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Online since: January 2012
Authors: Heng Li
Study of an Inorganic Ion Exchanger Mg2Ti1.25(PO4)3 Jinhe Jiang MicroScale Science Institute , Department of Chemistry and Chemical Engineering ,Weifang University, Weifang, 261061,China jiangjinhe2012@126.com Keywords: Mg2Ti1.25(PO4)3, Ion exchanger, Exchange capacity Abstract.
In this paper, the discussion is about the synthesis, structure and ion exchange of the Li-Ti composite oxide inorganic ion exchanger of Mg2Ti1.25(PO4)3.
The structure of compound metal oxide Mg2Ti1.25(PO4)3 crystallized at 750℃ was much perfect.
Distribution coefficient of MgTi-750(H)for alkali ions References [1] Z.S.Peng, Y.S.Yan, C.Y.Jiang, C.R.Wan, H.C.Gao: Advance on extraction lithium from salt lake, J.Chemistry Online. 1997, (12), 11 [2] Y.F.Liu, Q.Feng, Kenta Ool: Li extraction/insertion reaction with LiAlMnO4 and LiFeMnO4 spinels in the aqueous phase, J.Journal of Colloid and Interface Science . 1994, 163(1), 130 [3] D.Q.Dong, J.Zhong, D.L.Liu, Y.F.Liu: LiCu0.5Mn1.5O4 synthesis and Li+ extraction/reaction with it in the aqueous phase, J.China Journal of Applied Chemistry . 1998, 15(3), 11 [4] D.Q.Dong, F.B.Zhang, G.L.Zhang, Y.F.Liu: LiMg0.5Mn1.5O4 synthesis and its selectivity to Li+ exchange, J.Chinese Journal of Inorganic Chemistry. 2004, 9(9), 20
Online since: May 2019
Authors: Zhe Chen, Jing Zou, Yong Sheng Chen, Quan Fang Chen, Sha Ne Zhang, Guo Dong Xu, Mao You Lin, Miao Miao Wang, Shen Zhi, Shi Wen Xing
Results and Discussions Fig.1 shows the XRD pattern of the LiNi0.5Mn1.5O4 samples prepared by the novel wet chemistry synthesis process.
The results indicate that the cathode materials prepared through the wet chemistry synthesis method are pure phase samples.
The electrochemical properties of the prepared nano-structured samples were discussed in the following.
Chemistry of Materials. 2011, 23(11):2832-2841
Journal of Electroanalytical Chemistry, 2014, (727):8-12
Online since: June 2012
Authors: Fu Shi Zhang, Jun Hui Xiang, Li Xing, Xiao Hong Liang, Li Jie Cui, Bo Song, Hua Zheng Sai, Zhen You Li, Chun Lin Zhao
The effect of surfactent on the structure of the resulting aerogels was investigated.
The porous structure of aerogels was investigated by Brunauer-Emmett- Teller (BET) instrument and scanning electron micrograph (SEM).
In general, supercritically dring is necessary for silica aerogels to keep the highly porous structure from collapse.
Schubert, Aerogels—Airy Materials: Chemistry, Structure, and Properties, Angew.
Pajonk, Chemistry of Aerogels and Their Applications, Chem.
Online since: December 2012
Authors: Qing Hua Chen, Xin Ping Liu, Bao Quan Huang, Qing Rong Qian, Jing Xu
The difference in crystal structure of samples prepared from different fuels were identified by XRD.
The main peaks of C and D could be readily indexed to the cubic structure CaO (JCPDS 17-0912) .
,EPR study of the surface basicity of calcium oxide. 1. the CaO-NO chemistry, J.
Klabunde, Jane Stark, Olga Koper,et al., Nanocrystals as Stoichiometric Reagents with Unique Surface Chemistry, J.
Nitrate-citrate combustion synthesis and properties of Ce1-xCaxO2-x solid solutions, Materials Chemistry and Physics,2003,82:509-514
Online since: October 2014
Authors: Fu Sheng Zhang, Feng Wang, Xin Fang Feng, Chun Bao Ma, De Wei Wang, Jian Ouyang
Composition, structure and aggregation of resin and asphaltene With a variety of analytical methods, thorough studies on chemical structure and composition of resin and asphaltene have been conducted[3].
Since the basic structure of asphaltene is a plane structure with fused aromatic ring as its core, the force among the molecule structure of aromatic plane is large and hydrogen-bond groups are easily formed around the core.
