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Online since: April 2016
Authors: Xia Wu, Fei Peng Jiao, Xia Hui Peng, Lin Qi Liu, Chen Xi Zhao, Xiao Mei Wang, Jin Yu Liu
The excellent anion-exchange materials and their extensive intercalation chemistry have widespread applications in many fields, functioning as UV adsorbents [11], optical materials [12, 13], chemical sensors [14-16], drug or DNA transporters [17-21], etc.
The intercalated materials were characterized by different physico-chemistry techniques.
Table 1 The lattice parameters of samples a =2d (110)[nm] c =3d (003)[nm] MgAl–NO3–LDHs 0.31 2.75 ZnAl–NO3–LDHs 0.30 2.73 Calcein-Mg/Al-LDHs 0.31 5.43 Calcein-Zn/Al-LDHs 0.31 5.25 Supramolecular structure model of DTTA-LDHs.
Fig. 2 Assembly process of Calcein/LDHs: (a) the chemical formula of calcein, (b) the representation for the layer of LDHs, (c) structure model of the calcein-LDHs nanolaminates.
So, the organic anions in the interlayer still maintained their original structures and UV absorption ability and the calcein-Zn/Al-LDHs still can be a very good UV absorbent.
The intercalated materials were characterized by different physico-chemistry techniques.
Table 1 The lattice parameters of samples a =2d (110)[nm] c =3d (003)[nm] MgAl–NO3–LDHs 0.31 2.75 ZnAl–NO3–LDHs 0.30 2.73 Calcein-Mg/Al-LDHs 0.31 5.43 Calcein-Zn/Al-LDHs 0.31 5.25 Supramolecular structure model of DTTA-LDHs.
Fig. 2 Assembly process of Calcein/LDHs: (a) the chemical formula of calcein, (b) the representation for the layer of LDHs, (c) structure model of the calcein-LDHs nanolaminates.
So, the organic anions in the interlayer still maintained their original structures and UV absorption ability and the calcein-Zn/Al-LDHs still can be a very good UV absorbent.
Online since: July 2013
Authors: R. Tewari, Nidhi Gupta, D. Mitra, J.K. Sainis, San Ju Francis, J. Nuwad, Alka Gupta, Lalit Varshney
The spectrum obtained for nanoparticle synthesized at R= 1:3 was akin to the spectrum obtained at R=1:4.
3.3 XRD analysis of the nanoparticles
The crystal structure of the nanoparticles was determined by powder XRD (Fig. 3) which gives information about the overall quality and purity of the sample.
The bright hexagonal pattern of spots obtained confirms that the gold nanoplates are single crystals with fcc structure and is bound by {111} lattice planes on the top and bottom [22].
Belloni, Nucleation, growth and properties of nanoclusters studied by radiation chemistry - Application to catalysis.
Tian, Synthesis of high electrocatalytic performance of hexagram shaped gold particles having an open surface structure with kinks, Nano Res. 4 (2011) 612-622
Swallow, Radiation chemistry: An introduction, Wiley, New York. 1973
The bright hexagonal pattern of spots obtained confirms that the gold nanoplates are single crystals with fcc structure and is bound by {111} lattice planes on the top and bottom [22].
Belloni, Nucleation, growth and properties of nanoclusters studied by radiation chemistry - Application to catalysis.
Tian, Synthesis of high electrocatalytic performance of hexagram shaped gold particles having an open surface structure with kinks, Nano Res. 4 (2011) 612-622
Swallow, Radiation chemistry: An introduction, Wiley, New York. 1973
Online since: November 2016
Authors: Sigurd Schrader, Mauro Casalboni, Fabio de Matteis, Paolo Prosposito, Matteo Ciocci, Paolo di Nardo, Slava Ksenzov, Federico Mochi, Sonia Melino, Roberto Francini
We use an innovative composite material consisting of hydrogel with different molecular weight and with suitable accordion-like and woodpile structures in order to tailor stiffness and elasticity conferred to the final structure.
Tissue engineering approach consists in a combination of techniques, developed in the recent past in different scientific fields (medicine, biology, chemistry, physics and engineering) aimed to produce, starting from stem cells, portion of tissue, endowed with specific functionalities, able to restore, maintain, or improve damaged tissues or even whole organs.
We fabricated 3D structures exploiting a commercial overhead projector.
A 2PP 3D accordion-like structure is shown in Fig. 1b.
Figure 1: Optical images of a PEGda based structure synthesized by (a) 1PP process and (b) 2PP process.
Tissue engineering approach consists in a combination of techniques, developed in the recent past in different scientific fields (medicine, biology, chemistry, physics and engineering) aimed to produce, starting from stem cells, portion of tissue, endowed with specific functionalities, able to restore, maintain, or improve damaged tissues or even whole organs.
