Preparation and Properties of Recycled Polypropylene /Carbon Nanotube Composites

Article Preview

Abstract:

Recycled polypropylene (PP)/carbon nanotube (CNTs) composites with different CNTs fraction were prepared by the melting blend method. The effects of CNTs content on the thermal properties and mechanical properties were mainly investigated. The results show that the thermal degradation of the composites shifts towards higher temperatures as the concentration of CNTs is increased. With increasing CNTs content, tensile strength and elongation at break increase firstly and then decrease. When CNTs content is 3 %, tensile strength and elongation at break are 34.71 and 27.00, respectively. Moreover, a unique tensile rupture characteristic was found by SEM observations, which explained the critical broken theory of the PP/CNTs composites.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

106-110

Citation:

Online since:

July 2011

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2011 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] B.B. Johnson, M.H. Santare and J.E. Novotny: Wear behavior of Carbon Nanotube/High Density Polyethylene composites  . Mechanics of Materials Vol.41 (2009), p.1108.

DOI: 10.1016/j.mechmat.2009.04.003

Google Scholar

[2] S.P. Bao, S.C. Tjong: Mechanical behaviors of polypropylene/carbon nanotube nanocomposites: The effects of loading rate and temperature  . Materials Science and Engineering A Vol. 485 (2008), p.508.

DOI: 10.1016/j.msea.2007.08.050

Google Scholar

[3] W. Bauhofer, J. Z. Kovacs: A review and analysis of electrical percolation in carbon nanotube polymer composites  . Composites Science and Technology Vol.69 (2009), p.1486.

DOI: 10.1016/j.compscitech.2008.06.018

Google Scholar

[4] Z.W. Jiang , R.J. Song and W.G. Bi: Polypropylene as a carbon source for the synthesis of multi-walled carbon nanotubes via catalytic combustion  . Carbon Vol.45 (2007), p.449.

DOI: 10.1016/j.carbon.2006.08.012

Google Scholar

[5] C. Wei, K. Cho and D. Srivastava: Tensile strength of carbon nanotubes under realistic temperature and strain rate. Phys. Rev B: Conden. Matter. Mater. Phys Vol. 67(2003), p.1154.

DOI: 10.1103/physrevb.67.115407

Google Scholar

[6] Y. Mamunya, A. Boudenne and N. Lebovka: Electrical and thermophysical behaviour of PVC-MWCNT nanocomposites  . Composites Science and Technology Vol.68 (2008), p.1981.

DOI: 10.1016/j.compscitech.2007.11.014

Google Scholar

[7] S. Lee, E. Cho and S. Jeon: Rheological and electrical properties of polypropylene composites containing functionalized multi-walled carbon nanotubes and compatibilizers . Carbon Vol.45 (2007), p.2810.

DOI: 10.1016/j.carbon.2007.08.042

Google Scholar

[8] T. Kashiwagi, J. Fagan and J. F. Douglas: Relationship between dispersion metric and properties of PMMA/SWNT nanocomposites  . Polymer Vol.48 (2007), p.4855.

DOI: 10.1016/j.polymer.2007.06.015

Google Scholar

[9] T. Mcnally, P. Pftschke and P. Halley: Polyethylene multiwalled carbon nanotube composites  . Polymer Vol.46 (2005), p.8222.

Google Scholar

[10] Q. Wang, J. Dai and W. Li: The effects of CNT alignment on electrical conductivity and mechanical properties of SWNT/epoxy nanocomposites . Composites Science and Technology Vol.68 (2008), p.1644.

DOI: 10.1016/j.compscitech.2008.02.024

Google Scholar

[11] L. Bokobza: Multiwall carbon nanotube elastomeric composites: A review  . Polymer Vol.48 (2007), p.4907.

DOI: 10.1016/j.polymer.2007.06.046

Google Scholar

[12] Y. Li, H.Shimizu: Toward a Stretchable, Elastic, and Electrically Conductive Nanocomposite: Morphology and Properties of Poly[styrene-b-(ethylene-co-butylene)-b-styrene]/Multiwalled Carbon Nanotube Composites Fabricated by High-Shear Processing. Macromolecules Vol.42 (2009), p.2587.

DOI: 10.1021/ma802662c

Google Scholar

[13] G. Farzi, A. Sohaib and E. Beyou: Effect of radical grafting of tetramethylpentadecane and polypropylene on carbon nanotubes' dispersibility in various solvents and polypropylene matrix . Polymer Vol.50 (2009), p.5901.

DOI: 10.1016/j.polymer.2009.10.020

Google Scholar

[14] S. H. Liao, C. C. Wenga and C. Y. Yena: Preparation and properties of functionalized multiwalled carbon nanotubes/polypropylene nanocomposite bipolar plates for polymer electrolyte membrane fuel cells  . Journal of Power Sources Vol.195 (2010), p.263.

DOI: 10.1016/j.jpowsour.2009.06.064

Google Scholar

[15] I. Alig, D. Lellinger and S. M. Dudkin: Conductivity spectroscopy on melt processed polypropylene–multiwalled carbon nanotube composites: Recovery after shear and crystallization . Polymer Vol.48 (2007), p.1020.

DOI: 10.1016/j.polymer.2006.12.035

Google Scholar

[16] M.Yang, V.Koutsos and M. Zaiser: Size effect in the tensile fracture of single-walled carbon nanotubes with defects. Nanotechnology Vol.18 (2007), p.155708.

DOI: 10.1088/0957-4484/18/15/155708

Google Scholar