Oxidizing Effect of Corn Starch by Oxidizing with Hydrogen Peroxide Purpose Obtaining its Basis Adhesive Materials

Abstract:

Currently, native starch as a binder and sizing component is used extremely rarely due to its inherent disadvantages. It has been replaced everywhere with modified starches of various kinds. Studies have shown that polyelectrolyte flocculants can be created on the basis of starch if ionizable groups are introduced into the macromolecules of amylose and amylopectin. At the same time, it was found that the treatment of starch with oxidizing agents (of various natures and activities) can significantly improve the functional properties of native starch when gluing, used for surface sizing, and as a binder for corrugated cardboard. In this work, we also obtained oxidized starch in order to create an adhesive binder on its basis, and only local raw materials were used. It is shown that this method makes it possible to regulate the number of functional groups (oxidizing effect, or OE) in oxidized starch and its paste viscosity within a wide range. This is achieved by changing the molar ratio of the catalyst and oxidizer. During the oxidation process, it is possible to vary the concentration ratios of the oxidizer, catalyst, and conditions. Using FeSO₄ as a catalyzer, the oxidized starch pastes show a less pronounced pseudoplasticity and are characterized by reduced viscosity. The analysis showed that during the oxidation of corn starch with hydrogen peroxide, changes in the supramolecular structure of starch are insignificant: a certain repeated decrease in the level of crystallinity takes place, which leads to a decrease in the gelatinization temperature and also the viscosity of starch pastes.

• Periodical: Advanced Materials Research (Volume 1180)
• Pages: 43-51
• DOI: https://doi.org/10.4028/p-s5XYal
• Online since: August 2024
• Authors: Muzafar Samandarovich Sharipov*, Dildora Murodilloyevna Tillayeva, Nodir Shavkatovich Panoyev
• Keywords: Corn Starch, Crystallization, Functional Group, Gelatinization, Oxidation, Paste, Stability, Viscosity

References

[1] E.V. Novozhilov, D. G. Chukhchin, E. V. Smirnov, E. A. Varakin, I. V. Tyshkunova. Localization and Component Status of Starch Binder in Test Liner. IVUZ. «Lesnoy jurnal». 4 (2013) 111-118.

[2] Q.Wei, H.Zheng, M.Zhu et al. Starch-based surface-sizing agents in paper industry:an overview. J. Paper and Biomaterials, 6(4) (2021) 54-61

[3] Morikawa, K., & Nishinari, K.. Effect of concentration dependence of retrogradation behaviour of dispersions for native and chemically modified potato starch. Food Hydrocolloids 14 (2000) 395–401.

DOI: 10.1016/s0268-005x(00)00021-7

[4] T.M. Hoogstad, G. Konings, P.L. Buwalda, A.J.B. Boxtel, L. Kiewidt, J.H. Bitter, The effect of polydispersity on the conversion kinetics of starch oxidation and depolymerisation, Chemical Engineering Science: X (2019).

DOI: 10.1016/j.cesx.2019.100044

[5] Mikhaylova O.S. The effect of biomodified starch on the strength and deformation properties of cardboard. Phylosophy doctoral thesis. Russia, Kazan. 2018.

[6] B.Han. Properties of oxidized starch prepared by hydrogen peroxide, chlorine dioxide and sodium hypochlorite.Proceedings of the 2016 International Conference on Biomedical and Biological Engineering.Shanghai, China, 2016.

DOI: 10.2991/bbe-16.2016.69

[7] Y.R. Zhang, X.L. Wang, G.M. Zhao, Y.Z. Wang. Preparation and properties of oxidized starch withhigh degree of oxidation. Carbohydrates Polym.87(4)(2012) 2554-2562.

DOI: 10.1016/j.carbpol.2011.11.036

[8] Zh.Qiu, B.Zheng, J.Xu, J.Chen, L.Chen. 3D-printing of oxidized starch-based hydrogels with superior hydration properties. Carbohydrate Polymers.292 (2022) 119686

DOI: 10.1016/j.carbpol.2022.119686

[9] J.P. Wojeicchowski, G.L. Siqueira, L.G. Lacerda, E. Schnitzler and I.M. Demiate, Physicochemical, structural and thermal properties of oxidized, acetylated and dual-modified common bean (Phaseolus vulgaris L.) starch, Food Sci. Technol., 2018, 38, 318–327

DOI: 10.1590/1678-457x.04117

[10] P.A. Tolvanen. Development of an environmentally friendly method of starch oxidation by hydrogen peroxide and a complex water-soluble iron catalyst: Doctoral thesis / Abo Academi University. Abo, 2013. 103 p.

[11] H.C. Genuino, T.G. Meinds, J.O. P. Broekmanet all. Iron Tetrasulfonatophthalocyanine-Catalyzed Starch Oxidation Using H2O2: Interplay between Catalyst Activity, Selectivity, and Stability. ACS Omega. 6 (2021) 13847 −13857.

DOI: 10.1021/acsomega.1c01407

[12] N.Karić, J.Rušmirović, M.Đolić, T.Kovačević, L.Pecić, Željko Radovanović. Preparation and properties of hydrogen peroxide oxidized starch for industrial use. HemijskaIndustrija (Chemical Industry), 74(1), (2020). 25–36

DOI: 10.2298/HEMIND190722004K

[13] Y.Li, K.Zhang, Y-L. Song, F.Cheng, M.Zhou, Y.Lin, P-X. Zhu. Preparation of oxidized corn starch in dr y method assisted by kneader.J.Material Express, 11 (2021)100–106.

