A Preliminary Study on Li4Ti5O12 as a Novel Electrode Material for Calcium Ion Batteries

Chang Su Kim; Yun Taek Jeong; Soon Ki Jeong

doi:10.4028/www.scientific.net/AMR.1120-1121.119

Paper Titles

Investigation of Preparation and Thermoelectric Properties of Ca_2.5La_0.5Co₄O₉ Porous Ceramics
p.98

Study of Leaching Zinc from Difficult Dealt Zinc Oxide Ore with High Silicon in the Alkali
p.105

Synthesis and Salt Resistance of Novel Polyampholyte P(DMAPMA-co-HEA)-CA
p.110

Electrochemical Properties of Chemically Etched-NbO₂ as a Negative Electrode Material for Lithium Ion Batteries
p.115

A Preliminary Study on Li₄Ti₅O₁₂ as a Novel Electrode Material for Calcium Ion Batteries
p.119

Effects of Preparation Conditions on Alkali-Activation Reactivity of Chemosynthetic Al₂O₃-2SiO₂ Powders
p.123

Study of Circulation of Reaction Liquid in Liquid Phase Synthesis of LiFePO4 as Cathode Material
p.128

Synthesis of Li₂Fe_0.5Mn_0.5SiO₄/C as Cathode Material for Lithium-Ion Batteries Using Amorphous Li₂SiO₃
p.132

Study on Using Chenghe Fly Ash to Prepare 4A Molecular Sieve
p.137

HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 1120-1121A Preliminary Study on Li4Ti5O12 as a Novel...

A Preliminary Study on Li₄Ti₅O₁₂ as a Novel Electrode Material for Calcium Ion Batteries

Abstract:

The electrochemical behaviors of a spinel lithium titanate oxide (Li₄Ti₅O₁₂, LTO) electrode during as a novel electrode for calcium ion batteries were investigated during the charging and discharging to understand its electrochemical properties. The electrochemical performance of the LTO electrode was improved by the addition of dimethyl carbonate to the PC-based electrolyte. The initial charge and discharge capacities were ~262 and ~85 mAh g^–1, respectively. The results of the X-ray diffraction analysis showed that the lattice constant of LTO increased after charging, indicating that calcium ions were inserted into Li₄Ti₅O₁₂ during the charging.

You might also be interested in these eBooks

Contemporary Approaches in Material Science and Materials Processing Technologies

View Preview

Info:

Periodical:

Advanced Materials Research (Volumes 1120-1121)

Pages:

119-122

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.1120-1121.119

Citation:

Cite this paper

Online since:

July 2015

Authors:

Chang Su Kim, Yun Taek Jeong, Soon Ki Jeong*

Keywords:

Calcium Ion Battery, Li₄Ti₅O₁₂, Negative Electrode, PC-Based Electrolyte

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

* - Corresponding Author

References

[1] I. Kovalenko, B. Zdyrko, A. Magasinski, B. Hertzberg, Z. Milicev, R. Burtovyy, I. Luzinov, G. Yusin, Science 334 (2011) 75–79.

DOI: 10.1126/science.1209150

Google Scholar

[2] B. Peng, J. Liang, Z. Tao, J. Chen, J. Mater. Chem. 19 (2009) 2877–2883.

Google Scholar

[3] Y. Cao, L. Xiao, M. -L. Sushko, W. Wang, B. Schwenzer, J. Xiao, Z. Nie, L. -V. Saraf, Z. Yang, J. Liu, Nano Lett. 12 (2012) 3783–3787.

DOI: 10.1021/nl3016957

Google Scholar

[4] L. Jiao, H. Yuan, Y. Wang, J. Cao, Y. Wang, Electrochem. Commun. 7 (2005) 431–436.

Google Scholar

[5] S. Saito, S. Yanase, Radiosotopes 60 (2011) 265–274.

Google Scholar

[6] N. Wu, Y. -C. Lyu, R. -J. Xiao, X. Yu, Y. -X. Yin, X. -Q. Yang, H. Li, L. Gu, Y. -G. Guo, NPG Asia Materials 6 (2014) 1–7.

Google Scholar

[7] S. Takeuchi, T. Fukutsuka, K. Miyazaki, T. Abe, J. Power Sources 238 (2013) 65–68.

Google Scholar

[8] Y. Yamamda, Y. Takazawa, K. Miyazaki, T. Abe, J. Phys. Chem. C 114 (2010) 11680–11685.

Google Scholar

[9] T. -F. Yi, Y. Xie, Y. -R. Zhu, H. Shen, J. Power Sources 222 (2013) 448–454.

Google Scholar

[10] L. Kavan, J. Prochazka, T. -M. Spitler, M. Kalvac, M. Zukalova, T. Drezen, M. Gratzel, J Electrochem Soc. 150 (2003) A1000–A1007.

Google Scholar

[11] L. Aldon, P. Kubiak, M. Womes, J. -C. Jumas, J. -O. Fourcade, J. -L. Tirado, J. -I, Corredor, C. -P. Vicente, Chem. Mater. 16 (2004) 5721–5725.

DOI: 10.1021/cm0488837

Google Scholar

[12] S. -L. Chou, J. -Z Wang, H. -K. Liu, S. -X. Dou, J. Phys. Chem. C 115 (2011) 16220–16227.

Google Scholar

[13] Y. -R. Zhu, L. -C. Yin, T. -F. Yi, H. Liu, Y. Xie, R. -S. Zhu J. Alloys Compd. 547 (2013) 107–112.

Google Scholar