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Effect of plasticizer of sizing agent on the surface of carbon fibers and interface of its composites Huanxia ZHANG1,a, AMin CAO2,b, Yongkang LUO3,c, Wei LI4,d 1，3，4Donghua University,College of Textiles, 2999 North Renmin Road, Songjiang District,Shanghai.201620,P.R.China 2Shanghai Institute of Organic Chemistry，345Lingling Road, Xuhui District,Shanghai.200032,P.R.China aZhanghuanxia818@163.com ,bacao@mail.sioc.ac.cn, cyongkangluo@yahoo.com.cn,d liwei@dhu.edu.cn Keywords: plasticizer, wear resistant, Surface energies, IFSS Abstract.
The sizing agent has been prepared in the lab of Shanghai Institute of Organic Chemistry.
Contact angle measurements The carbon fibers surface is non-polar and compound of highly crystallized graphitic basal planes with inert structures [8].As a result, the interfacial bonding strength between the carbon fibers and the resin matrix is low, good mechanical properties of composites cannot be achieved [9].
[8] H.B.Ezekiel,D.Sharp,M.M.Villalba,J.Davis,Laseranod ,sized carbon fiber: coupled activation and patterning of sensor substrates, Journal of Physics and Chemistry of Solids 69 (2008) 2932–2935
[11] T.H.Cheng,J.Zhang,S.Yumitori,F.R.Jones,C.W.Anderson, Sizing resin structure and interphase formation in carbon fiber composites, Composites 25 (1994)661–670.

De Gendt1,3 1 Imec, Kapeldreef 75, 3001 Leuven, Belgium 2 Dublin Institute of Technology, Ireland 3 also at Dept. of Chemistry, KULeuven, 3001 Leuven, Belgium a QuocToan.Le@imec.be Keywords: Post-etch residue removal, downstream plasma treatment, fluorocarbon polymer, ellipsometric porosimetry, porous low-k dielectrics Introduction In back-end of line (BEOL), the fluorinated polymer deposited on dielectric sidewalls during patterning [1,2] must be removed prior to subsequent processing steps to achieve good adhesion and coverage of materials (metals) deposited in the etched features.
The outcome of the present study offers an alternative approach to the two-step process via UV pre-treatment mentioned earlier and the single step process using formulated chemistries recently available [4].
Experimental The test materials used in this study were a model CFx polymer film generated by plasma polymerization using a C4F8/CF4-based plasma chemistry.
The absorbance bands recorded for this polymer are very similar to the one deposited on patterned structures described in literature [5] and to another model polymer deposited on a resist-mask checkerboard wafer reported previously [2-3].
Another aspect of this study concerned the effect of the dielectric patterning plasma (C4F8/CF4-based) on certain properties of the porous dielectric such as pore structure, surface sealing, and the extent of damage induced by the plasma.

We deduced the structure of the europium polymer as Fig.2 showed.
Fig.1 IR of PMMA, europium complex Fig.2 Structure of europium polymer and europium polymers UV Absorption Spectra UV absorption spectra of europium complex, the ligand TTA, polymer and PMMA were shown in Fig.3, there was no obvious absorption in the visible spectra, and the maximum absorption of TTA ligand was at 328nm, showed enol absorption band[9].
Materials Chemistry and Physics, 2005, 91: 172-179 [7] B.L.
Yang: Acta Scientiarum Naturalium Universitatis Sunyatseni, Vol. 4(2001), pp.61-65 [8] Hong Guo L, Seongtae P, Kinwan J, Wan Song Z．HyoJin S，Yong L．Different Photoluminescent Properties of Binary and Ternary Europium Chelates Doped in PMMA[J]．Materials chemistry and Physics, 2003, 82: 84-92
Zhang: Analytical Chemistry of Rare Earth Elements,(Beijing: Science Press, China 2000)

High-rate capability and excellent cycling stability of Li3V2(PO4)3/C cathode material prepared via sol-gel combined with ball milling method Yun-fei Longa, Qing-hua Xiaob, Jing Suc, Yi-ju LVd, Xiao-yan Lve, Yan-xuan Wenf School of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, China alongyf@gxu.edu.cn, bqinghua0603@163.com, csujing928@126.com, dleague051@163.com, elvxiaoyan666@163.com, fwenyanxuan@vip.163.com KEY WORDS: Lithium ion batteries; Cathode materials; Li3V2(PO4)3/C; Sol-gel.
Introduction Monoclinic structure Li3V2(PO4)3, as an potential cathode material, has attracted much attention for its high specific density, excellent rate capability and stability [1, 2].
(1) The phase composition and structure of the products were characterized by X-ray diffraction (XRD, Rigaku D/MAX2500V diffractometer with Cu Kα radiation).
Wei: Journal of Physical Chemistry C, Vol. 112(2008)No.14,p.5689
Battaglia: Journal of Materials Chemistry, Vol.22(2012)No.31,p.15775

