Catalytic Function of Fir Char Sulfonic on Styrene Oxide Alcoholysis Reactions

Li Ping Yuan; Yun Chu Hu; Qiong Xun; Du Lin Yin

doi:10.4028/www.scientific.net/AMR.233-235.74

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 233-235Catalytic Function of Fir Char Sulfonic on Styrene...

Catalytic Function of Fir Char Sulfonic on Styrene Oxide Alcoholysis Reactions

Abstract:

Fir char sulfonic acid was prepared by pyrolysis at 350°C and sulfonation from fir processing residues. FT-IR、XRD and XPS analysis showed that fir pyrocarbon retains the benzene ring structure of lignin, with the active hydrogen for sulfonation. And sulfonic groups successfully bonded with the charcoal skeleton. The catalytic properties of fir char sulfonic acid were investigated in the ring-opening addition reactions of styrene oxide with five alcohols. The results showed that fir char sulfonic acid has good catalytic activity in these alcoholysis reactions. The catalyst is also security, stability and environment friendly.

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Advanced Materials Research (Volumes 233-235)

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74-77

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.233-235.74

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Online since:

May 2011

Authors:

Li Ping Yuan, Yun Chu Hu, Qiong Xun, Du Lin Yin

Keywords:

Alcoholysis, Catalyst, Char Sulfonic Acid, FIR, Styrene Oxide

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References

[1] http://www.chinairn.com/yanjiubaogao/5970mucaijiagong.html.

Google Scholar

[2] Moritake Yutaka. Bamboo charcoal pillow. Japan Patent: JP 2001-327383, 2001.

Google Scholar

[3] T.Hirose, B Y Zhao, T.Okabe, et al. Effect of carbonization temperature on the basic properties of woodceramics made from carbonized bamboo fiber and liquefied wood.J Mater Sci, 2002(37): 3453-3458.

Google Scholar

[4] Sugiura Kinji. Charcoal Revolution—Purified Envionment of Earth. Tokyo: Bolcono publishing Company, 1992: 8-92.

Google Scholar

[5] M.Hara, T.Yoshida, A.Takagaki, A carbon material as a strong protonic acid. Angew Chem Int Ed, 2004(43): 2955-2958.

DOI: 10.1002/anie.200453947

Google Scholar

[6] M.Toda, A.Takagaki, M.Olamura, et al. Biodiesel made with sugar catalyst. Nature, 2005, 438(10): 178.

Google Scholar

[7] M.Okamura, A.Takagaki, M.Toda, et al. Acid—catalyzed reactions on flexible polycyclic aromatic carbon in amorphous carbon. Chem Mater, 2006, 18: 3039-3045.

DOI: 10.1021/cm0605623

Google Scholar

[8] A.Takagaki, M.Toda, M.Okamura, et al. Esterification of higher fatty acids by a novel strong solid acid. Catal Today, 2006, 116: 157-161.

DOI: 10.1016/j.cattod.2006.01.037

Google Scholar

[9] D L Yin, Q Xu, L Q Mao.China Patent: ZL 200610032187.9，2008-10-01.

Google Scholar

[10] Q Xu, D L Yin, Z G Yang, , et al Synthesis of chalcones catalyzed bu a novel solid sulfonic acid from bamboo. Catal Commun, 2008, 9:1579-1582.

DOI: 10.1016/j.catcom.2008.01.007

Google Scholar