Optrode Based Polymer for the Estimation of Free Chlorine

Article Preview

Abstract:

This paper describes the construction of low cost optical fiber sensor for the measurement of free chlorine and also residuals. The granules of poly (norborene) s bound with Cyanuric acid are synthesized as polymer film and applied on glass surface, which is used as sensing membrane. The prepared sensor membrane has a good photochemical stability and it would not leach out by continuous exposure to sample solution. The film is used to measure the changes in the absorbance intensity as a result of reaction between Cyanuric acid and free chlorine. The chlorine is used for the destruction of microbiological pathogens to protect the public health from water-borne diseases. This experiment was conducted for various chlorine samples. The sensor possess good repeatability with the range from 1.0 mg/l to 9.0 mg/l with minimal response time and also shows the characteristics such as reproducibility and stable results for more than 70 samples with a period of 5 days.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

856-860

Citation:

Online since:

June 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] C. Shang ,E.R. BAbcIII, Differentiation and quantification of free chlorine and inorganic chloramines in aqueous solution by MIMS, Environ. Sci. TEchnol(1999).

DOI: 10.1021/es9812103

Google Scholar

[2] S. Kodama , A. Yamamoto , M. Ohto, A. madsunaga , Major degradation pathway of thiuram in tap water processed by oxidation with sodium hypochloride. J Agric Food Chem. 1999 Jul; 47(7): 2914-9.

DOI: 10.1021/jf9813440

Google Scholar

[3] W. lee ,W. Paul, X Yang ,C. Shang , Comparison of Colorimetric and membrane Introduction Mass Spectrometry Techniques for Chloroamine Analysis, water res 41 . 41(2007).

DOI: 10.1016/j.watres.2007.04.032

Google Scholar

[4] Aaron Janzen, P. Eng Alvin Beier, R.E.T., P.L. (Eng). Groundwater Chlorination: Where Do You Fit On The Curve? April 1, (2009).

Google Scholar

[5] Daniel. L Harp , Current Tecnology of Chklorine Analysis for Water and Wastewater in technical Information Series –Booklet No. 17, Hach Company (2002).

Google Scholar

[6] G. constable ,B. Somerville , A century of innovation twenty engineering achievement that transformed our lifes, joseph henry press, Washington , DC, (2003).

DOI: 10.1063/1.1878337

Google Scholar

[7] Office of water U.S.E.P.A., 2006 Edition of teh drinking Water Standards and Health Advisories in Washington, DC, Office of Water , USEPA , (2006).

Google Scholar

[8] M. Tachikawa ,C. Sayama , k. Saita,M. tezuka, R. Sawamura Effects of isocyanuric acid on the monochlorodimedone chlorinating rates with free chlorine and ammonia chloramine in water , water res. 36(2002).

DOI: 10.1016/s0043-1354(01)00482-1

Google Scholar

[9] Information on http: /www. american chemistry . com/s. chlorine/in.

Google Scholar