Trichloromonoxomolybdenum(V): An Efficient Catalyst for the Preparation of Symmetrical Disulfides from Thiols

Wen Li; Shui Ku Chen; Zhan Hai Huang; Shui Xia Fang; Can Li

doi:10.4028/www.scientific.net/AMR.233-235.62

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Trichloromonoxomolybdenum(V): An Efficient Catalyst for the Preparation of Symmetrical Disulfides from Thiols
p.62

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 233-235Trichloromonoxomolybdenum(V): An Efficient...

Trichloromonoxomolybdenum(V): An Efficient Catalyst for the Preparation of Symmetrical Disulfides from Thiols

Abstract:

Disulfides play important roles in biological and chemical processes. Oxidation of thiols is the most exploited method for disulfide synthesis. Trichloromonoxomolybdenum (V) has been found to be a superior oxotransfer reaction catalyst for the conversion of thiols to the corresponding disulfides in excellent yields under mild reaction conditions. A viable kilo-scale synthesis of the symmetrical disulfide was described. Simple workups, economical and practical are the some advantages of this method.

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Advanced Materials Research (Volumes 233-235)

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62-65

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https://doi.org/10.4028/www.scientific.net/AMR.233-235.62

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Online since:

May 2011

Authors:

Wen Li, Shui Ku Chen, Zhan Hai Huang, Shui Xia Fang, Can Li

Keywords:

Disulfide, Molybdenum (V) Complex, Oxotransfer Reaction, Preparation, Thiol

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