Nitrogen Doped TiO2 Prepared under Microwave Irradiation: Effect of Different Irradiation Light

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A visible light active nitrogen (N) doped TiO2 was prepared using commercially available TiO2 P25. In this study, a simple N doped TiO2 was prepared by mixing of TiO2 powder with urea as N precursor under microwave irradiation instead of normal using muffle furnace as heating media. Prepared N doped TiO2 samples shows active under visible light irradiation due to lower band gaps energy of N doped TiO2 observed by UV/Vis-DRS. U3-800 was found as optimum N doped where photodegradation rate of RR4 dye under is 1.6 times faster compared with unmodified TiO2 as well as control TiO2 under normal 55-W fluorescent lamp. An active photo response under visible light was observed from U3-800 with 80 minutes of time irradiation to complete RR4 color removal, while no photocatalytic degradation was observed from unmodified and control TiO2. As a result, this study contributed to purification of effluent specifically toxic dyes with complete mineralization under visible light irradiation. For the future work, the modification of TiO2 with nitrogen and metal doping will indirectly increase the efficiency of photodegradation under visible light. In future, the immobilized technique can also be applied for N doped TiO2 to overcome the reusability issue.

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372-377

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May 2016

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© 2016 Trans Tech Publications Ltd. All Rights Reserved

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