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Online since: October 2010
Authors: Hai Tao Wang, Li Chen, Hai Yang Zhao, Yi Ping Zhao, Jun Fu Wei
As has been mentioned, PAAm hydrogels has the swelling capacity in water due to its hydrophilic groups and cross-linking structures.
Journal of Polymer Science: Part A: Polymer Chemistry, Vol. 42(12), 2004, p.2886 [7] H.
Yang, et al, Journal of Polymer Science: Part A: Polymer Chemistry, Vol. 42(17), 2004, p.4237 [11] L.
Tuo, et al, Macromolecular Chemistry and Physics, Vol.202(18), 2001, p.3530 [13] C.
Chemistry of Materials, Vol. 5(2), 1993, p.229
Journal of Polymer Science: Part A: Polymer Chemistry, Vol. 42(12), 2004, p.2886 [7] H.
Yang, et al, Journal of Polymer Science: Part A: Polymer Chemistry, Vol. 42(17), 2004, p.4237 [11] L.
Tuo, et al, Macromolecular Chemistry and Physics, Vol.202(18), 2001, p.3530 [13] C.
Chemistry of Materials, Vol. 5(2), 1993, p.229
Online since: October 2013
Authors: Laura Castro, María Luisa Blázquez, Felisa González, Jesús Angel Muñoz, Antonio Ballester
Introduction
The application of nanoscale materials and structures is an emerging area of nanoscience and nanotechnology.
The observation of silver nanoparticles by TEM showed that wire-like structures were synthesised at acidic pH (Fig. 2A).
Dendritic structures were obtained by agglomeration (Fig. 3A) and the platinum nature was evidenced by electron dispersive spectroscopy (Fig. 3B).
Chemistry of Materials. 21 (2009) 3562-3569
Iravani, Green synthesis of metal nanoparticles using plants, Green Chemistry. 13 (2011) 2638–2650
The observation of silver nanoparticles by TEM showed that wire-like structures were synthesised at acidic pH (Fig. 2A).
Dendritic structures were obtained by agglomeration (Fig. 3A) and the platinum nature was evidenced by electron dispersive spectroscopy (Fig. 3B).
Chemistry of Materials. 21 (2009) 3562-3569
Iravani, Green synthesis of metal nanoparticles using plants, Green Chemistry. 13 (2011) 2638–2650
Online since: March 2013
Authors: Jesper Friis, Knut Marthinsen, Ke Huang, Emmanuel Hersent
Modelling the evolution in microchemistry and its effects on the softening behavior of cold rolled AlFeMnSi-alloys during annealing
Emmanuel Hersent1,a, Ke Huang1,b, Jesper Friis2,c, and Knut Marthinsen1,d
1Department of Materials Science and Engineering, NTNU, NO-7491, Trondheim, Norway
2SINTEF Materials and Chemistry, NO-7465, Trondheim, Norway
aemmanuel.hersent@material.ntnu.no, bke.huang@ntnu.no, cjesper.friis@sintef.no, dknut.marthinsen@material.ntnu.no
Keywords: precipitation, recrystallization, modeling, concurrent precipitation
Abstract.
The last two properties are mainly controlled by the grain structure/size in the material and show opposite trends with increasing grain size: mechanical strength decreases whereas the material becomes less subject to corrosion.
The final grain structure results from the recovery/recrystallization behavior during the final heat treatment after cold rolling and is often strongly influenced by concurrent precipitation.
As the precipitates are non-stoichiometric, it is necessary to track how the precipitate chemistry changes with time.
Model Predictions Model calculations have been carried out by assuming an initial deformed structure with and and an initial precipitation state with constituents having a and and dispersoids having a and .
The last two properties are mainly controlled by the grain structure/size in the material and show opposite trends with increasing grain size: mechanical strength decreases whereas the material becomes less subject to corrosion.
The final grain structure results from the recovery/recrystallization behavior during the final heat treatment after cold rolling and is often strongly influenced by concurrent precipitation.
As the precipitates are non-stoichiometric, it is necessary to track how the precipitate chemistry changes with time.
Model Predictions Model calculations have been carried out by assuming an initial deformed structure with and and an initial precipitation state with constituents having a and and dispersoids having a and .
