Synthesis and Fluorescence Property of Rare-Earth Terbium Active Monomer Complexes

Article Preview

Abstract:

Tb-MA-Phen mononuclear rare earth complexes were prepared. The structure and properties of the complexes were characterized by elemental analysis, FT-IR and UV, TA, X-ray powder diffraction and SEM. Moreover, the rare earth ions were doped into the polymer matrix using the combinatorial method. High luminescence copolymer was synthesized by polymerizing α-methyl methyacrylate (MA) and Styrene (St) with terbium-methacrylate complex in solution with AIBN as initiator, respectively.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

724-728

Citation:

Online since:

June 2013

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] L. H. Wang, W. Wang, W. G. Zhang, E. T. Kang, W. Huang, Chem. Mater., 12: 2212,(2000).

Google Scholar

[2] B. Li, PhD dissertation, Changchun Institute of applied Chemistry, (1997).

Google Scholar

[3] E. Banks, Y. Okamoto, Y. Ueba, J. Appl. Polym. Sci., 25 (2): 359, (1980).

Google Scholar

[4] T. Sawada, S. Ando, Chem. Mater., 10: 3368, (1998).

Google Scholar

[5] Chen Ye,Sun Xiao Jun,Cai Wei Min,et al.Preparation and luminescence properties of the europium complex withα-naphthylacetic acid incorporated in silica matrix by sol-gel method[J]. Materials Chemistry and Physics,80:371-375,(2003).

DOI: 10.1016/s0254-0584(02)00541-2

Google Scholar

[6] Y. Q. Liang, Y. F. Zhao, Y. N. Zhao, Acta. Phys-Chim. Sin., 1: 493, (1985).

Google Scholar

[7] Y. Q. Liang, J. Z. Liu, G. F. Liu, Y. N. Zhao, Chem. J. Chinese. Univ., 8: 474, (1981).

Google Scholar

[8] D. M. Wang, Q. Lin, H.R. Li, Z. X. Chu, L. S. Fu, B. Yang , Chem. J.Chin. univer. , 22(4): 695, (2001).

Google Scholar

[9] M. Mikami, I. Nakagawa, T. Shimanouchi, Spectrochim. Acta., 23A: 1037, (1967).

Google Scholar

[10] Eisenberg A.Clustering of Ions in Organic Polymers A Theoretical Approach Macromolecules, 3(2): 147~154, (1970).

DOI: 10.1021/ma60014a006

Google Scholar