Effects of Surface Treatment on the Performance of PEDOT: PSS/n-GaN Schottky Solar Cells

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We developed heterojunction-based Schottky solar cells consisting of π-conjugated polymers and n-type GaN. PEDOT: PSS was used as the transparent Schottky contact material. In order to improve the performance of solar cells, the effects of surface treatment on the electrical performance of PEDOT: PSS/n-GaN Schottky contacts were investigated. The Voc increased from 0.52V to 0.62V,0.54V and 0.54V and Isc from 0.33 mA/cm2 to 0.45mA/cm2,0.40mA/cm2 and 0.35mA/cm2 after HCl, HF solution and oxygen plasma treatments. The I-V and the XPS measurements indicated that the barrier height of PEDOT:PSS/n-GaN was increased from 0.62eV to 0.76eV, 0.72eV and 0.70eV and the ideality factor improved from 1.81 to 1.63, 1.67 and 1.73 respectively, which induced the variation of the solar cells characteristics..

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331-334

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January 2014

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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