In this paper, one-dimensional heat conduction equations is studied, many difference Schemes have been proposed to solve it. In order to find a high accuracy difference scheme in all the methods, we give a numerical experimentation in this paper. by numerical experimentation, a high accuracy difference scheme for solving Heat conduction equations initial boundary value problem is found, according to the truncation error and stability analysis ,we find its accuracy is better-then- third-order in time and space direction. this is a valuable method and better then the others this is a high accuracy difference Scheme. this scheme is a valuable method in Heat conduction and Fluid mechanics.