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Online since: July 2011
Authors: Xiao Wu Yang, Yi Ding Shen, Pei Zhi Li, Gang Hui Li
Waterborne cationic fluorinated polyurethane modified by perfluorinated alkyl long chain
YANG Xiaowu1, a, SHEN Yiding1,b , LI Peizhi1, c and LI Ganghui 1,d
1 Key laboratory of Auxiliary Chemistry & technology for Chemical Industry, Ministry of Education.
Furthermore, its molecular structure can be adjusted to suit different applications by changing the ratio or category of soft and hard segments[1-2].
It is well known from the literature that once fluorine side chains are attached to the hard blocks, structure and cohesion of the hard segments can be changed.
Results and Discussion FT-IR analysis The molecular structure of the waterborne cationic polyurethane and waterborne cationic fluorinated polyurethane were characterized by FT-IR spectroscopy (as shown in Fig. 1).
It is clear that the low surface energies of FPUA films come mainly from the chemical structure of FEOH, which has strong hydrophobic fluorinated groups.
Furthermore, its molecular structure can be adjusted to suit different applications by changing the ratio or category of soft and hard segments[1-2].
It is well known from the literature that once fluorine side chains are attached to the hard blocks, structure and cohesion of the hard segments can be changed.
Results and Discussion FT-IR analysis The molecular structure of the waterborne cationic polyurethane and waterborne cationic fluorinated polyurethane were characterized by FT-IR spectroscopy (as shown in Fig. 1).
It is clear that the low surface energies of FPUA films come mainly from the chemical structure of FEOH, which has strong hydrophobic fluorinated groups.
Online since: December 2013
Authors: Xiang Hui Hou, Rosniza Hussin, Kwang Leong Choy
XRD patterns confirmed that ZnO with wutrtize crystal structure and TiO2 with anatase structure were presented.
All XRD patterns confirmed that ZnO with wutrtize crystal structure and TiO2 with anatase structure were presented.
XRD pattern of ZnO thin film matched with the wurtize structure (JCP 22.2CA 01-079-2205) and TiO2 thin films matched with the anatase structure (JCPDS pattern 00-021-1272).
All the peaks of the single layer ZnO deposited using 1200 cycles are in good accordance with the diffraction values of hexagonal wurtzite structure with predominantly (00.2) orientation.
Chang, Atomic layer-controlled growth of transparent conducting ZnO on plastic substrates ,Materials Chemistry and Physics 58 (1999) 132-138
All XRD patterns confirmed that ZnO with wutrtize crystal structure and TiO2 with anatase structure were presented.
XRD pattern of ZnO thin film matched with the wurtize structure (JCP 22.2CA 01-079-2205) and TiO2 thin films matched with the anatase structure (JCPDS pattern 00-021-1272).
All the peaks of the single layer ZnO deposited using 1200 cycles are in good accordance with the diffraction values of hexagonal wurtzite structure with predominantly (00.2) orientation.
Chang, Atomic layer-controlled growth of transparent conducting ZnO on plastic substrates ,Materials Chemistry and Physics 58 (1999) 132-138
Online since: April 2024
Authors: Touhami Mokrani, Rudzani A. Sigwadi, Mayetu E. Segale
Bruker Fourier-transform infrared spectroscopy (FTIR) was employed to investigate the changes in the chemical bond structures.
All samples exhibited typical key absorption bands signifying the presence of Nafion® structure.
Josa, Water channel structure of alternative perfluorosulfonic acid membranes for fuel cells.
Food Chemistry Advances, 2022: p. 100069
Zenkina, Reducing the resistance for the use of electrochemical impedance spectroscopy analysis in materials chemistry.
All samples exhibited typical key absorption bands signifying the presence of Nafion® structure.
Josa, Water channel structure of alternative perfluorosulfonic acid membranes for fuel cells.
Food Chemistry Advances, 2022: p. 100069
Zenkina, Reducing the resistance for the use of electrochemical impedance spectroscopy analysis in materials chemistry.
Online since: August 2012
Authors: Shi Wei Zhang, Zhi Jun Zhang, Jun Liu
The microscopic tissue structure was observed and chemical compositions were analyzed for those freeze-dried whole antlers in comparison with the traditional water boiling and hot air drying method.
