Synthesis and Salt Resistance of Novel Polyampholyte P(DMAPMA-co-HEA)-CA

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Abstract:

A novel polyampholyte P(DMAPMA-co-HEA)-CA was prepared by the quaternization of chloroacetic acid (CA) to P(DMAPMA-co-HEA), which was synthesized by the copolymerization of 2-hydroxyethyl acrylate (HEA) and N-(3-dimethylaminopropyl)maleamic acid (DMAPMA). The isoelectric point (IEP) of P(DMAPMA-co-HEA)-CA was studied by titration, and the salt resistance of P(DMAPMA-co-HEA)-CA expressed by viscosity was determined in sodium chloride solution by Ubbelohde viscometer. The results show that P(DMAPMA-co-HEA)-CA possesses excellent salt resistance in sodium chloride solution.

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Advanced Materials Research (Volumes 1120-1121)

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110-114

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July 2015

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© 2015 Trans Tech Publications Ltd. All Rights Reserved

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[1] A.V. Dobrynin, R.H. Colby, M. Rubinstein, Polyampholytes, J. Polym. Sci. Pol. Phys. 42 (2004) 3513-3538.

DOI: 10.1002/polb.20207

Google Scholar

[2] G. Ehrlich, P. Doty, Macro-ions, III. The Solution Behavior of a Polymeric Ampholyte, J. Am. Chem. Soc. 76 (1954) 3764-3777.

DOI: 10.1021/ja01643a053

Google Scholar

[3] C.L. McCormick, C.B. Johnson, Water-soluble polymers: 33. Ampholytic terpolymers of sodium 2-acrylamido-2-methylpropanesulphonate with 2-acrylamido-2-methylpropane dimethylammonium chloride and acrylamide: synthesis and aqueous-solution behaviour, Polymer 31 (1990).

DOI: 10.1016/0032-3861(90)90258-z

Google Scholar

[4] B. Gao, X. Zhang, Y. Zhu, Studies on the preparation and antibacterial properties of quaternized polyethyleneimine, J. Biomat. Sci. Polym. E. 18 (2007) 531-544.

Google Scholar

[5] J. You, H. Hu, J. Zhou, Synthesis, structure and solution properties of the novel polyampholytes based on cellulose, Cellulose 20 (2013) 1175-1185.

DOI: 10.1007/s10570-013-9891-9

Google Scholar

[6] A.B. Lowe, C.L. McCormick, Synthesis and Solution Properties of Zwitterionic Polymers, Chem. Rev. 102 (2002) 4177-4189.

DOI: 10.1021/cr020371t

Google Scholar

[7] T. Alfrey, H. Morawetz, E.B. Fitzgerald, R.M. Fuoss, Synthetic electrical analog of proteins1, J. Am. Chem. Soc. 72 (1950) 1864.

DOI: 10.1021/ja01160a532

Google Scholar

[8] A.B. Lowe, C.L. McCormick, Polyelectrolytes and Polyzwitterions, American Chemical Society, New York, (2006).

Google Scholar

[9] R.G. Ezell, C.L. McCormick, Electrolyte and pH-responsive polyampholytes with potential as viscosity-control agents in enhanced petroleum recovery, J. Appl. Polym. Sci. 104 (2007) 2812-2821.

DOI: 10.1002/app.24999

Google Scholar

[10] ISO-304. Surfactant.

Google Scholar

[11] A. Dubey, N.A. D Burke, H.D.H. Stoever, Preparation and characterization of narrow compositional distribution polyampholytes as potential biomaterials: Copolymers of N-(3-Aminopropyl)methacrylamide hydrochloride (APM) and methacrylic acid (MAA), J. Polym. Sci. Pol. Chem. 53 (2015).

DOI: 10.1002/pola.27377

Google Scholar