Introduction In recent years, the studies on cross-coupling reactions have emerged as key synthetic steps in modern synthetic chemistry with new examples of element-element forming reactions being developed based on cross coupling reaction.
Fig. 1: The molecular structure of picoline thiourea (PTu) Experimental Materials and Instrumentation All chemicals used in this study were commercially available and used as received without any purification steps taken place.
For 13C NMR, PTu was consistent with the proposed molecular structure where the resonance of methyl group at δC 17.63 ppm.
Acknowledgements The authors would like to thank Ministry of Higher Education (MOHE) for research grant (FRGS 59158), School of Fundamental Science, Institute of Marine Biotechnology (IMB) Universiti Malaysia Terengganu (UMT) and Department of Chemistry, Universiti Teknologi Malaysia (UTM) for the technical, research facilities and support.
Daud: Procedia Chemistry, 20 (2016), p. 105-114.

Fig.1 The structure of daidzin.
Keung: Bioorganic & Medicinal Chemistry, Vol. 11(18) (2003) p. 4069-4081
Ho: Advances in Protein Chemistry,Vol. 45 (1994), p. 153
Zhang: European Journal of Medical Chemistry, Vol. 44 (2009), p. 4083
Liu: Journal of Solution Chemistry, Vol. 41 (2012), p. 351

Gold-nanoparticles (GNPs) play a special role in nanoscience and nanotechnology due to their high stability, electrical conductivity, optical properties and unique surface chemistry properties [12].
The hydrophobic structures in the lipid molecules become strong impediments for the hydrophilic probing molecules of [Fe(CN)6]3+ and [Fe(CN)6]2+, indicating that a stable BLM has been formed on the electrode surface.
Kerker, Editor, Surface Chemistry and Colloids, MTP International Review of Science, Butterworths, London, 1972, Series 2, Vol.7, Chapters 1 and 2
Robertson, Membrane structure, J.
Wescott, Reconstitution of cell membrane structure in vitro and its transformation into an excitable system, Nature 194 (1962) 979-980

Random mutagenesis is a good method for identifying critical regions of proteins, and played an important role in studying structure-function relations and developing novel proteins [4].
Janssen: Chemistry & biology.
Miller: Analytical chemistry.
Tsuda: Journal of Biological Chemistry.
Todaro: Journal of Biological Chemistry.

Synthesis of the carboxyl and pyridine functional ionic liquids Ying Xiong1,a, Min Yang*2.b 1.School of Chemistry and Material Science, Guizhou Normal University, Guiyang China 2.College Of Chemistry and Chemical Engineering, Guizhou University, Guiyang China a.yingxiong_10000@126.com,b.merrypengmin@126.com Keywords:basic ionic liquids; carboxyl; pyridine functional ionic liquids; synthesis Abstract.The effects of different solvents on synthesis of base functional ionic liquid, butyl pyridinium hydroxide ([bPy]OH), from butyl pyridinium bromine ([bPy]Br) were investigated systematically using KOH/NaOH as the base agent and strong base anion exchange resin.
For a new catalyst system, the structures of carboxylic functional ionic liquids have the obvious effects on their catalytic performances.
Due to the diversity of coordination modes of carboxyl groups, transition metal carboxylates tend to form cluster or polymer structures.
Chinese Journal of Applied Chemistry, 2007, 24 (9) : pp.1089 - 1091
Kazheva Synthesis and Structure of Co(III) Complexes with 2-Pyridinecarboxylic Acid [J]Russian Journal of Inorganic Chemistry, 2008, Vol. 53, No. 2, pp. 202–208

Synthesis and Characterization of Ce1-xZrxO2 Nanopaticles Elham Motyeian1 , Hamid Reza Aghabozorg2, Hossein Aghabozorg3 1 Faculty of Science, Department of Chemistry,Payame Noor University (PNU),Qom, Iran 2 Research Institute of Petroleum Industry-CRC,Tehran, Iran 3 Faculty of Chemistry,Islamic Azad University, North Branch, Tehran, Iran e-mail: e_motyeian@yahoo.com, e-mail: aghabozorghr@ripi.ir, e-mail: haghabozorg@yahoo.com Keywords: hydrothermal Sol-Gel, Cerium Oxide, nanoparticles, XRD, TEM Abstract.
The prepared powders have been characterized by powder X-ray diffraction (XRD), X-ray Fluorescence (XRF) .These studies reveled that zirconium is a good host for insertion into Cerium oxide in fluorite structure.
These results revealed that with adding Zr4+ ions (as guest) to the CeO2 structure (as host lattice), the interaction between doped Zr4+ cations and anions is increase and resulted in decreasing of unit cell parameters.
Also, the unit cell volume decrease with adding Zr4+ guest atoms to the CeO2 structure.
These experimental results are consistent with the above discussion regarding to the decrease of the unit cell volume with doping Zr4+ guest ions into the CeO2 structure.