We fabricated 3D structures exploiting a commercial overhead projector.
A 2PP 3D accordion-like structure is shown in Fig. 1b.
Figure 1: Optical images of a PEGda based structure synthesized by (a) 1PP process and (b) 2PP process.
Online since: November 2013
Authors: Ahdie Pourfereidouni, Gholam Hossein Akbari
They observed a disorder FCC structure with nano-crystalline grain sizes around 4.7 nm.
The cold worked structures in powder particles comprise of dislocation structure, sub-boundaries and even new developed boundaries due to sub-boundary rotations during milling.
Soffa, The structure and properties of age hardened Cu-Ti alloys, J.
Materials Chemistry 9 (1) (1999) 305-314
Pearson, A Handbook of Lattice Spacing and Structures of Metals and Alloys, Pergamon Press, London, vol 4 (1958) pp 602
The cold worked structures in powder particles comprise of dislocation structure, sub-boundaries and even new developed boundaries due to sub-boundary rotations during milling.
Soffa, The structure and properties of age hardened Cu-Ti alloys, J.
Materials Chemistry 9 (1) (1999) 305-314
Pearson, A Handbook of Lattice Spacing and Structures of Metals and Alloys, Pergamon Press, London, vol 4 (1958) pp 602
Online since: May 2020
Authors: D.E. Zhivulin, Vladimir E. Zhivulin, O.V. Zaitseva
Soon there appeared works devoted to the study of high-entropic oxide systems with a more complex crystal structure.
The authors of [16-19] presented the results of the high-entropy phases creation with a perovskite structure.
A multicomponent (high-entropy) oxide phase with a spinel structure was obtained in [20].
It was assumed that the formation of phases with the structure of M-type hexaferrites is most likely for these systems.
Dragoe, Room temperature lithium superionic conductivity in high entropy oxides, Journal of Materials Chemistry A, 4 (2016) 9536-9541
The authors of [16-19] presented the results of the high-entropy phases creation with a perovskite structure.
A multicomponent (high-entropy) oxide phase with a spinel structure was obtained in [20].
It was assumed that the formation of phases with the structure of M-type hexaferrites is most likely for these systems.
Dragoe, Room temperature lithium superionic conductivity in high entropy oxides, Journal of Materials Chemistry A, 4 (2016) 9536-9541
Online since: May 2020
Authors: Alexander V. Mosunov, G.M. Kaleva, Sergei Yu. Stefanovich, Dmitry A. Kiselev, T.S. Ilina, E.D. Politova, N.V. Sadovskaya
Stefanovich1,4
1L.Ya.Karpov Institute of Physical Chemistry; Vorontsovo pole, 10, Moscow 105064 Russia,
2National University of Science and Technology “MISiS”, Leninskii pr. 4, Moscow, 119049 Russia,
3Fryazino branch of the Kotel’nikov Institute of Radioengineering and Electronics of Russian Academy of Sciences, Vvedensky Square 1, Fryazino, Moscow region, 141190 Russia,
4Lomonosov Moscow State University, Leninskie gory 1, Moscow 119992 Russia,
E-mail: politova@nifhi.ru
Keywords: sodium-potassium niobate, perovskite structure, microstructure, properties
Abstract.
Results and Discussion Pure samples with perovskite structure were prepared (Figure 1).
Initial KNN samples have typical orthorhombic structure.
To study the effect of the electric field on domain structure, a two square areas of 15 µm × 15 µm and 7.5 µm × 7.5 µm (structure “box-in-box”) was scanned under a DC voltage of – 30 V and +30 V applying to the cantilever, respectively (Figure 7, middle row).
Structure and electrical properties of K0.5Na0.5NbO3 –LiSbO3 lead-free piezoelectric ceramics.
Results and Discussion Pure samples with perovskite structure were prepared (Figure 1).
Initial KNN samples have typical orthorhombic structure.
To study the effect of the electric field on domain structure, a two square areas of 15 µm × 15 µm and 7.5 µm × 7.5 µm (structure “box-in-box”) was scanned under a DC voltage of – 30 V and +30 V applying to the cantilever, respectively (Figure 7, middle row).
Structure and electrical properties of K0.5Na0.5NbO3 –LiSbO3 lead-free piezoelectric ceramics.
