Absorption Equilibrium and Thermodynamics of Fenugreek Yellow Pigment on Macroporous Resins

Article Preview

Abstract:

The adsorption equilibrium and thermodynamics of pigment extracted from Fenugreek after degumming on macroporous resins was investigated under differentinitial concentrations. The suitability of the Freundlich and Langmuir adsorption models to the equilibrium data was investigated. The model fitness was determined by R2 . Thermodynamic parameters were calculated by the Van’t Hof equation.The results showed that Freundlich model gave a better fit of adsorption isotherms than Langmuir models. The positive value of enthalpy(∆H) indicated that the adsorption was endothermic, the negative value of Gibbs free energy (∆G) showed the spontaneous and favoured nature of adsorption, and the entropy(∆S) was positive.The resins LS-46 showed an effective adsorbtion for Fenugreek yellow pigment.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 233-235)

Pages:

91-94

Citation:

Online since:

May 2011

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2011 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Fazili F. R. Y, Hardman R:Phytochemistry, Vol.10 (1971) , p.2497

Google Scholar

[2] N. Garti, Z. Madar, A. Aserin, B. Sternheim:Lebensmittel-Wissenschaft und-Technologie, Vol.30(1997),P.305-311

Google Scholar

[3] Fernandes P B,Doublire J I.Kappa:Carbohydrate Polymers, Vol.16 (1991) , p.253

Google Scholar

[4] Hoffman J, Swensson S:Carbohydr Res, Vol.65(1987) , p.65

Google Scholar

[5] Mirzaeva M R, Rakhmanberdyeva R K, Rakhimov D A:Chem. Nat.Compd, Vol.16(2000) ,p.505

Google Scholar

[6] S. Sohn, D. Kim: Chemosphere Vol.58 (2005) ,p.115–123.

Google Scholar

[7] H.M.F. Freundlich:Physikalische Chemie (Leipzig) , Vol.57A (1906) ,p.385–470.

Google Scholar

[8] I. Langmuir: J. Am. Chem. Soc. ,Vol.38 (11) (1916) ,p.2221–2295.

Google Scholar

[9] M.S. Bilgili:J. Hazard. Mater. ,Vol.137 (2006) ,p.157–164.

Google Scholar

[10] Garcia-Delgado R.A., Cotouelo-Minguez L.M., Rodriguez J.J.: Sep.Sci.Technol.,Vol 27(1992), p.975.

Google Scholar

[11] Li A.M.,Wu H.S. Zhang Q.X.,et al.:Chinese Journal of Polymer Science ,Vol.22(2004),pp.259-267 .

Google Scholar

[12] Zhenguo Zhao,Aixing Fan: ACTA CHIM ICA SINICAVol.52 (1994) ,pp.427-432.(In Chinese)

Google Scholar