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A Novel H-Phosphonate Method for the Synthesis of D-Mannose-1-Phosphate

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Abstract:

A novel and efficient method for the preparation of α-D-mannose-1-phosphate has been developed. Phosphitylation of tetraacetylated D-mannose, hydrolysis yielded H-phosphonate monoester. Silylation of H-phosphonate, followed by oxidative coupling and hydrolysis gave protected D-mannose-1-phosphate. Finally, deprotection of tetraacetylated D-mannose-1-phosphate afforded D-mannose-1-phosphate in excellent yield.

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Periodical:

Applied Mechanics and Materials (Volume 483)

Pages:

88-91

DOI:

https://doi.org/10.4028/www.scientific.net/AMM.483.88

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Online since:

December 2013

Authors:

Xing Jian Li, Shan Shan Gong, Qi Sun*

Keywords:

Deacetylation, H-Phosphonate Monoester, Mannose-1-Phosphate, Phosphitylation

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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