Liquid Crystalline Epoxy Resin Cured with Azomethine Hardening Compounds

Ho Kyoung Choi; Jae Hyun Choi; Hyeoung Seok Lee; Jae Sik Na

doi:10.4028/www.scientific.net/AMM.749.22

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HomeApplied Mechanics and MaterialsApplied Mechanics and Materials Vol. 749Liquid Crystalline Epoxy Resin Cured with...

Liquid Crystalline Epoxy Resin Cured with Azomethine Hardening Compounds

Abstract:

Bisphenol of 4,4’-dihydroxy-N-benzylidene-4-aminophenol containing azomethine group was synthesized via condensation of an aromatic amine namely 4-aminophenol with p-hydroxybenz aldehyde. It’s epoxy derivate and epicholorohydrin produced the new liquid crystalline diglycidyl ether of 4,4’-dihydroxy-N-benzylidene-4-aminophenol. A new type of liquid crystalline epoxy and azoemthine hardening agent are characterized at 300°C for 10 min, using c11z as a catalyst. The chemical structures were confirmed by FT-IR, ¹H-NMR. The curing reaction with 4,4’-dihydroxy-N-benzylidene-4-aminophenol were carried out in the ratio of glycidyl ether of 4,4’-dihydroxy-N-benzy lidene-4-aminophenol/azomethine hardening 1:0.8. The degree of crystallinity studied by X-ray diffractometer, differential scanning calorimetry (DSC) and polarized optical microscope (POM).

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Periodical:

Applied Mechanics and Materials (Volume 749)

Pages:

22-24

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https://doi.org/10.4028/www.scientific.net/AMM.749.22

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Online since:

April 2015

Authors:

Ho Kyoung Choi, Jae Hyun Choi, Hyeoung Seok Lee, Jae Sik Na*

Keywords:

Azomethine, Liquid Crystalline Epoxy

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* - Corresponding Author

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