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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 160-162Experimental Investigation on Adsorptive Removal...

Experimental Investigation on Adsorptive Removal of Phenolic Compounds from Aqueous Solution by Cr-Bentonite

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Abstract:

The ability of Cr-bentonite prepared using synthetic wastewater containing chromium was investigated for adsorptive removal of 4-aminophenol and 4-chlorophenol from aqueous solution in a batch system at 25 °C. The physic-chemical parameters including pH value of solution and contact time were studied. The experimental data were analyzed by the Langmuir, Freundlich and Temkin models of sorption. The equilibrium sorption data for 4-aminophenol and 4-chlorophenol were well fitted to Langmuir adsorption isotherm and the monolayer sorption capacity was found to be 26.53 and 23.81 mg/g at 25 °C, respectively. The sorption energy calculated from Dubinin-Redushkevich (D-R) isotherm are 8.31 and 8.20 kJ/mol for the uptake of 4-aminophenol and 4-chlorophenol respectively which indicates that both the sorption processes are chemical in nature. The kinetic data were analyzed using pseudo-first order, pseudo-second order kinetic equation and intraparticle diffusion model. The experimental data fit very well the pseudo-second order kinetic model. Intraparticle diffusion affects 4-aminophenol and 4-chlorophenol uptake. Sorption studies carried out using industrial wastewater samples containing phenolic compounds show that there is significant potential for Cr-bentonite as an adsorbent material for phenollic compounds removal from aqueous solutions.

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Materials Science and Engineering Applications

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Periodical:

Advanced Materials Research (Volumes 160-162)

Pages:

163-170

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.160-162.163

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Online since:

November 2010

Authors:

Hong Zheng, Yang Wang, Peng Liang, Hong Bin Qi

Keywords:

Cr-Bentonite, Isotherm, Kinetic, Phenolic Compound, Sorption

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© 2011 Trans Tech Publications Ltd. All Rights Reserved

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[1] S. Dutta, J.K. Basu and R.N. Ghar: Sep. Purif. Technol. Vol. 21 (2001), p.227.

[2] C.S.A. Sa and R.A.R. Boaventura: Biochem. Eng. J. Vol. 9 (2001), p.211.

[3] K. Karim and S.K. Gupta: Bioresource Technol. Vol. 80 (2001), p.179.

[4] H. El-Hamshary, S. El-Sigeny, M.F.A. Taleb and N.A. El-Kelesh: Sep. Purif. Technol. Vol. 57 (2007), p.329.

DOI: 10.1016/j.seppur.2007.04.013

[5] T.G. Danis, T.A. Albanis, D.E. Petrakis and P.J. Pomonis: Water Res. Vol. 32 (1998), p.295.

[6] S. Rengaraj, S. -H. Moon, R. Sivabalan, B. Arabindoo and V. Murugesan: J. Hazard. Mater. B Vol. 89 (2002), p.185.

[7] K. Abburi: J. Hazard. Mater. Vol. 105(2003), p.143.

[8] S. Al-Asheh, F. Banat and L. Abu-Aitah: Sep. Purif. Technol. Vol. 33 (2003), p.1.

[9] J. -M. Chern and Yi. -W. Chien: Water Res. Vol. 37 (2003), p.2347.

[10] I. Abay, A. Denizli, E. Bişkin and B. Salih: Chemosphere Vol. 61 (2005), p.1263.

[11] N. Kyuya, A. Namba, S.R. Mukaia, H. Tamona, P. Ariyadejwanichb and W. Tanthapanichakoon: Water Res. Vol. 38 (2004), p.1791.

[12] M. Ahmaruzzaman: Adv. J. Colloid Interface Sci. Vol. 143 (2008), p.48.

[13] R. E. Grim: Applied Clay Mineralogy (McGraw-Hill Book Company, New York, 1962).

[14] B.L. Sawliney and S.S. Singh: Clays Clay Miner. Vol. 45 (1997), p.333.

[15] P. Alba, B. Ilaria and C. Gessa: Clays Clay Miner. Vol. 48 (2000), p.19.

[16] P. Alba, B. Ilaria and C. Gessa: Clays Clay Miner. Vol. 51 (2003), p.143.

[17] H. Zheng, D. Liu, Y. Zheng, S. Liang and Z. Liu: J. Hazard. Mater. Vol. 167(2009), p.141.

[18] H. Zheng, Y. Wang, Y. Zheng, H. Zhang, S. Liang and M. Long: Chem. Eng. J. Vol. 143 (2008), p.117.

[19] I. Langmuir: J. Am. Chem. Soc. Vol. 40 (1918), p.1361.

[20] H. Freundlich: Phys. Chem. Soc. Vol. 40 (1906), p.1361.

[21] M.J. Temkin and V. Pyzhev: Acta Physiochim. URSS Vol. 12 (1940), p.217.

[22] M.M. Dubinin, E.D. Zaverina and L.V. Radushkevich: Zh. Fiz. Khim. Vol. 21 (1947), p.1351.

[23] T.K. Naiya, A.K. Bhattacharya and S.K. Das: J. Colloid Interface Sci. Vol. 333 (2009), p.14.

[24] R.E. Treybal: Mass Transfer Operations (McGraw Hill, New York, 1968).

[25] B.H. Hameed, D.K. Mahmoud and A.L. Ahmad: J. Hazard. Mater. Vol. 158 (2008), p.65.

[26] S. Lagergren: Handl. Vol. 24 (1898), p.1.

[27] S. Azizian: J. Colloid Interface Sci. Vol. 276 (2004), p.47.

[28] W.J. Weber Jr. and J.C. Morris: J. Sanit. Eng. Div. Proceed. Am. Soc. Civil Eng. Vol. 89 (1963), p.31.

[29] D. Karadag, Y. Koc, M. Turan and B. Armagan: J. Hazard. Mater. B Vol. 136 (2006), p.604.

[30] K.V. Kumar, V. Ramamurthi and S. Sivanesan: J. Colloid Interface Sci. Vol. 284 (2005), p.14.