Removal of Carbon Dioxide by Emulsion Liquid Membrane Containing Blended Amine

Siti Balqis Mohd Najib; Khairul Sozana Nor Kamaruddin

doi:10.4028/www.scientific.net/AMR.1113.481

Paper Titles

Tar Elimination from Producer Gas by Using In Situ Catalytic Reforming of Tar
p.459

The Effects of Soaking on Rice Granules for Bedak sejuk Production
p.465

Total Phenolic Content and Antioxidant Activity of Local Fruit Wastes in Malaysia
p.471

Ultrasound-Assisted Extraction of Natural Dye from Exocarp and Mesocarp of Cocos nucifera
p.477

Removal of Carbon Dioxide by Emulsion Liquid Membrane Containing Blended Amine
p.481

Reusability of Fenton Sludge to Reduce COD and Color on Palm Oil Mill Secondary Effluent (POMSE)
p.486

Flooding with Biopolymer from Microbes Derived from Mushroom and Cabbage to Enhance Sweep Efficiency in Enhanced Oil Recovery
p.492

Morphology of L-Alanine Crystal, Associated with its Interaction with Glycine Additive: A Molecular Modelling and Experimental Study
p.498

Racemic Ibuprofen Morphology: Molecular Modelling and Experimental
p.504

HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 1113Removal of Carbon Dioxide by Emulsion Liquid...

Removal of Carbon Dioxide by Emulsion Liquid Membrane Containing Blended Amine

Abstract:

The capture of carbon dioxide (CO₂) by aqueous alkanolamine is the most cost effective technology available today. However, some problem such as amine losses, corrosion and low absorption rate arise when aqueous alkanolamines is used as an absorbent. To overcome these problems, liquid emulsion was introduced as an alternative for CO₂ removal. However, the main concern of using liquid emulsion is the stability of the emulsion. In this study, a formulation containing mixture of blended alkanolamine was used. Methyldiethanolamine (MDEA) and 2-amino-2-methyl-1-propanol (AMP) were used as extractants and were mixed with sodium hydroxide (NaOH) solution to form the aqueous phase. Meanwhile, the organic phase consists of kerosene and Span 80. The emulsion was prepared by homogenizing both phases at speed of 10 000 rpm for five minutes. The stability of the MDEA-AMP emulsion was determined and the CO₂ absorption by the emulsion was measured. This study showed that using 8 mL MDEA and 4mL AMP, the stability of the emulsion was 74.00% and 48.05% of CO₂was removed.

You might also be interested in these eBooks

Material Science Technology and Global Sustainability

View Preview

Info:

Periodical:

Advanced Materials Research (Volume 1113)

Pages:

481-485

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.1113.481

Citation:

Cite this paper

Online since:

July 2015

Authors:

Siti Balqis Mohd Najib, Khairul Sozana Nor Kamaruddin

Keywords:

Absorption, Amines, CO₂ Removal, Emulsion, Stability

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

References

[1] M.L. Gray, Y. Soong, K.J. Champagne, H. Pennline, J.P. Baltrus, R.W. Stevens, R. Jr. Khatri, S.S.C. Chuang and T. Filburn, 2005. Improved Immobilized Carbon Dioxdie Capture Sorbents. Fuel Processing Technology. 86(14-15): 1449–1455.

DOI: 10.1016/j.fuproc.2005.01.005

Google Scholar

[2] A. Meisen, and X.S. Shuai, 1997. Research and Development Issue in CO2 Capture. Energy Conversion and Management. 38: 837-842.

Google Scholar

[3] X. Xu, C. Song, B.G. Miller and A.W. Scaroni, 2005. Adsorption Separation of Carbon Dioxide From Flue Gas of Natural Gas-Fired Boiler by A Novel Nanoporous Molecular Basket, Adsorbent. Fuel Processing Technology. 86: 1457-1472.

DOI: 10.1016/j.fuproc.2005.01.002

Google Scholar

[4] K. S. N. Kamarudin, I. Bhatti, S. N. Suahadah, U. N. Hamzah, Z. F. MohdFaiz, 2010. Removal of Carbon Dioxide Using Water-in-oil Emulsion Liquid Membrane Containing Triethanolamine. Journal of Applied Sciences Research. 6(12), 2251-2256.

Google Scholar

[5] M. Fingas, B. Fieldhouse and J. Mullin, 1995. Water in Oil Emulsions: How They are Formed and Broken. Proceeding International Oil Spill Conference, Long Beach, California. 829-830.

DOI: 10.7901/2169-3358-1995-1-829

Google Scholar

[6] S. W. Park, J. H. Ryu, S. S. Lee, K. S. Hwang, and H. Kumazawa, 1997. Gas Absorption of CO2 into Emulsion with Alkaline Aqueous Solution. ibid, 35, 476.

Google Scholar

[7] M. K. Aroua, M. Z. Haji-Sulaiman, and K. Ramasamy, 2002. Modelling of carbon dioxide absorption in aqueous solutions of AMP and MDEA and their blends using Aspenplus. Separation and Purification Technology. 29, 153-162.

DOI: 10.1016/s1383-5866(02)00071-0

Google Scholar

[8] M. Huang, A. N. Soriano, A. R. Caparanga, M. Li 2011. Kinetics of absorption of carbon dioxide in 2-amino-2-methyl-l-propanol +N-methyldiethanolamine + water Journal of the Taiwan Institute of Chemical Engineering 42: 76-85.

DOI: 10.1016/j.jtice.2010.04.007

Google Scholar