Online since: August 2021
Authors: Vladimir I. Kuz'min, Evgeniy V. Kuz’min, Vladimir I. Lysak
Gurulev, Effect of plastic deformation on the structure and properties of laminated composite materials, Welding International. 16 (2002) 890-893
Chugunov, Special features of plastic deformation of the metal of the weld zone in explosive welding aluminium to copper, Physics and Chemistry of Materials Treatment. 37(2003) 73-78
Kuz'min, A study of the influence of thickness of anti-diffusion layer on the structure and thermal resistance of composite A5-Cr-St3, Solid State Phenomena. 299 (2020) 137-142
Kuz'min, A study of the structure and reqularities of formation of the compounds during explosive welding of steel-aluminum composite, Solid State Phenomena. 284 (2018) 212-217
Arisova, Structure and properties of explosion welded composites from steels of different kinds, Metal Science and Heat Treatment. 46 (2004) 167-169
Chugunov, Special features of plastic deformation of the metal of the weld zone in explosive welding aluminium to copper, Physics and Chemistry of Materials Treatment. 37(2003) 73-78
Kuz'min, A study of the influence of thickness of anti-diffusion layer on the structure and thermal resistance of composite A5-Cr-St3, Solid State Phenomena. 299 (2020) 137-142
Kuz'min, A study of the structure and reqularities of formation of the compounds during explosive welding of steel-aluminum composite, Solid State Phenomena. 284 (2018) 212-217
Arisova, Structure and properties of explosion welded composites from steels of different kinds, Metal Science and Heat Treatment. 46 (2004) 167-169
Online since: October 2011
Authors: Jun Hong Liu, Ming Dou, Li Xiao Zhou, Kang Xie
Study on Optimized Conditions of Cellulose Degradation of Bermuda grass
Junhong Liu 1,a, Ming Dou 2,Lixiao Zhou 1, Kang Xie 1
1Bio-engineering Department of Henan University of Urban Construction, Pingdingshan, Henan
467044, China
2Faculty of Chemical and material engineering of Hebi Vocational and Technical College,Hebi,
Henan 458030, China
aemail:ljhwtl@126.com
Key words:Bermuda grass, cellulose, degradation, pretreatment
Abstract: Biomass plays unprecedented role in energy structure, whose study focuses on technology reform, the study on exploring raw material is limited.
Chemistry and bioengineering Vol. 5 ( 2003) ,p.8-9
Chemistry and bioengineering Vol. 5 ( 2003) ,p.8-9
Online since: May 2006
Authors: Luiz Pereira, Lilian Marques Silva, Joana Catarina Madaleno, Roberto R. Lima, Maria Lucia Pereira Silva, Alexsander T. Carvalho
On MS system is possible to evaluate the main molecules leaving the structure.
Therefore, for comparison, used and not used structures were analyzed.
In order to verify the reproducibility of these structures several pulses were inserted.
For some structures pulses of 2-propanol were alternated with n-hexane.
Zellers, Analytical Chemistry, vol. 73, no. 14 (2001) p. 3449 [4] C.
Therefore, for comparison, used and not used structures were analyzed.
In order to verify the reproducibility of these structures several pulses were inserted.
For some structures pulses of 2-propanol were alternated with n-hexane.
Zellers, Analytical Chemistry, vol. 73, no. 14 (2001) p. 3449 [4] C.
Online since: July 2011
Authors: Guo Cai Tian, Zhi Liang Jiao, Ya Dong Li
Thus understanding the structure, interactions and dynamics properties of water or other small impure molecules in ionic liquids can help us control or remove these impure species.
Many simulation works have performed on the interface and their phase-separation of [Bmim]PF/water, [Omim]PF/water and [Bmim]NTf /water mixture [19,20], and the shear viscosity of [Emim]NTf/water mixture [21], as well as the structure and hydrogen bond of [Dmim]BF/water [22] [Dmim]Cl/water [23], and [Bmim]BF/water [24,25], on the structure and thermodynamics of [Bmim]BF/water mixture [26].
The structure of [Emim]BF4 and water molecule in simulations are shown in Fig.1.
The radial distribution functions g are a classic tool to characterize the structure of the liquids and their mixture, through the effective pairwise interaction between atoms A and B.
The structure, IR spectrum of water molecule in [Emim]BF4/water mixture at room temperatures were studied with computer simulation.
Many simulation works have performed on the interface and their phase-separation of [Bmim]PF/water, [Omim]PF/water and [Bmim]NTf /water mixture [19,20], and the shear viscosity of [Emim]NTf/water mixture [21], as well as the structure and hydrogen bond of [Dmim]BF/water [22] [Dmim]Cl/water [23], and [Bmim]BF/water [24,25], on the structure and thermodynamics of [Bmim]BF/water mixture [26].
The structure of [Emim]BF4 and water molecule in simulations are shown in Fig.1.
The radial distribution functions g are a classic tool to characterize the structure of the liquids and their mixture, through the effective pairwise interaction between atoms A and B.
The structure, IR spectrum of water molecule in [Emim]BF4/water mixture at room temperatures were studied with computer simulation.