Synthesis, Crystal Structure of a Twin-Nest-Shaped Cluster Compound, [Mo2O2S6Cu6I2(4,4'-bipy)3]n

Yan Xu; Yun Biao Sun; Yi Min Wu

doi:10.4028/www.scientific.net/AMR.1033-1034.615

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 1033-1034Synthesis, Crystal Structure of a Twin-Nest-Shaped...

Synthesis, Crystal Structure of a Twin-Nest-Shaped Cluster Compound, [Mo₂O₂S₆Cu₆I₂(4,4'-bipy)₃]_n

Abstract:

The title complex, [Mo₂O₂S₆Cu₆I₂(4,4'-bipy)₃]_n 1, is consists of cluster cation [Mo₂O₂S₆Cu₆I]⁺ and counterion I^-. The cluster cation consists of two nest-shaped [MoOS₃Cu₃]²⁺fragments interconnected through iodides [Cu-I distance:3.1951(16) Å,and Cu-I-Cu bond angle:180° ]. From a topological viewpoint, each building cluster [MoOS₃Cu₃]⁺, linked by another three crystallographically equivalent [MoOS₃Cu₃]⁺ units through single 4,4’-bipy bridges, can be regarded as a 6-connected node, affording a novel two-dimensional layered structure.

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Advanced Materials Research (Volumes 1033-1034)

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615-618

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https://doi.org/10.4028/www.scientific.net/AMR.1033-1034.615

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October 2014

Authors:

Yan Xu, Yun Biao Sun, Yi Min Wu

Keywords:

Cluster Compound, Crystal Structure, Molybdenum

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References

[1] V. H. Houlding and V. M. Miskowski: Coord. Chem. Rev Vol. 111 (1991), p.145.

Google Scholar

[2] A. McAuley, S. Subramanian and M. J. Zaworotko: J. Chem. Soc., Chem. Commun (1992), p.1321.

Google Scholar

[3] K. Liang, H. Zheng Y.L. Song, M. F. Lappert, Y.Z. Li, X.Q. Xin Z.X. Huang, J.T. Chen, and S.F. Lu: Angew. Chem. Int. Ed. Vol. 43(2004), p.5776.

Google Scholar

[4] J.F. Zhang Y.L. Song, J.Y. Yang M.G. Humphrey, and C. Zhang: Crystal Growth & Design, Vol. 8(2008), p.387.

Google Scholar

[5] H. Zheng, J. L Zhou,M. F. Lappert,Y. l. Song Y.Z. Li, and X. Q Xin,Y. Mishing: Eur. J. Inorg. Chem. (2004), p.2754.

Google Scholar

[6] K.X. Huang,Y. l. Song, Z.R. Pan Y.Z. Li, X. Zhuo, and H.G. Zheng: Inorg. Chem. Vol. 46(2007), p.6233.

Google Scholar

[7] Y. Han , Z.H. Zhang , Y.Y. Liu , Y.Y. Niu, D.G. Ding , B.L. Wu , H.W. Hou , and Y.T. Fan: Cryst. Growth Des., , Vol. 11 (2011), p.3448.

Google Scholar

[8] Z.R. Pan,J. Xu,H. GZheng K.X. Huang, Y.Z. Li,Z.J. Guo, and S. R. Batten: Inorg. Chem. Vol. 48 (2009), p.5772.

Google Scholar