optimal carbon source to form diamond structure.
Turkevich:Journal of Physical Chemistry.Vol.106 (2002), p. 6634 [2] E.
Valence Electron Structure of Interfaces and their Properties.
Online since: October 2006
Authors: Wolfgang J. Choyke, Robert P. Devaty, R.M. Feenstra, Yue Ke, S. Gaan, Catherine Moisson
Plan and cross sectional SEM images revealing the early stages of pore formation are obtained to evaluate the porous structure.
The M44 CMP sample also has a nano-columnar structure, but only 13 microns thick.
However, the cross sectional images (Fig. 4(c) and (d)) reveal the differences in the porous structures.
The M1 CMP sample has an approximately seven micron thick nano-columnar porous structure.
To understand the difference between Si-face and C-face porous SiC, we need to consider the different etching rates and chemistry on these two faces.
Online since: January 2011
Authors: V. Swaminathan, M. Jayachandran, L.C. Nehru, C. Sanjeeviraja
According to the concept used in propellant chemistry [121], reducing elements with the valencies of Sn =+2 and H=+1 respectively.
P Gast, In Physical Chemistry of Surfaces 6th ed., Wiley Interscience, New York, 257 (1997)
Li, and D Que, Materials Chemistry and Physics, 93 (2005) 65
Chemistry of nanocrystalline oxide materials: combustion synthesis, properties and applications.
C., Journal of Solid State Chemistry 21 (1977) 253
Online since: April 2015
Authors: Lenka Bodnárová, Ámos Dufka
The resistance of the performed rehabilitation and the durability of the rehabilitated structure can be in principle determined by two approaches.
Methodic of repair materials development The basic demands on materials determined for rehabilitation of reinforced concrete structures define especially the regulations of the Standard ČSN EN 1504-3, and further the: “Technical Conditions for Rehabilitation of Reinforced Concrete structures” TP SSBK III.
The material must fulfill these parameters, if it is intended for rehabilitation of real reinforced concrete structures.
The use of Geopolymers in Rehabilitation of Reinforced Concrete structures.
Industrial and Engineering Chemistry Research 38. 1999. pp. 3932 – 3941.
Online since: December 2013
Authors: Xia Li, Jie Dai, Kai Li Liu
The effect of the thermal treatment on the structure of the LaPO4 nanorods was also investigated.
The morphology and the crystal structure of the samples were observed using a field emission scanning electron microscope (FE-SEM, JSM-6700F) and powder X-ray diffraction (XRD, Cu Kα=1.5406Å).
As can be seen from Fig. 1 (b-d), the characteristic peaks of the monoclinic structure gradually enhanced as temperature increases.
Moreover the characteristic peaks of the monoclinic structure gradually enhanced by increasing thermal treatment temperature.
Gan: Materials Chemistry and Physics, Vol. 133 (2012),p.263.
Online since: April 2014
Authors: Bin Sun, Xiu Ling Xu, Guo Wei Zhou
Cetyltrimethylammonium Bromide-Assisted Hydrothermal Synthesis of Mixed-Phase TiO2 Nanorod and Its Photocatalytic Activity Bin Sun1,a, Xiuling Xu1,2,b and Guowei Zhou*1,c 1Key Laboratory of Fine Chemicals in Universities of Shandong, School of Chemistry and Pharmaceutical Engineering, Qilu University of Technology, Jinan 250353, China 2School of Chemical Engineering and Environment, Weifang University of Science and Technology, Weifang 262700, China asunbin200703@126.com, bxuxiuling813@sina.com, cguoweizhou@hotmail.com Keywords: Cetyltrimethylammonium bromide, TiO2 nanorods, Rutile, Brookite, Photocatalytic degradation, Wastewater Abstract.
TiO2 nanorods were successfully fabricated via hydrothermal method using cetyltrimethylammonium bromide (CTAB) as the structure-directing agent.
In this study, we have successfully prepared TiO2 nanorods using tetrabutyl titanate (TBT) with cetyltrimethylammonium bromide (CTAB) as the structure-directing agent.
The crystal structures of the TiO2 powders were characterized by X-ray diffraction (XRD, Bruker Company) with Cu Ka radiation (40 kV, 40 mA, l = 0.15406 nm).
It is generally accepted that the photoactivity of TiO2 depends on quite a number of parameters, including the crystal structure, special surface area, and average crystallite size, etc.
Online since: December 2014
Authors: Wan Qiu Zhou, Xin Li, Jian Wang, Yan Hong Kang, Shi Gang Xin, Ting Ting Huang
Corrosion Behavior of Conducting Polymer PANI in Simulating PEMFC Conditions ZHOU Wan Qiua, LI Xinb, HUANG Ting Tingc, WANG Jiand, XIN Shi Gange and KANG Yan Hongf College of Chemistry and Life Science, Shenyang Normal University, Shenyang 110034, China aemail: wqzhou@imr.ac.cn, bemail:xli@163.com, cemail: tthuang @163.com, demail:jwang@163.com, eemail:sgxin@163.com, femail:yhkang@163.com Keywords: PEMFC, stainless steel bipolar plates, PANI, corrosion behavior Abstract.
Structure and morphology of PANI polymer coating were characterized by means of fourier transform infrared reflection(FTIR) spectrum and scanning electron microscopy(SEM).
The surface morphology of PANI polymer coating was observed by scanning electron microscopy(SEM), and the chemical structure of the coating was investigated by FTIR.
Chemical structure analysis.
Chemical structure was tested by fourier transform infrared reflection(FTIR) spectroscopy.
Online since: February 2013
Authors: Li Qin Wang, Yang Han, Xiu Jun Fu, Hai Tao Wu, E Chang, Hai Ying Wang, Quan Huo, Rui Jun Zhang
Synthesis and Characterization of MCM-41 Molecular Sieves Nanoparticals Liqin Wang1,2,a, Yang Han1, Xiujun Fu1, Haitao Wu1, E Chang1,Haiying Wang1, Quan Huo1, Ruijun Zhang2 1Hebei Key Laboratory of Applied Chemistry, College of Environmental and Chemical Engineering, Yanshan University, Qinhuangdao, Hebei, 066004, China 2State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao, Hebei, 066004, China awangliqin@ysu.edu.cn Keywords: MCM-41 molecular sieves, Nanoparticals, Synthesis, Characterization Abstract.
The adsorption-desorption isotherms were corresponded to typical type IV isotherms with the hysteresis loop of type H2, which showed the samples had mesoporous structure.
The crystal structure of samples was determined by X-ray powder diffract meter (XRD) of D/MAX-rB, which was radiated by Cu Kα, pipe pressure was 40 mV, and wavelength (l) was 1.54056 Å.
Furthermore, the samples had typical hexagonal mesoporous structure[5].
The samples had high crystsllinity and typical hexagonal mesoporous structure.