Synthesis of AgCl Nanoparticles in W/O Microemulsion and Study of AgCl/Poly(GMA-co-MMA-co-AMPS) Copolymer Organic-Inorganic Hybrid Membranes

Ting Wang; Li Guang Wu; Zeng Jiang

doi:10.4028/www.scientific.net/AMM.328.719

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HomeApplied Mechanics and MaterialsApplied Mechanics and Materials Vol. 328Synthesis of AgCl Nanoparticles in W/O...

Synthesis of AgCl Nanoparticles in W/O Microemulsion and Study of AgCl/Poly(GMA-co-MMA-co-AMPS) Copolymer Organic-Inorganic Hybrid Membranes

Abstract:

AgCl Nanoparticles were synthesized in the W/O microemulsion using 2-acrylamido-2-methyl propane sulfonic acid as a surfactant, glycidyl methacrylate (GMA)/ methacrylate (MMA) mixtures as an oil phase. Then, AgCl/poly (GMA-MMA-AMPS) copolymer organic-inorganic hybrid membranes were prepared by in-situ microemulsion polymerization for separation of benzene/cyclohexane mixture. The effect of concentration of surfactant (C_AMPS) and salt (NaCl and AgNO₃) on the morphology of AgCl nanoparticles was studied by TEM. The results showed that the sizes of AgCl nanoparticles increased with salt concentration. AgCl nanoparticles maintained well dispersion in AgCl/poly (GMA-MMA-AMPS) copolymer organic-inorganic hybrid membranes. The hybrid membrane demonstrated good separation performance for benzene/cyclohexane mixtures.

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Applied Mechanics and Materials (Volume 328)

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719-723

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https://doi.org/10.4028/www.scientific.net/AMM.328.719

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June 2013

Authors:

Ting Wang, Li Guang Wu, Zeng Jiang

Keywords:

AgCl Nanoparticle, Hybrid Membrane, Swelling, W/O Microemulsion

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