It is believed that the above object can be achieved by improving the aromaticity of the demulsifier molecular structure.
Oilfield Chemistry, 15(1):87-96
Oilfield Chemistry, 11(3):266-272
Online since: May 2015
Authors: Mohamad Firdaus Abdul Wahid, N.R. Nik Roselina, C.M. Mardziah, Koay Mei Hyie
After the powders had undergone a calcination process, the samples tend to change from a partially amorphous structure to a more crystalline structure.
This shows that the samples have amorphous structure [5] which is consistent with XRD results.
These bands appeared in all samples and could be related to another phase in the apatite structure.
Girija, "Synthesis, characterization and in vitro studies of zinc and carbonate co-substituted nano-hydroxyapatite for biomedical applications," Materials Chemistry and Physics, vol. 134, pp. 1127-1135, 2012
Rey, "Adaptative physico-chemistry of bio-related calcium phosphates," Journal of Materials Chemistry, vol. 14, pp. 2148-2153, 2004.
Online since: February 2014
Authors: Xin Xing Zhou, Guo Fei Zhang, Rong Mao Liu, Liang Zheng
However, Pan and co-workers[6] used quantum-chemistry to study asphalt oxidative aging.
Asphalt molecular structure would change greatly before and after aging.
Lloyd, Quantum-chemistry study of asphalt oxidative aging: an XPS-aided analysis, Ind.
Mullins, Molecular size and structure of asphaltenes from various sources, Energy & Fuels. 14 (2000) 677-684
Zhang, Effect of ultraviolet aging on rheology, chemistry and morphology of ultraviolet absorber modified bitumen, Materials and Structures. 46 (2013) 1123-1132.
Online since: March 2013
Authors: Qian Qian You, Pu Yu Zhang
Synthesis of copper complexes of poly [2-(dimethylamino ethyl methacrylate)-b-poly (oligo (ethylene glycol) monomethylether methacrylate-b-poly [2-(dimethylamino ethyl methacrylate) Qianqian You a,Puyu Zhangb Institute of Fine Chemistry and Engineering, College of Chemistry and Chemical Engineering, Henan University, China P.R., 475004 ayouqian710@yahoo.com.cn, bzhangpuyu@henu.edu.cn Keywords: double hydrophilic; copolymer; complex.
The chain structure and component of such copolymers were characterized by spectroscopic studies (FTIR, 1H NMR).
These variations in the band might be due to the different structures between Cu(II)/polymer/SO4 complex and Cu(II)/polymer/SO4 complex.
These micelles had clear tubular structure in figure 3 (a) and (c).
Cu(II)/polymer/SO4 and Cu(II)/polymer/Cl2 had different crystal structure.
Online since: January 2013
Authors: Yan Zhen Yin, Jia Ming Li, Zhong Feng Shi, Li Zhang, Ni Huang, Rui Yun Feng
Synthesis and Surface Photoelectric Properties of a Trinuclear Chromium(III) Complex Zhongfeng Shi1, a, Jiaming Li1,b *, Yanzhen Yin1,c Li Zhang1, Ni Huang1 and Ruiyun Feng1 1 College of Chemistry and Chemical Engineering, Qinzhou University, Qinzhou, Guangxi, 535000,China ashizhongfeng01@163.com, b ljmmarise@163.com, c yinyanzhen2009@163.com Keywords: Trinuclear Chromium complex, Synthesis, Structure, Surface Photoelectric Property Abstract.
The crystal structure was determined by a Bruker CCD area detector.
The structures were refined by the full matrix least-squares method on F2.
Results and discussion Description of the Structure of Complex The X-ray single-crystal diffraction result indicates that the complex possesses an molecular structure (Fig. 1).
Inorganic Chemistry, Vol. 46, (2007), P. 11017 [19] G.M.
Online since: October 2011
Authors: Shao Jian He, Yi Qing Wang, Jun Lin, Li Qun Zhang
Further addition of sulfur would result in the formation of cyclic sulfide through recombination of polysulfide, increasing the structure rigidity.
The last is zone 3, through which the modulus keeps fairly constant, demonstrating a fully developed crosslinked structure.
Due to the formation of cyclic sulfide at higher sulfur loading, the polymer structure rigidity increases.
Numaziri: Rubber Chemistry and Technology, 926-930(1940)
Numaziri: Rubber Chemistry and Technology, 598-603(1940).