These included color, microscopic tissue structure and blood distribution fields.
The microscopic tissue structures of samples were observed under the bio-microscope (AP300, Motic Ltd., China).
From microscopic tissue structure observations and chemical composition analysis, it was clear that the freeze-dried antlers differed significantly from traditionally dried antlers.
References [1] Ran Zhou, Shufen li, In Vitro Antioxidant Analysis and Characterisation of Antler Velvet Extract, Food Chemistry, vol. 114, pp.1321-1327, 2009
These included color, microscopic tissue structure and blood distribution fields.
The microscopic tissue structures of samples were observed under the bio-microscope (AP300, Motic Ltd., China).
From microscopic tissue structure observations and chemical composition analysis, it was clear that the freeze-dried antlers differed significantly from traditionally dried antlers.
References [1] Ran Zhou, Shufen li, In Vitro Antioxidant Analysis and Characterisation of Antler Velvet Extract, Food Chemistry, vol. 114, pp.1321-1327, 2009
Online since: January 2015
Authors: Tomasz Jan Kaldonski, Stanislaw Cudzilo
Study on the Thermal Stability of Selected Ionic Liquids
Tomasz Jan KALDONSKI1, a* and Stanislaw CUDZILO2
1Military University of Technology, Faculty of Mechanical Engineering, Poland
2Military University of Technology, Faculty of New Technology and Chemistry, Poland
akaldonskit@wat.edu.pl
Keywords: tribological nodes, lubricating oils, ionic liquids.
At the same time, it has been stated that the thermal resistance of ionic liquids depends on the composition and chemical structure of anion and cation.
Description of Lubricating Liquids under Tests Polish patented ionic liquids [10, 11], based on 1-alkyl-3-alkoxymethylimidazolium, purchased from POCH S.A, with differentiated structure of alkyl chain of cation, with [(CF3SO2)2N]¯ anion, and liquid based on the same cation, but with [BF4]¯ anion, were primarily tested.
Considerable similarity of TG/DTA curves for CJ002, CJ003, CJ004 ionic liquids is the result of their similar structure, see Figure 2.
Despite similarities of chemical composition and structure, these substances differ significantly in resistance to high temperature.
At the same time, it has been stated that the thermal resistance of ionic liquids depends on the composition and chemical structure of anion and cation.
Description of Lubricating Liquids under Tests Polish patented ionic liquids [10, 11], based on 1-alkyl-3-alkoxymethylimidazolium, purchased from POCH S.A, with differentiated structure of alkyl chain of cation, with [(CF3SO2)2N]¯ anion, and liquid based on the same cation, but with [BF4]¯ anion, were primarily tested.
Considerable similarity of TG/DTA curves for CJ002, CJ003, CJ004 ionic liquids is the result of their similar structure, see Figure 2.
Despite similarities of chemical composition and structure, these substances differ significantly in resistance to high temperature.
Online since: March 2014
Authors: Sandeep R. Shah, Ian L. Pryce, Todd B. St John, James M. Greer
Consequently, aircraft structures made from these alloys have exhibited fatigue and corrosion damage.
These sub-critical failures determine the residual life of the structure and are primarily used to evaluate their durability and damage tolerance.
In the case of SCC crack propagation, when the crack tip chemistry can change due to environment, the fracture toughness can be significantly changed.
Pressurization hoop stress cycling on aircraft structure is a very low frequency phenomenon.
[3] MIL-HDBK-5H: Metallic Materials and Elements for Aerospace Vehicle Structures, Air Force Research Laborabory, MLSC, Wright-Patterson AFB, OH, (1998)
These sub-critical failures determine the residual life of the structure and are primarily used to evaluate their durability and damage tolerance.
In the case of SCC crack propagation, when the crack tip chemistry can change due to environment, the fracture toughness can be significantly changed.
Pressurization hoop stress cycling on aircraft structure is a very low frequency phenomenon.
[3] MIL-HDBK-5H: Metallic Materials and Elements for Aerospace Vehicle Structures, Air Force Research Laborabory, MLSC, Wright-Patterson AFB, OH, (1998)
Online since: December 2012
Authors: Xia Zhang, Chan Wen Miao, Bei Ding, Dong Liang Zhou
Introduction
CSH gel hydration account for up to 70% of cement hydration products, structure and composition of CSH gel play a very important role on the performance of cementitious materials.
