Characterization of Nanostructured and Conventional TiAlN Coatings Deposited on AISI-304 Boiler Steel

Article Preview

Abstract:

In the manuscript conventional and nanostructured nitrided coatings developed to increase hardness and to improve the wear, erosion and corrosion resistance of structural materials. Three coatings of TiAlN were deposited on AISI-304, out of which two were thin nanocoatings at different temperatures of 500°C and 200°C are developed by Oerlikon Balzer’s rapid coating system machine under a reactive nitrogen atmosphere. One conventional coating TiAl was deposited by Plasma spraying method which was post nitrided. Then the coated samples were characterized with relative to coating thickness, microhardness, porosity and structure. The XRD and SEM/EDAX techniques have been used to identify various phases formed after coating on the surface of steel.The microhardness of conventional TiAlN coating was found to be of the order of 900-950 Hv. The grain size for nanostructured TiAlN coatings deposited at 500°C and 200°C are 15nm and 14nm respectively as calculated by Sherrer’s formula from XRD plot.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

1-14

Citation:

Online since:

June 2016

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2016 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] B.Q. Wang, G.Q. Geng and A.V. Levy, Erosion and Erosion-Corrosion Behaviour of Chromized-Siliconized Steel, Surf. Coat. Technol., Vol. 54-55, (1992), pp.529-35.

DOI: 10.1016/s0257-8972(07)80077-6

Google Scholar

[2] Turunen Erja, Varis Tommi, E. Tom Gustafsson, Keskinen Jari, Falt Teppo and Hannula Simo-Pekka, Parameter optimization of HVOF sprayed nanostructured optimization alumina and alumina-nickel composite coatings, Surface Coatings and Technology, Vol. (200), issue 16-17, (2006).

DOI: 10.1016/j.surfcoat.2005.05.018

Google Scholar

[3] Chanxian Ding, Huang Chen, Xuanyong Liu and Yi Zeng, Plasma sprayed nanostructured zirconia coatings for wear resistance, Thermal Spray 2003. Advancing the science & applying the technology (Ed. ) C. Moreau and B. Marple, Published by ASM International, Materials Park, Ohio, USA, (2003).

DOI: 10.31399/asm.cp.itsc2003p0455

Google Scholar

[4] Hazoor Singh Sidhu, Buta Singh Sidhu and S. Prakash, Mechanical and microstructural properties of HVOF sprayed WC-CO and Cr3C2-NiCr coatings on the boiler tube steels using LPG as the fuel gas, Journal of Materials Processing Technology, Vol. 171, (2006).

DOI: 10.1016/j.jmatprotec.2005.06.058

Google Scholar

[5] B.S. Sidhu, D. Puri and S. Prakash, Characterisations of Plasma Sprayed and Laser Remelted NiCrAlY Bond Coats and Ni3Al Coatings on Boiler Tube Steels, Mater. Sci. Eng. A-Struct., Vol. 368, No. 1-2, (2004), pp.149-158.

DOI: 10.1016/j.msea.2003.10.281

Google Scholar

[6] L. Leblanc, Abrasion and sliding wear of nanostructured ceramic coatings, Thermal Spray 2003. Advancing the science & applying the technology (Ed. ) C. Moreau and B. Marple, Published by ASM International, Materials Park, Ohio, USA, (2003).

DOI: 10.31399/asm.cp.itsc2003p0291

Google Scholar

[7] Luo Hong, Goberman Daniel, Shaw Leon and Gell Maurice, Indentation fracture behaviour of plasma sprayed nanostructured Al2O3-13wt% T1O2 coatings, Materials Science & Engineering A, Vol. (346), (2003), pp.237-245.

DOI: 10.1016/s0921-5093(02)00523-3

Google Scholar

[8] V. Chawla, B.S. Sidhu, D. Puri, S. Parkash Performance of Plasma Sprayed Nano structured and Conventional Coatings, Journal of Australian ceramic society, Vol. 44, No. 2, (2008), pp.56-62.

Google Scholar

[9] L. Fedrizzi, S. Rossi, R. Cristel and P.L. Bonora Corrosion and wear behaviour of HVOF cermet coatings used to replace hard chromium, Elect. Chem. Acta 49, (2004), pp.2803-2814.

DOI: 10.1016/j.electacta.2004.01.043

Google Scholar

[10] B.S. Sidhu, D. Puri and S. Prakash, Characterisations of Plasma Sprayed and Laser Remelted NiCrAlY Bond Coats and Ni3Al Coatings on Boiler Tube Steels, Mater. Sci. Eng. A-Struct., Vol. 368, No. 1-2, (2004), pp.149-158.

DOI: 10.1016/j.msea.2003.10.281

Google Scholar

[11] H.C. Chen, Z.Y. Liu and Y. C. Chuang, Degradation of Plasma-Sprayed Alumina and Zirconia Coatings on Stainless Steel During Thermal Cycling and Hot Corrosion, Thin Solid Films, Vol. 223, No. 1, (1993), pp.56-64.

DOI: 10.1016/0040-6090(93)90727-7

Google Scholar

[12] L.C. Erickson, R. Westergard, U. Wiklund, N. Axen, H.M. Hawthorne and S. Hogmark, Cohesion in Plasma-Sprayed Coatings: A Comparison between Evaluation Methods, Wear, Vol. 214, (1998), pp.30-37.

DOI: 10.1016/s0043-1648(97)00216-0

Google Scholar

[13] V.H. Hidalgo, F.J.B. Varela and A.C. Menendez, Characterization and High Temperature Behaviour of Thermal Sprayed Coatings Used in Boilers, Proc. of the 15th Int. Thermal Spray Conf., 25-29th May, Nice, France, (1998), pp.617-21.