DOI: 10.1166/mex.2021.1903

[14] J.O.P. Broekman, H.C. Genuino, H.J. Heeres, J. Brinksma, T.Wielema, P.J. Deuss. Benign catalytic oxidation of potato starch using a homogeneous binuclear manganese catalyst and hydrogen peroxide. Catal. Sci. Technol. 13 (2023) 1233–1243.

DOI: 10.1039/d2cy01629j

[15] H.E. Grommers, D.A. van der Krogt, Chapter 11 - Potato Starch:Production, Modifications and Uses, in Starch (Third Edition), eds. J. BeMiller, R. Whistler, Academic Press, San Diego, 2009, p.511–539.

DOI: 10.1016/b978-0-12-746275-2.00011-2

[16] Y.R. Zhang, S.D. Zhang, X.L. Wang, R.Y. Chen, Y.Z. Wang. Effect of carbonyl content on the properties of thermoplastic oxidized starch. Carbohydrate Polymers, 78(1), (2009) 157–161

DOI: 10.1016/j.carbpol.2009.04.023

[17] C.M. Butrim, T.D. Bildyukevich, N.S. Butrim, T.L. Yurkshtovich. Modification of potato starch under the action of solutions hydrogen peroxide. Chemistry and chemical technology. Izv. universities. v. 58, no.1. (2015) 28-32.

[18] N.L. Vanier, S.L.M. El Halal, A.R.G. Dias, E.da Rosa Zavareze. Molecular structure,functionality and applications of oxidized starches: A review. Food Chemistry. 2017 Apr;221:1546-1559. DOI: 10.1016/j.foodchem.2016.10.138. PMID: 27979128.

DOI: 10.1016/j.foodchem.2016.10.138

[19] A.Arias, G.Feijoo, M.T. Moreira. Evaluation of Starch as an Environmental-Friendly Bio-Resource for the Development of Wood Bioadhesives. Molecules 2021, 26, 4526. https://doi.org/10.3390/ molecules26154526

DOI: 10.3390/molecules26154526

[20] D.Tillayeva, M.Sharipov.Starch oxidation and study of changing its properties for use as an adhesive component for the production of corrugated cardboard. International Scientific Siberian Transport Forum - TransSiberia 2023.Novosibirsk, Russia2023. Proceedings of E3S Web of Conf., 2023. v.402. no.07033.

DOI: 10.1051/e3sconf/202340207033

[21] P.Tolvanen, P.Mäki-Arvela, A.B. Sorokin, T.Salmi, D.Y. Murzin. Kinetics of starch oxidation using hydrogen peroxide as an environmentally friendly oxidant and an iron complex as a catalyst // Chem. Eng. J. 154-1. (2009) 52–59. DOI: 10.1016/j. cej.2009.02.001.

DOI: 10.1016/j.cej.2009.02.001

[22] Sharipov M.S. Study of changes in the properties of starch during oxidation in the creation of a component of adhesive material for surface treatment of paper //Journal of Chemistry and Technologies, 2022. v. 30, n.1, pp.69-78.

[23] J.C. Bustillos-Rodríguez, M.Ordóñez-García, J.M. Tirado-Gallegos and other. Physico-chemical, thermal and rheological properties of native and oxidized starch from corn landraces and hybrids. Food Biophysics, 14(2) (2019) 182–192.

DOI: 10.1007/s11483-019-09569-z

[24] J.M. Pereira, J.A. Evangelho, F.A. Moura, L.C. Gutkoski, A.R.G. Dias, Crystallinity, thermal and gel properties of oat starch oxidized using hydrogen peroxide. International Food Research Journal, 24(4) (2017) 1545–1552.

[25] D.P. Hung, M.V. Phuc, N.A. Hiep, T.V. Thanh, N.T. Vuong. Oxidized maize starch: characterization and its effect on the biodegradable films. Vietnam Journal of Science and Technology, 55 (4) (2017) 395-402.

DOI: 10.15625/0866-708x/54/3/7101

[26] L.H. Garrido, E.Schnitzler, M.E.B. Zortéa, T. de Souza Rocha, I.M. Demiate - Physicochemical properties of cassava starch oxidized by sodium hypochlorite, Journal of Food Science and Technology 51(2014) 2640–2647.

DOI: 10.1007/s13197-012-0794-9

[27] J.Liu, B.Wang, L.Lin, J.Zhang, W.Liu, J.Xie, Y.Ding. Functional, physico-chemical properties and structure of cross-linked oxidized maize starch, Food Hydrocolloids 36 (2014) 45-52.

DOI: 10.1016/j.foodhyd.2013.08.013

[28] R.Sacithraa, M.M. Madhan, S.Vijayachitra. Quantitative Analysis of Tapioca Starch using FT-IR Spectroscopy and Partial Least Squares- International Conference on Innovations In Intelligent Instrumentation, Optimization And Signal Processing "ICIIIOSP-2013", International Journal of Computer Applications, 2013. pp.29-33.