Synthesis and Characterization of Novel Ester Functionalized Chiral Ionic Liquids

Hong Li Wang; Xiao Ling Hu; Ping Guan; Jin Yang Yu; Yi Mei Tang

doi:10.4028/www.scientific.net/AMR.197-198.471

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 197-198Synthesis and Characterization of Novel Ester...

Synthesis and Characterization of Novel Ester Functionalized Chiral Ionic Liquids

Abstract:

Three different chiral ionic liquids, chloride (R)-(+)-β-(1-methyl-imidazole)–propio-nate, (R)-(+)-β-(1-methyl-imidazole)-propionate terafluoroborate and hexafluorophosphate, weresuccessfully synthesized via the nucleophilic substitution reaction and the anion metathesis reaction, with (S)-(-)-2-chloro-propionic acid as the chiral source. Structures of the chiral io-nic liquids have been characterized by the infrared spectroscopy, nuclear magnetic resonancespectroscopy and quantum chemical structure optimization method. These new ionic materia-ls can be used as building blocks for the synthesis of ionic liquids.

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Periodical:

Advanced Materials Research (Volumes 197-198)

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471-477

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.197-198.471

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Online since:

February 2011

Authors:

Hong Li Wang, Xiao Ling Hu, Ping Guan, Jin Yang Yu, Yi Mei Tang

Keywords:

Chirality, Ionic Liquid (IL), Structure Calculation, Synthesis

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