Online since: January 2015
Authors: Qing Wei Zhang, Wei Xie, Bao Hong Shen, Qiang Xie, Xiao Liang Li
Journal of Photochemistry and Photobiology a-Chemistry, 2009, 208(1): 27-35
Chemistry Review, 2007, 107(7): 2891-2959
Industrial & Engineering Chemistry Research, 2005, 44(19): 7366-7372
Journal of Industrial and Engineering Chemistry, 2009, 15(2): 190-195
Journal of Physical Chemistry C, 2007, 111(49): 18334-18340
Chemistry Review, 2007, 107(7): 2891-2959
Industrial & Engineering Chemistry Research, 2005, 44(19): 7366-7372
Journal of Industrial and Engineering Chemistry, 2009, 15(2): 190-195
Journal of Physical Chemistry C, 2007, 111(49): 18334-18340
Online since: July 2015
Authors: Petr Konvalinka, Ondřej Holčapek, Pavel Reiterman
We can find its use in special monolithic structures in industry, for fire-resistance brick, protection cladding, etc.
This process has led to large number of structures collapse and resulted in strict prohibition of use of aluminous cement in load-bearing structures.
[7] Kurdowski, W.: Cement and Concrete Chemistry, 2014, ISBN 987-97-007-7911-0 [8] Nilforoushan, M., R., Et al.
R., Talebian, N.: The Hydration Products of a refractory Calcium Aluminate Cement at Low Temperatures, Iranian Journal Chemistry Chemical Engineering 26/2 (2007)
M.: Structure and Performance of Cements.
This process has led to large number of structures collapse and resulted in strict prohibition of use of aluminous cement in load-bearing structures.
[7] Kurdowski, W.: Cement and Concrete Chemistry, 2014, ISBN 987-97-007-7911-0 [8] Nilforoushan, M., R., Et al.
R., Talebian, N.: The Hydration Products of a refractory Calcium Aluminate Cement at Low Temperatures, Iranian Journal Chemistry Chemical Engineering 26/2 (2007)
M.: Structure and Performance of Cements.
Online since: March 2013
Authors: Chinnapiyan Vedhi, R.R. Muthuchudarkodi
SYNTHESIS AND CHARACTERIZATION OF NANO CuO-ZrO2 MIXED OXIDE
R.R.Muthuchudarkodi1,a and C.Vedhi2,b
1Department of Chemistry, V.O Chidambaram College, Tuticorin –628008, Tamilnadu, INDIA
2Department of Chemistry, V.O Chidambaram College, Tuticorin –628008, Tamilnadu, INDIA
amuthu.rajaram@gmail.com ,bcvedhi@rediffmail.com
Keywords: Nano copper oxide, Nano Zirconium oxide, CuO-ZrO2, EDAX, Cyclic Voltammetry
ABSTRACT
Nano CuO-ZrO2 mixed oxides were prepared by wet chemical method by mixing equimolar solutions (0.45M) of cupric chloride (1.92g) and Zirconium oxychloride (3.63g) in aqueous Sodium hydroxide and refluxed at elevated temperature.
SEM morphological studies of CuO, ZrO2 and mixed CuO-ZrO2 revealed the particle distribution with uniform granular structure.
Stabilized Zirconia is used in Oxygen sensors and fuel cell membranes because it has the ability to allow oxygen ions to move freely through the crystal structure at high temperature.
References [1] Jolivet,J.P.(2000) Metal oxide chemistry and synthesis, Wiley, Chichester
SEM morphological studies of CuO, ZrO2 and mixed CuO-ZrO2 revealed the particle distribution with uniform granular structure.
Stabilized Zirconia is used in Oxygen sensors and fuel cell membranes because it has the ability to allow oxygen ions to move freely through the crystal structure at high temperature.
References [1] Jolivet,J.P.(2000) Metal oxide chemistry and synthesis, Wiley, Chichester
Online since: June 2015
Authors: Sergio Cava, Vânia Caldas Sousa, Tiago Delbrücke, Rogério A. Gouvêa, Cristiane W. Raubach, Sergio M. Tebcheranic, Evaldo T. Kubaski, Jose R. Jurado, Mário Lúcio Moreira, Elson Longo
In the FEG-SEM analysis, an interconnected porous structure with small grains was observed.
The crystalline phase of Al2O3-ZrO2 shown in Fig. 1 has a cubic structure [16], not being detected by Raman.
