Trichloromonoxomolybdenum(V): An Efficient Catalyst for the Preparation of Symmetrical Disulfides from Thiols

Abstract:

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Disulfides play important roles in biological and chemical processes. Oxidation of thiols is the most exploited method for disulfide synthesis. Trichloromonoxomolybdenum (V) has been found to be a superior oxotransfer reaction catalyst for the conversion of thiols to the corresponding disulfides in excellent yields under mild reaction conditions. A viable kilo-scale synthesis of the symmetrical disulfide was described. Simple workups, economical and practical are the some advantages of this method.

Info:

Periodical:

Advanced Materials Research (Volumes 233-235)

Edited by:

Zhong Cao, Lixian Sun, Xueqiang Cao, Yinghe He

Pages:

62-65

DOI:

10.4028/www.scientific.net/AMR.233-235.62

Citation:

W. Li et al., "Trichloromonoxomolybdenum(V): An Efficient Catalyst for the Preparation of Symmetrical Disulfides from Thiols", Advanced Materials Research, Vols. 233-235, pp. 62-65, 2011

Online since:

May 2011

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Price:

$35.00

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