Conversion of Lignocellulose into Fermentable Sugars Using Solid Acid Catalysis – A Review

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From literature it is depicted that the conversion of biomass to renewable chemicals and fuels is becoming a pivotal research topic for the last few decades. Cellulose is a rich biomass, which is formed by carbon dioxide and water by sunlight. However the efficient chemical conversion of cellulose is considered to be a challenge for the researchers because of its persistent property. A lot of research is carried out on heterogeneous catalyst, among the others, solid acid catalyst are recognized as the most attractive choice for the conversion of cellulose because they are tunable and durable in nature. In this article, an overview of the conversion of cellulose into platform chemicals using the solid acid catalyst is carried out.

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341-344

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September 2014

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] Piccolo, C. and F. Bezzo, A techno-economic comparison between two technologies for bioethanol production from lignocellulose. Biomass and bioenergy, 2009. 33(3): pp.478-491.

DOI: 10.1016/j.biombioe.2008.08.008

Google Scholar

[2] Camacho, F. and P. Gonzalez-Tello, Microcrystalline-cellulose hydrolysis with concentrated sulphuric acid.

Google Scholar

[3] Agarwal, U.P., J. Zhu, and S.A. Ralph, Enzymatic hydrolysis of loblolly pine: effects of cellulose crystallinity and delignification. Holzforschung, 2013. 67(4): pp.371-377.

DOI: 10.1515/hf-2012-0116

Google Scholar

[4] Gliozzi, G., et al., Zr/P/O catalyst for the direct acid chemo-hydrolysis of non-pretreated microcrystalline cellulose and softwood sawdust. Applied Catalysis B: Environmental, 2014. 145(0): pp.24-33.

DOI: 10.1016/j.apcatb.2012.12.035

Google Scholar

[5] Sun, Y. and J. Cheng, Hydrolysis of lignocellulosic materials for ethanol production: a review. Bioresource technology, 2002. 83(1): pp.1-11.

DOI: 10.1016/s0960-8524(01)00212-7

Google Scholar

[6] Bootsma, J.A. and B.H. Shanks, Cellobiose hydrolysis using organic–inorganic hybrid mesoporous silica catalysts. Applied Catalysis A: General, 2007. 327(1): pp.44-51.

DOI: 10.1016/j.apcata.2007.03.039

Google Scholar

[7] Rinaldi, R. and F. Schüth, Design of solid catalysts for the conversion of biomass. Energy & Environmental Science, 2009. 2(6): pp.610-626.

Google Scholar

[8] Zhang, C., et al., Magnetic core-shell Fe3O4@C-SO3H nanoparticle catalyst for hydrolysis of cellulose. Cellulose, 2013. 20(1): pp.127-134.

DOI: 10.1007/s10570-012-9839-5

Google Scholar

[9] Onda, A., T. Ochi, and K. Yanagisawa, Hydrolysis of cellulose selectively into glucose over sulfonated activated-carbon catalyst under hydrothermal conditions. Topics in Catalysis, 2009. 52(6-7): pp.801-807.

DOI: 10.1007/s11244-009-9237-x

Google Scholar

[10] Ramesh Kumar, C., P.S. Sai Prasad, and N. Lingaiah, Aluminium exchanged heteropoly tungstate supported on titania catalysts: The generation of Lewis acidity and its role for benzylation reaction. Journal of Molecular Catalysis A: Chemical, 2011. 350(1–2): pp.83-90.

DOI: 10.1016/j.molcata.2011.09.011

Google Scholar

[11] Tian, J., et al., Hydrolysis of cellulose by the heteropoly acid H<sub Cellulose, 2010. 17(3): pp.587-594.

Google Scholar

[12] Dimitrijevic, R., W. Lutz, and A. Ritzmann, Hydrothermal stability of zeolites: Determination of extra-framework species of HY faujasite-type steamed zeolite. Journal of Physics and Chemistry of Solids, 2006. 67(8): pp.1741-1748.

DOI: 10.1016/j.jpcs.2006.03.014

Google Scholar

[13] Lai, D. m., et al., Hydrolysis of cellulose into glucose by magnetic solid acid. ChemSusChem, 2011. 4(1): pp.55-58.

Google Scholar

[14] Tagusagawa, C., et al., Highly Active Mesoporous Nb–W Oxide Solid‐Acid Catalyst. Angewandte Chemie, 2010. 122(6): pp.1146-1150.

DOI: 10.1002/ange.200904791

Google Scholar

[15] Toda, M., et al., Default Green chemistry: Biodiesel made with sugar catalyst. Nature, 2005. 438: pp.178-178.

Google Scholar

[16] Huang, J., et al., Concentration and acid strength of hydroxyl groups in zeolites La, Na-X and La, Na-Y with different lanthanum exchange degrees studied by solid-state NMR spectroscopy. Microporous and Mesoporous Materials, 2007. 104(1–3): pp.129-136.

DOI: 10.1016/j.micromeso.2007.01.016

Google Scholar

[17] Pedrosa, A.M.G., et al., Synthesis, characterization and catalytic properties of the cobalt and nickel supported on HZSM-12 zeolite. Catalysis Communications, 2006. 7(10): pp.791-796.

DOI: 10.1016/j.catcom.2006.02.012

Google Scholar

[18] Zhang, et al., Recent Research on One-Dimensional Silicon-Based Semiconductor Nanomaterials: Synthesis, Structures, Properties and Applications. Critical Reviews in Solid State and Material Sciences, 2011. 36(3): pp.148-173.

DOI: 10.1080/10408436.2011.589233

Google Scholar