Varela: Materials chemistry and physics Vol. 103 (2007), p. 394
Djelloul: Journal of Solid State Chemistry Vol. 183 (2010), p. 1063
Scardi: Journal of Solid State Chemistry Vol. 86 (1990), p. 263
The crystalline phase of Al2O3-ZrO2 shown in Fig. 1 has a cubic structure [16], not being detected by Raman.
Varela: Materials chemistry and physics Vol. 103 (2007), p. 394
Djelloul: Journal of Solid State Chemistry Vol. 183 (2010), p. 1063
Scardi: Journal of Solid State Chemistry Vol. 86 (1990), p. 263
Online since: September 2013
Authors: N.R. Nik Roselina, Wan Normimi Roslini Abdullah, Nor Azrina Resali, Koay Mei Hyie, Z. Salleh, C.M. Mardziah
The Hc value of dendritic structure was found to be higher compared to the spherical structure.
The phase also exhibited the BCC crystal structure.
The dendritic structure in 30 minutes deposition exhibited the highest Hc value compared to the irregular structures in 90 minutes deposition.
Cheetham, The Chemistry of Nanomaterials.
Li, Highly Ordered Snowflakelike Metallic Cobalt Microcrystal, Journal Physical Chemistry C 111 (2006) 163-167
The phase also exhibited the BCC crystal structure.
The dendritic structure in 30 minutes deposition exhibited the highest Hc value compared to the irregular structures in 90 minutes deposition.
Cheetham, The Chemistry of Nanomaterials.
Li, Highly Ordered Snowflakelike Metallic Cobalt Microcrystal, Journal Physical Chemistry C 111 (2006) 163-167
Online since: November 2014
Authors: Qiang Li, Cai Xia Li, Xiao Dong Zhang, Dan Yu Jiang
Synthesis and Photo-catalytic Performance of
ZnO/Graphene Composites
Caixia Li1, a, Xiaodong Zhang1, Danyu Jiang3 and Qiang Li2, b*
1College of Resources and Environment, Yuxi Normal University, Yuxi 653100, China
2Department of Chemistry, East China Normal University, Shanghai 200062, China
3Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China
alicaixia1112@126.com, bqli@chem.ecnu.edu.cn
Keywords: ZnO; graphene; photo-degradation.
The phase structure and morphologies of the as-obtained composites were characterized and observed by X-ray diffraction (XRD) and Transmission Electron Microscopy (TEM).
The measurements showed that the different ZnO/Graphene composites prepared in this work have a remarkable structure, however, compared to the sample 2, the agglomeration of ZnO nano-particles supported on the surface of Graphene in the sample 4 is serious relativly.
Daifullah, Impact of Surface Chemistry on the Removal of Indigo Carmine Dye Using Apricot Stone Active Carbon.
Khomutov, Promising avenues of research in nanoscience: chemistry of semiconductor nanoparticles.
The phase structure and morphologies of the as-obtained composites were characterized and observed by X-ray diffraction (XRD) and Transmission Electron Microscopy (TEM).
The measurements showed that the different ZnO/Graphene composites prepared in this work have a remarkable structure, however, compared to the sample 2, the agglomeration of ZnO nano-particles supported on the surface of Graphene in the sample 4 is serious relativly.
Daifullah, Impact of Surface Chemistry on the Removal of Indigo Carmine Dye Using Apricot Stone Active Carbon.
Khomutov, Promising avenues of research in nanoscience: chemistry of semiconductor nanoparticles.
Online since: June 2014
Authors: Jia Chun Lu, Ping Huang, Zhi Chao Liu
The structure characteristic of pyrocarbon fluoride depends on the nature of host carbon.
These structure characteristics mainly depend on the temperature of heat-treatment (Tg).
The electrochemical behavior of fluorinated pyrocarbon depends on the structure of the host carbon.
Nakajima: Journal of Fluorine Chemistry. 149 (2013) 104-111
Zemva: Journal of Fluorine Chemistry. 120 (2003) 143-150.
These structure characteristics mainly depend on the temperature of heat-treatment (Tg).
The electrochemical behavior of fluorinated pyrocarbon depends on the structure of the host carbon.
Nakajima: Journal of Fluorine Chemistry. 149 (2013) 104-111
Zemva: Journal of Fluorine Chemistry. 120 (2003) 143-150.