Cationic Catalyst as Latent Curing Agent for Epoxy Resin

Ho Kyoung Choi; Bong Goo Choi; Yong Yoon Lee; Jae Sik Na

doi:10.4028/www.scientific.net/AMM.749.126

Paper Titles

Refractive Index Variation of Fe₃O₄ Thin Film According to Deposition Rate
p.106

The Usage of Pet Kok is a Possibility of Reducing the Amount of Heavy Oil in the Rotary Kilns in the New Foundry of the New Ferronikel in Drenas
p.111

Modelling of Material Composition in X-Ray Diagnostics
p.116

An Analysis of Low-Pressure High-Frequency Plasma Chemical Vapor Deposition System for Flexible Solar Cell Characteristics
p.121

Cationic Catalyst as Latent Curing Agent for Epoxy Resin
p.126

Dependence of Mechanical and Dielectric Properties on Temperature of Poly(Vinylidene Fluoride-Hexafluoropropylene)
p.129

Density Functional Theory Studies of Electronic Structures and Hyperfine Interactions of Muonium in Imidazole
p.134

Optical Property of Sb-Doped SnO₂ Nanoparticle Thin Films by Sparking Process
p.141

Ellipsometry as Testing Method of Properties of Nano-Scale Films
p.146

HomeApplied Mechanics and MaterialsApplied Mechanics and Materials Vol. 749Cationic Catalyst as Latent Curing Agent for Epoxy...

Cationic Catalyst as Latent Curing Agent for Epoxy Resin

Abstract:

1-Benzyl-3-methyl-imidazolium hexafluoroantimonate (BMH) was newly synthesized and characterized with FT-IR, 1H-NMR. We synthesized catalysts fulfill requirements for a rapid cure at a moderately elevated temperature in curing the epoxy resin for neat diglycidyl ether bisphenol A (DGBEA). The cure behavior of this resin was investigated at elevated temperature and cure temperature in the presence of 0.5, 1.0, 2.0 wt% of 1-benzyl-3-methyl-imidazolium hexafluoroantimonate (BMH) by mean of differential scanning calorimeter (DSC). Chemical conversion as function of temperature and amount of BMH (0.5, 1.0, 2.0 wt%) were determined from DSC. It was found that BMH were superior latent thermal catalyst for catinonic curing which have a good thermal stability.

You might also be interested in these eBooks

View Preview

Info:

Periodical:

Applied Mechanics and Materials (Volume 749)

Pages:

126-128

DOI:

https://doi.org/10.4028/www.scientific.net/AMM.749.126

Citation:

Cite this paper

Online since:

April 2015

Authors:

Ho Kyoung Choi, Bong Goo Choi, Yong Yoon Lee, Jae Sik Na

Keywords:

Cationic Catalyst, Conversion, Epoxy Resin, Latent Curing Agent

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

References

[1] O. Shimomura, I. Tomita and T. Endo, Curing behavior of epoxy resin initiated by S-alkylsulfonium salts of aromatic sulfides as thermal latent cationic initiators, , J. polym. sci. partA polm. chem. 39 (2001) 868-871.

DOI: 10.1002/1099-0518(20010315)39:6<868::aid-pola1060>3.0.co;2-4

Google Scholar

[2] K. Morio, H. Murase, H. Tsuchiya and T. Endo, Thermoinitiated cationic polymerization of epoxy resins by sulfonium salts, J. Appl. Polym. Sci. 32 (2009) 5727-5732.

DOI: 10.1002/app.1986.070320705

Google Scholar

[3] S. Murai, Y. Nakano and S. Hayase, Novel latent initiator for cationic polymerization of epoxides, J. Appl. Polym. Sci. 80 (2001) 181-187.

DOI: 10.1002/1097-4628(20010411)80:2<181::aid-app1085>3.0.co;2-l

Google Scholar

[4] S.P. Pappas and L.W. Hill, Kinetic parameter considerations for maximizing stability and minimizing cure temperature of thermosetting coatings, J Coat Technol, 53 (1981) 43-51.

Google Scholar

[5] T. Endo, A. Kikkawa, H. Uno, H. Sato, M Hiza and T. Takata, Cationic polymerization of vinyl monomers with latent catalysts. I. Cationic polymerization of styrene with a benzylsulfonium salt at high temperature, J Polym Sci Part C 27 (1989) 73-77.

DOI: 10.1002/pol.1989.140270205

Google Scholar

[6] J. Gu, S.C. Narang and E.M. Pearce, Curing of epoxy resins with diphenyliodonium salts as thermal initiators, J Appl Polym Sci 30 (1985) 2997-3007.

DOI: 10.1002/app.1985.070300722

Google Scholar

[7] J. Park, Photo-induced cationic ring-opening polymerization of 4-methylene-2-styryl-1, 3-dioxolane by benzylsulfonium salt, Korea Polymer Journal, 9 (2001) 206-209.

Google Scholar