Synthesis and Crystal Structure of 13-cis-Retinoate Aryl Derivatives

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A series of 13-cis-retinoate aryl derivatives were synthesized from 13-cis-retinoic acid and phenols or arylalcohol with dicyclohexylcarbodiimide (DCC) as reagent and 4-dimethylaminopyridine (DMAP) as catalyst. Their structures were characterized by 1H, 13C NMR, IR and MS. The crystal of 3a has been determined by single crystal X-ray diffraction analysis and its molecular structure has been confirmed. Compound 3a belongs to monoclinic system with space group P2 (1)/c, a = 22.235 (3) Å, b = 7.4117 (10) Å, c = 15.990 (2) Å, β = 109.253 (3) °, V = 2487.7 (6) Å3, Z = 4, R = 0.0613, ωR = 0.01437.

Info:

Periodical:

Advanced Materials Research (Volumes 236-238)

Edited by:

Zhong Cao, Yinghe He, Lixian Sun and Xueqiang Cao

Pages:

3037-3040

DOI:

10.4028/www.scientific.net/AMR.236-238.3037

Citation:

W. G. Yi et al., "Synthesis and Crystal Structure of 13-cis-Retinoate Aryl Derivatives", Advanced Materials Research, Vols. 236-238, pp. 3037-3040, 2011

Online since:

May 2011

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$35.00

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