Synthese, Crystal Structure of O-P-O Bridged MnIII(Schiff Base) Phosphinate Complexe

Yan Xu

doi:10.4028/www.scientific.net/AMM.700.156

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HomeApplied Mechanics and MaterialsApplied Mechanics and Materials Vol. 700Synthese, Crystal Structure of O-P-O Bridged...

Synthese, Crystal Structure of O-P-O Bridged Mn^III(Schiff Base) Phosphinate Complexe

Abstract:

A novel O-P-O bridged [Mn (3-MeOsalen)·H₂O] (3-MeOsalen = N,N'-ethylenebis (3-methoxysalicylideneiminato) dianion) chain compound, namely [Mn₂(3-MeOsalen)₂(O₂PPh₂)(H₂O)₂] [Mn (3-MeOsalen)(H₂O)₂]·(ClO₄)₂·(H₂O)₄ (1) is successfully synthesized and structurally characterized. Compound 1 crystallized in monoclinic, space group P2₁/c. This compound consists of two fragments, the dinuclear cationic unit [Mn₂(3-MeOsalen)₂(O₂PPh₂)(H₂O)₂]⁺, which is resulted from O-P-O bridged cationic unit [Mn (3-MeOsalen)·H₂O]⁺, and mononuclear unit [Mn (3-MeOsalen)(H₂O)₂]⁺, forming an one-dimensional chain by intermolecular hydrogen bonding and strong π-π stacking.

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Applied Mechanics and Materials (Volume 700)

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156-160

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https://doi.org/10.4028/www.scientific.net/AMM.700.156

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December 2014

Authors:

Yan Xu*

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Crystal Structure, Manganese, Phosphinate, Schiff Base

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References

[1] C. Janiak: Dalton Trans. (2003), p.2781.

Google Scholar

[2] T.M. Smith, D. Symester, K. Perrin, J. Vargas, M. Tichenor, C. J. O'Conno, J. Zubieta: Inorganica Chimica Acta Vol. 402 (2013), p.46.

DOI: 10.1016/j.ica.2013.03.003

Google Scholar

[3] F. Benetollo, V. Peruzzo, S. Tamburini , P.A. Vigato F. Benetollo, V. Peruzzo, S. Tamburini, P.A. Vigato Inorganic Chemistry Communications Vol. 15 (2012) , p.84.

DOI: 10.1016/j.inoche.2011.09.044

Google Scholar

[4] H. Miyasaka, R. Clérac,T. Ishii, H.C. Chang, S. Kitagawac, and M. Yamashita: J. Chem. Soc., Dalton Trans (2002), p.1528.

Google Scholar

[5] K. Bernot, J. Luzon, R. Sessoli, A. Vindigni, J. Thion, S. Richeter, and A. Lee: J. Am. Chem. Soc. Vol. 130 (2008), p.1619.

DOI: 10.1021/ja0751734

Google Scholar

[6] W.X. Zhang, T. Shiga, H. Miyasaka, and M. Yamashita: J. Am. Chem. Soc. Vol. 134 (2012), p.6908.

Google Scholar

[7] V. Chandrasekhar, J. Goura, and E. C. Sanudo: Inorg. Chem. Vol. 51 (2012), p.8479.

Google Scholar

[8] T.T. Wang, S.S. Bao, J. Huang, Y.Z. Li and L.M. Zheng: Dalton Trans., Vol. 42 (2013), p.1842.

Google Scholar

[9] J.W. Lee, K.S. Lim, D. W. Ryu, E. K. Koh, S.W. Yoon, B. J . Suh, and C. S. Hong: Inorg. Chem. Vol. 52 (2013), p.8677.

Google Scholar

[10] H. J. Choi, J.J. Sokol, and J.R. Long: Inorg. Chem. Vol. 43 (2004), p.1606.

Google Scholar

[11] P. Przychodzeń,K. Lewiński, M. Bałanda, R. Pełka, M. Rams, T. Wasiutyński, C. Guyard-Duhayon and B. Sieklucka, Inorg. Chem. Vol. 43 (2004), p.2967.

DOI: 10.1021/ic035464n

Google Scholar