Catalytic Conversion of Oil Palm Fronds to Levulinic Acid in Ionic Liquid

Article Preview

Abstract:

Conversion of oil palm fronds (OPF) to levulinic acid (LA) over Fe/HY zeolite catalyst in BMIM[Br] ionic liquid has been investigated in this study. The optimization of OPF conversion reported 24.7% levulinic acid yield at 153 °C, 5.9 h, 0.96 g and 1.1 g of reaction temperature, reaction time, OPF loading and catalyst loading, respectively. The results indicated that BMIM[Br] could disrupt the covalent linkages in the OPF structures and dissolved the hollocellulose. This allowed the hollocellulose chains, accessible to the chemical transformation, to react and produce LA in presence of the Fe/HY catalyst. This study demonstrated that the combination of Fe/HY catalyst and BMIM[Br] has the potential to be applied for biomass conversion to LA under adequate process conditions.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

361-365

Citation:

Online since:

September 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] D.W. Rackemann, W.O.S. Doherty, The conversion of lignocellulosics to levulinic acid. Biofuels Bioprod. Biorefin. 5 (2011) 198–214.

DOI: 10.1002/bbb.267

Google Scholar

[2] C. Chang, P. Cen, X. Ma, Levulinic acid production from wheat straw. Bioresource Technol. 98 (2007) 1448–1453.

DOI: 10.1016/j.biortech.2006.03.031

Google Scholar

[3] L. Peng, L. Lin, J. Zhang, J. Zhuang, B. Zhang, Y. Gong, Catalytic conversion of cellulose to levulinic acid by metal chlorides. Molecules. 15 (2010) 5258–5272.

DOI: 10.3390/molecules15085258

Google Scholar

[4] H. Olivier-Borbigou, L. Magna, D. Morvan, Ionic liquids and catalysis: Recent progress from knowledge to applications. Appl. Catal. A: Gen. 373 (2010) 1–56.

DOI: 10.1016/j.apcata.2009.10.008

Google Scholar

[5] J.A. Cornell. How to Apply Response Surface Methodology. American Society for Quality Control, (1990).

Google Scholar

[6] M. Kang, S.W. Kim, J.W. Kim, T.H. Kim, J.S. Kim. Optimization of levulinic acid production from Gelidium amansii. Renew Energ. 54 (2013) 173–179.

DOI: 10.1016/j.renene.2012.08.028

Google Scholar

[7] X.C. Yu, D.L. Sun, X.S. Li. Preparation of levulinic acid using cellulase and solid acid synergistic hydrolysis for rice straw. Asian J Chem 22 (2010) 7113–7122.

Google Scholar

[8] N. Ya'aini, N.A.S. Amin, S. Endud, Optimization of levulinic acid from lignocellulosic biomass using a new hybrid catalyst. Bioresource Technol. 116 (2012) 58–65.

DOI: 10.1016/j.biortech.2012.03.097

Google Scholar