DOI: 10.31399/asm.cp.itsc1998p0617

Google Scholar

[14] V.H., Hidalgo, F.J.B. Varela, S.P. Martinez, and S.G. Espana, Characterization and High Temperature Behaviour of Cr3C2-NiCr Plasma Sprayed Coatings, Proc. of the United Thermal Spray Conf., Germany, (1999), pp.683-86.

DOI: 10.31399/asm.cp.itsc1999p0683

Google Scholar

[15] Buta Singh, Studies on the Role of Coatings in Improving Resistance to Hot Corrosion and Degradation, Ph.D. Thesis, Met. & Mat. Eng. Dept., Indian Institute of Technology Roorkee, Roorkee, India (2003).

Google Scholar

[16] H. Singh, D. Puri and S. Prakash, Some Studies on Hot Corrosion Performance of Plasma Sprayed Coatings on a e-based Superalloy, Surf. Coat. Technol., Vol. 192, (2005), pp.27-38.

DOI: 10.1016/j.surfcoat.2004.03.030

Google Scholar

[17] Y.H. Yoo, D.P. Le, J.G. Kim, S.K. Kim and P.V. Vinh, Corrosion Behaviour of tiN, TiAlN, TiAlSiN thin Films Deposited on Tool Steel in the 3. 5 wt. % NaCl Solution, Thin Solid Films, Vol. 516, No. 11, (2008), pp.3544-3548.

DOI: 10.1016/j.tsf.2007.08.069

Google Scholar

[18] C.V. Falub, A. Karimi, M. Ante and W. Kalss, Interdependence between Stress and Texture in Arc Evaporated Ti-Al-N Thin Films, Surf. Coat. Technol., Vol. 201, No. 7, (2007), pp.5891-5898.

DOI: 10.1016/j.surfcoat.2006.10.046

Google Scholar

[19] B.Y. Man, L. Guzman, A. Miotello and M. Adami, Microstructure, Oxidation and H2-pemeation Resistance of TiAlN Films Deposited by DC Magnetron Sputtering Technique, Surf. Coat. Technol., Vol. 180-181, (2004), pp.9-14.

DOI: 10.1016/j.surfcoat.2003.10.021

Google Scholar

[20] S. Adachi and K. Nakata Improvement of Adhesive Strength of Ti-Al Plasma -Sprayed Coatings, Surf. Coat. Technol., Vol. 201, (2007), pp.5617-5620.

DOI: 10.1016/j.surfcoat.2006.07.014

Google Scholar

[21] P. Vuoristo, K. Niemi, A. Makela and T. Mantyla, Abrasion and Erosion Wear Resistance of Cr3C2-NiCr Coatings Prepared by Plasma, Detonation and High-Velocity Oxyfuel Spraying, Proc. of the 7th National Thermal Spray Conf., Boston, Massachusetts, (1994).

Google Scholar

[22] H. Chen and I.M. Hutchings, Abrasive Wear Resistance of Plasma-Sprayed Tungsten Carbide-Cobalt Coatings, Surf. Coat. Technol., Vol. 107, (1998), pp.106-14.

DOI: 10.1016/s0257-8972(98)00581-7

Google Scholar

[23] R. Westergard, L.C. Erickson, N. Axen, H.M. Hawthorne and S. Hogmark, The Erosion and Abrasion Characteristics of Alumina Coatings Plasma Sprayed Under Different Spraying Conditions, Trib. Int., Vol. 31, No. 5, (1998), pp.271-79.

DOI: 10.1016/s0301-679x(98)00033-4

Google Scholar

[24] V.H. Hidalgo, F.J.B. Varela and E.F. Rico, Erosion Wear and Mechanical Properties of Plasma-Sprayed Nickel- and Iron-Based Coatings Subjected to Service Conditions in Boilers, Trib. Int., Vol. 30, No. 9, (1997), pp.641-49.

DOI: 10.1016/s0301-679x(97)00029-7

Google Scholar

[25] V.H. Hidalgo, J.B. Varela, J.M. de la Calle and A.C. Menendez, Characterisation of NiCr Flame and Plasma Sprayed Coatings for Use in High Temperature Regions of Boilers, Surface Engg., Vol. 16, No. 2, (2000), pp.137-42.

DOI: 10.1179/026708400101517035

Google Scholar

[26] S.T. Bluni and A.R. Mardar, Effects of Thermal Spray Coating Composition and Microstructure on Coating Response and Substrate Protection at High Temperatures, Corros., Vol. 52, No. 3, (1996), pp.213-218.

DOI: 10.5006/1.3292116

Google Scholar

[27] H. Herman, Plasma Sprayed Coatings, Scientific American, Vol. 259, No. 3, (1988), pp.78-83.

Google Scholar

[28] K. Korpiola and P. Vuoristo, Effect of HVOF Gas Velocity and Fuel to Oxygen Ratio on the Wear Properties of Tungsten Carbide Coating, In: Bernt, C. C. (ed. ). Thermal Spray: Practical Solutions for Engineering Problems. Cincinnati. USA. 11 - 17 October. ASM, (1996).

DOI: 10.31399/asm.cp.itsc1996p0177

Google Scholar

[29] J.E. Nerz, B.A. Kushner, A.J. Jr. Rotolico, Microstructural Evaluation of Tungsten Carbide-Cobalt Coatings, ASM International (USA), (1992), pp.115-120.

DOI: 10.1007/bf02659015

Google Scholar

[30] B. Wang, R.F. Huang, G.H. Song, J. Gong, C. Sun, L.S. Wen and Y.F. Han, Interdiffusion Behavior of Ni-Cr-Al-Y Coatings Deposited by Arc-Ion Plating, Oxid. Met., Vol. 56, No. 1-2, (2001), pp.1-12.

Google Scholar