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Online since: June 2004
Authors: Kenneth A. Jones, T.S. Zheleva, Matthew H. Ervin, R.D. Vispute, G.J. Gerardi, Pankaj B. Shah, Michael A. Derenge, Jaime A. Freitas
Army Research Lab - SEDD, 2800 Powder Mill Road, Adelphi, MD 20783 USA 2 William Paterson University, Chemistry & Physics Dept., Wayne, NJ 07470 3 Naval Research Lab, Code 6877, 4555 Overlook Ave., Washington, DC 20375 4 Physics Dept., University of Maryland, College Park, MD 20742 USA Keywords: Silicon Carbide, Implantation, Aluminum, Silicon, Defects Abstract.
Introduction SiC device structures usually require at least one implant step because the rate of diffusion for doping them is too slow even at temperatures as high as 1800°C.
Just as the electrical properties do not asymptotically approach the as-grown condition, the physical structure also does not as there appears to be a nucleation and growth of some structural defects.
This can account for the lower mobilities in the implanted and annealed structures and can possibly account for the low activation as defect states associated with the residual damage, such as the DI defect, trap out some of the carriers.
Online since: May 2005
Authors: Mietek Bakowski, Mikko Ritala, Markku Leskelä, Anders Hallén, Adolf Schöner, Viljami Pore, Maciej Wolborski
Box Electrum 229, SE-164 40 Kista, Sweden 2 ACREO AB, Electrum 236 SE-164 40 Kista, Sweden 3 Department of Chemistry, P.O.
After the deposition MIS structures were prepared with nickel as a top electrode on both Si and SiC substrates.
Table 2 Roughness before/ after annealing [nm] Breakdown electric field for negative/positive top metalization bias [MV/cm] Al2O3 on Si 0.5/0.8 8.4 / 7.3 Al2O3 on SiC 0.6/0.5 7.5 / inversion was not created TiO2 on Si 5.3/4.5 0.25 / 0.25 TiO2 on SiC 4.1-4.5/5.9 0.25 / 0.25 Ti oxide Al oxide SiC Si Fig.1 Breakdown measurements of the MIS structures for both dielectrics on Si and SiC, current density scale is the same for both pictures and the electric field scale for silicon is from -10 MV/cm to 10 MV/cm RBS analysis was performed on both Si and SiC substrates and the stochiometry of Al2O3 (2:3) and TiO2 (1:2) films was confirmed (see Fig. 2).
Fig. 3: CV characteristics of MIS structures with Al2O3 on Si (Fig. 3a) and SiC (Fig. 3b) as a function of frequency. 0 20 40 60 80 100 120 -5 0 5 10 15 20 25 30 35 40 Voltage [V] Capacitance [pF] 1MHz 100kHz 1kHz 100Hz 20Hz 0 20 40 60 80 100 120 -6 -4 -2 0 2 4 6 8 10 Voltage [V] Capacitance [pF] 1MHz 100kHz 10kHz 1kHz Si p-type SiC n-type Conclusions A factor of two reduction of the leakage current (measured at 500 V) was obtained for Al2O3 passivation in comparison with the non-passivated devices after bonding.
Online since: October 2011
Authors: Lei Zhou, Ming Jia, Chun Long Xu, Qiang Zhou, Jun Han
Due to the unsteady flow behavior can be more accurately simulated, LES methods more suited for complex highly time dependent flows such as those in internal combustion engine to capture the highly unsteady, anisotropic fuel-air mixing process and dynamically evolving fine-scale vortical and scalar structures [2].
By that time the spray structure has already developed.
Diesel combustion modeling using LES turbulence model with detailed chemistry, Combustion theory and modelling,2008, 12 (2):205-219
Using large eddy simulations to study diesel DI-HCCI engine flow structure, mixing and combustion: Madison: University of Wisconsin, 2007
Online since: May 2011
Authors: Wei Wei, Guo Tong Qin, Pei Jing Tang, Li Ping Wu
Effects of Pyrolysis Conditions on the Permeance of Phenol-formaldehyde Resin based Carbon Membrane for CO2 Separation Wei Wei1, a, Guotong Qin2,b, Peijing Tang1,c, Liping Wu1, d 1Department of Environmental Engineering, College of Arts and Science of Beijing Union University, 197 Beituchengxi Road, Beijing 100083, China 2School of Chemistry and Environment, Beihang University, 37 Xueyuan Road, Beijing 100083, China aweiwei@ygi.edu.cn, bguotongqin@yahoo.com.cn, cpeijing@ygi.edu.cn, dliping@ygi.edu.cn Keywords: Carbon membranes; phenol-formaldehyde novolac resin; carbonization; CO2 separation Abstract.
Volatile products during pyrolysis channelled their ways out of the membrane matrix that formed porous structure.
By thermostabilization with hexamine, the linear chains of polymer were partly crosslinked and formed a stable structure.
Rearrangement of structure occurred during pyrolysis which can release thermal stress.
Online since: December 2010
Authors: Wen Kui Li, Ze Hua Zhou, Zhi Qin Chen, Wei Jun Zeng, Hong Ying Yu
It is well known that the fundamental structure units in both anatase and rutile TiO2 are [TiO6] octahedra, but their modes of arrangement and link are different.