The experiments confirm that trialkoxysilanes such as ethyl- or aminopropyl-silane are incorporated in the silicate chains of C-S-H structure.
Polymer structure was investigated by infrared spectroscopy.
Drame, et al: Material and structures 42 (2009) 1003-1014
Taylor: Cement Chemistry, 2nd Edn.
The experiments confirm that trialkoxysilanes such as ethyl- or aminopropyl-silane are incorporated in the silicate chains of C-S-H structure.
Polymer structure was investigated by infrared spectroscopy.
Drame, et al: Material and structures 42 (2009) 1003-1014
Taylor: Cement Chemistry, 2nd Edn.
Online since: May 2025
Authors: Sabu John, Saad Saleh Alghamdi, Rajkamal Balu, Namita Choudhury, Naba Kumar Dutta
To optimize the integration of these materials for processing as 3D printed structures requires the exploration of functional compatibilizers to enhance the homogeneity and 3D printability of the Nylon-Cork composite.
In this ATR-FTIR work discussed in [12], specific point location analyses of the interface and interphase regions of nylon-cork composite revealed that when the APTS compatibilizer was used, the chemistry at the interface/phase was markedly altered.
Composite Structures 2021, 258, 113200
Transformation mechanism from cork into honeycomb–like biochar with rich hierarchical pore structure during slow pyrolysis.
Composite Structures 2013, 105, 153-162
In this ATR-FTIR work discussed in [12], specific point location analyses of the interface and interphase regions of nylon-cork composite revealed that when the APTS compatibilizer was used, the chemistry at the interface/phase was markedly altered.
Composite Structures 2021, 258, 113200
Transformation mechanism from cork into honeycomb–like biochar with rich hierarchical pore structure during slow pyrolysis.
Composite Structures 2013, 105, 153-162
Online since: February 2026
Authors: Santosh Khanal, Netra Prasad Subedi, Kedar Nath Ghimire
A wide variety of LDH structures can be designed by varying the nature of divalent and trivalent cations, their mole ratios, and the type of intercalated anions [15].
The XRD patterns of three LDHs are identical, showing similar crystalline structure.
XRD patterns of Mg-Al LDHs are similar irrespective of metal ion ratio and synthesis method indicating similar crystal structure.
A small characteristic peak appear at around 1630 cm-1 is due to the bending vibration of hydrogen-bonded OH groups (H-O-H) in interlayer water molecules, a typical feature of LDH structures [23].
Ardini, MgAl-NO₃ LDH: Adsorption isotherms and multivariate optimization for Cr(VI) removal, Chemistry. 5(1) (2023) 633–645. https://doi.org/10.3390/chemistry5010045
The XRD patterns of three LDHs are identical, showing similar crystalline structure.
XRD patterns of Mg-Al LDHs are similar irrespective of metal ion ratio and synthesis method indicating similar crystal structure.
A small characteristic peak appear at around 1630 cm-1 is due to the bending vibration of hydrogen-bonded OH groups (H-O-H) in interlayer water molecules, a typical feature of LDH structures [23].
Ardini, MgAl-NO₃ LDH: Adsorption isotherms and multivariate optimization for Cr(VI) removal, Chemistry. 5(1) (2023) 633–645. https://doi.org/10.3390/chemistry5010045
Online since: November 2025
Authors: Abayomi Olukayode Ewetade, Simeon Olutayo Odunfa, Mopelola Abidemi Idowu, Joseph Olawale Akinyele
SEM revealed differences in GPCD and GPCW with the latter displaying less dense structures and larger voids, consistent with the reduction in compressive strength over time.
This study concluded that GPC can be used for coastal marine concrete structures.
Pure fly ash geopolymer is not suitable for reinforced structures in saline environments.
“Durability Problems of Reinforced Concrete Structures on the Lagos Lagoon in Nigeria”.
“Geopolymer, Chemistry and applications” 5th Edition (2020).
This study concluded that GPC can be used for coastal marine concrete structures.
Pure fly ash geopolymer is not suitable for reinforced structures in saline environments.
“Durability Problems of Reinforced Concrete Structures on the Lagos Lagoon in Nigeria”.
“Geopolymer, Chemistry and applications” 5th Edition (2020).