Ionic Transport and Electrochemical Properties of PMMA-Based Gel Polymer Electrolytes for Magnesium Batteries

Nurul Husna Zainol; Mohd. Zharfan Mohd. Halizan; Woon Gie Chong; Zurina Osman

doi:10.4028/www.scientific.net/AMR.1024.348

Paper Titles

Dielectric Relaxation in Lanthanide Doped/Based Oxides Used for High-k Layers
p.331

Electrochemical Stability of High Conducting PAN-Based Electrolytes for Lithium Ion Polymer Cells
p.335

The Structure and Electrochemical Performance of LiNi_0.3Co_0.3Mn_0.3Cr_0.1O₂ Cathode Materials
p.339

Luminescence of Sr₂MgSi₂O₇ Phosphor Prepared by Solid State Reaction
p.344

Ionic Transport and Electrochemical Properties of PMMA-Based Gel Polymer Electrolytes for Magnesium Batteries
p.348

Energy Bandgap Engineering of ZnO Using Impurity Elements for Solar Cell Applications: A DFT Study
p.352

Growth and Characterization of (100) and (111) 3C-SiC Thin Film for MEMS Capacitive Pressure Sensor for Extreme Environments
p.356

Post-Deposition Annealing in Nitrous Oxide Ambient of RF-Magnetron Sputtered Y₂O₃ Film on Silicon Substrate
p.360

Effects of Post-Deposition Annealing Time on Metal-Organic Decomposed Lanthanum Cerium Oxide Film Spin-Coated on Si Substrate
p.364

HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 1024Ionic Transport and Electrochemical Properties of...

Ionic Transport and Electrochemical Properties of PMMA-Based Gel Polymer Electrolytes for Magnesium Batteries

Abstract:

Poly (methyl) methacrylate (PMMA)-based gel polymer electrolytes (GPEs) containing magnesium triflate, Mg (CF₃SO₃)₂ salt were prepared using solution casting technique. Different concentrations of Mg (CF₃SO₃)₂ ranging from 5 wt.% to 30 wt.% have been added into a mixture of ethylene carbonate (EC) and propylene carbonate (PC) with a fixed mass ratio of 2:1. These free-standing GPE films were characterized using electrochemical impedance spectroscopy (EIS), linear sweep voltammetry (LSV) and cyclic voltammetry (CV). The highest ionic conductivity of 1.27 x 10^-3 S cm^-1 is obtained from the GPE film containing 20 wt.% of Mg (CF₃SO₃)₂ salt. The electrochemical window stability has been found in the range of-2.5 V to 2.5 V for the highest conducting GPE film. This value is considerably high enough for the GPE film to be used as electrolyte in magnesium rechargeable batteries.

You might also be interested in these eBooks

Advancement of Materials and Nanotechnology III

View Preview

Info:

Periodical:

Advanced Materials Research (Volume 1024)

Pages:

348-351

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.1024.348

Citation:

Cite this paper

Online since:

August 2014

Authors:

Nurul Husna Zainol*, Mohd. Zharfan Mohd. Halizan, Woon Gie Chong, Zurina Osman

Keywords:

Conductivity, CV, Gel Polymer Electrolytes, LSV, Magnesium Salt

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

* - Corresponding Author

References

[1] S. Ramesh, C. -H. Liew and K. Ramesh. Evaluation and investigation on the effect of ionic liquid onto PMMA-PVC gel polymer blend electrolytes. J. Non-Cryst. Solids 357 (2011) 2132-2138.

DOI: 10.1016/j.jnoncrysol.2011.03.004

Google Scholar

[2] J. -S. Oh, J. -M. Ko and D. -W Kim. Preparation and characterization of gel polymer electrolytes for solid sate magnesium batteries. Electrochim Acta 50 (2004) 903-906.

DOI: 10.1016/j.electacta.2004.01.099

Google Scholar

[3] N. Yoshimoto, S. Yakushiji, M. Ishikawa and M. Morita. Rechargeable magnesium batteries with polymeric gel electrolytes containing magnesium salts. Electrochim Acta 48 (2003) 2317-2322.

DOI: 10.1016/s0013-4686(03)00221-4

Google Scholar

[4] G. Girish Kumar and N. Munichandraiah. Poly(methylmethacrylate)-magnesium triflate gel polymer electrolyte for solid state magnesium battery application. Electrochim Acta 47 (2002) 1013-1022.

DOI: 10.1016/s0013-4686(01)00832-5

Google Scholar

[5] G.P. Pandey, R.C. Agrawal, and S.A. Hashmi. Performance studies on composite gel polymer electrolytes for rechargeable magnesium battery application. J. Phys and Chem of Solids 72 (2011) 1408-1413.

DOI: 10.1016/j.jpcs.2011.08.003

Google Scholar

[6] S.K. Tripathi, Amrita Jain, Ashish Gupta and Manju Mishra. Electrical and electrochemical studies on magnesium ion-based polymer gel electrolytes. J. Solid State Electrochem 16 (2012) 1799-1806.

DOI: 10.1007/s10008-012-1656-0

Google Scholar

[7] K.W. Chew and K.W. Tan. The effects of ceramic fillers on PMMA-based polymer electrolyte salted with lithium triflate, LiCF3SO3. Int. J. Electrochem Sci. 6 (2011) 5792-5801.

Google Scholar

[8] M.R. Johan and L.M. Ting. Structural, Thermal and Electrical Properties of Nano Manganese-Composite Polymer Electrolytes. Int. J. Electrochem Sci. 6 (2011) 4737-4748.

Google Scholar

[9] Y. Kumar, S.A. Hashmi, & G.P. Pandey. Ionic liquid mediated magnesium ion conduction in poly(ethylene oxide) based polymer electrolyte. Electrochim Acta 56(11) (2011)3864-3873.

DOI: 10.1016/j.electacta.2011.02.035

Google Scholar

[10] C. -C. Hu, & T. -W. Tsou. Ideal capacitive behavior of hydrous manganese oxide prepared by anodic deposition. Electrochem Commun 4(2) (2002) 105-109.

DOI: 10.1016/s1388-2481(01)00285-5

Google Scholar