The different arrangement of [TiO6] octahedra get different crystal structures and various morphologies, which could be concerned with the coordination group of Ti(IV) complex ion in microwave hydrothermal solution.
F: Structure Inorganic Chemistry, 4th ed.
Online since: March 2004
Authors: Jong Ho Lee, Hai Won Lee, Joo Sun Kim, Geon Ja Lim, Sang Hoon Hyun
The mechanical energy was enough to surmount the activation energy for the chemical reaction between the reactants, however, the run-away reaction behavior resulted in aggregate particular structure of products.
The crystallinity of the particle synthesized by mechanochemical process was likely to be out of the ideal structure [9], and therefore, has required to be controlled directly at the stage of synthesis depending on the each purpose when applied as a powder form without any consolidation process.
McCormick: Nano Structured Materials, Vol. 8 (1997), p.75 [4] J.
Iler: The Chemistry of Silica; Solubility, Polymerization, Colloid and Surface properties, and Biochemistry (John Wiley & Sons Inc., New York 1979)
Online since: May 2004
Authors: M. Cilense, G. Brankovic, V.M. Vukotić, Tatjana Srećković, Z. Marinković, D. Arandjelović
Arandjelovi
 3 1 Center for Multidisciplinary Studies, University of Belgrade, Belgrade, Serbia and Montenegro 2Instituto de Química, UNESP, Araraquara, SP, Brazil 3Institute for General and Physical Chemistry, Belgrade, Serbia and Montenegro Keywords: CaTiO3, Mechanochemical Synthesis, Planetary Ball Mill ABSTRACT The synthesis of calcium titanate, CaTiO3, was performed by mechanical activation and thermal treatment.
INTRODUCTION Ceramics based on materials with a perovskite structure are very significant electronic ceramic materials.
Calcium titanate, CaTiO3, belongs to the group of compounds with a perovskite structure.
Acknowledgement The authors thank the Ministry of Science, Technology and Development of the Republic of Serbia for funding this research through the project "Synthesis of functional materials from the viewpoint of the synthesis-structure-properties-application relationship", No. 1832.
Online since: June 2014
Authors: Zbyněk Keršner, Hana Šimonová, Vlastimil Bílek Jr., Barbara Kucharczyková, Libor Topolář, Ivana Havlíková, Lubos Pazdera
Pilot Study of the Effect of Admixtures in Fine-grained Cement-based Composites on Volume Changes and Fracture Parameters Vlastimil Bílek Jr.1,a, Libor Topolář2,b, Hana Šimonová2,c, Barbara Kucharczyková2,d, Ivana Havlíková2,e, Luboš Pazdera2,f and Zbyněk Keršner2,g* 1Brno University of Technology, Faculty of Chemistry, Purkyňova 464/118, 612 00 Brno, Czech Republic 2Brno University of Technology, Faculty of Civil Engineering, Veveří 331/95, 602 00 Brno, Czech Republic axcbilekv@fch.vutbr.cz, btopolar.l@fce.vutbr.cz, csimonova.h@fce.vutbr.cz, dkucharczykova.b@fce.vutbr.cz, ehavlikova.i@fce.vutbr.cz, fpazdera.l@fce.vutbr.cz, gkersner.z@fce.vutbr.cz Keywords: fine-grained cement-based composite, slag, fly ash, metakaolin, fracture test, impact-echo, “double-K” model Abstract.
These reactions cause the volumetric expansion of concrete, which can lead to the formation of cracks in cement paste and aggregate, or even to the failure of the concrete structure.
A short-duration mechanical impact, generated by tapping a hammer against the surface of a concrete structure, produces low-frequency stress waves that propagate into the structure and are reflected by internal flaws and/or external surfaces.
Online since: December 2012
Authors: Jin Zhang, Bing Hu
It is mostly because of their trouble in choosing the definition of new terms and knowing the long and complicated sentence structure.
As for the subject Macromolecular Materials and Engineering, ESP involves materials, various molding methods, molding equipment, macromolecular chemistry and physics, performance test of macromolecular materials.
During the teaching course, the multimedia technology is applied to the gradual analysis of sentence structure on the screen.
For example, to analyze “However, in practice, cross-linked elastomers can have very imperfect network structures which contain dangling chain ends, loops in polymer chains, and branched molecules only partly incorporated into the network, as well as molecules entrapped in the network but not attached to it by chemical bonds.”, the slideshow is set to play main part “cross-linked elastomers can have very imperfect network first, then adds the attributive and points out the modifying part “in polymer chains, only partly incorporated into the network, entrapped in the network but not attached to it by chemical bond.”
Online since: November 2025
Authors: Orest Kvitsiani, Tinatin Laperashvili
Schematic of equipment for annealing of structures.
The schematic of the equipment for annealing semiconductor structures is shown in Fig. 2.
Photo-spectral characteristic of In/GaP structure annealed at 290°C for 30 min.
Reiss, Chemistry of InP nanocrystal syntheses, Chem.
Mikelashvili, Solar cells based on InP/GaP/Si structure, Proc.