Synthesis and Characterization of Novel Ester Functionalized Chiral Ionic Liquids

Abstract:

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Three different chiral ionic liquids, chloride (R)-(+)-β-(1-methyl-imidazole)–propio-nate, (R)-(+)-β-(1-methyl-imidazole)-propionate terafluoroborate and hexafluorophosphate, weresuccessfully synthesized via the nucleophilic substitution reaction and the anion metathesis reaction, with (S)-(-)-2-chloro-propionic acid as the chiral source. Structures of the chiral io-nic liquids have been characterized by the infrared spectroscopy, nuclear magnetic resonancespectroscopy and quantum chemical structure optimization method. These new ionic materia-ls can be used as building blocks for the synthesis of ionic liquids.

Info:

Periodical:

Advanced Materials Research (Volumes 197-198)

Edited by:

Huaiying Zhou, Tianlong Gu, Daoguo Yang, Zhengyi Jiang, Jianmin Zeng

Pages:

471-477

DOI:

10.4028/www.scientific.net/AMR.197-198.471

Citation:

H. L. Wang et al., "Synthesis and Characterization of Novel Ester Functionalized Chiral Ionic Liquids", Advanced Materials Research, Vols. 197-198, pp. 471-477, 2011

Online since:

February 2011

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Price:

$35.00

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