The Electrochemical Characteristics of Corrosion Scale on P110 Carbon Steel

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Abstract:

The properties of corrosion scale on P110 carbon steel in the saltwater solution containing CO2 have been examined by electrochemical impedance spectroscope (EIS). The change of electrode reaction process on the corrosion scale has been discussed in the present work. It is found that the corrosion rate decreases with the increasing of the experimental time, and the reducing tendency of corrosion rate becomes low as the experimental time was 72 hours, EIS results indicate that the polarization resistance increases gradually and the electrode reaction is controlled by both diffusion and activation in comparison with activation only at the beginning.

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Advanced Materials Research (Volumes 287-290)

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2332-2338

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July 2011

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© 2011 Trans Tech Publications Ltd. All Rights Reserved

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[1] H.C. Kou, D. Landolt, Galvanostatic transient study of anodic film formation on iron in concentrated chloride media, Corros. Sci. 16 (1976) 915-922.

DOI: 10.1016/s0010-938x(76)80011-x

Google Scholar

[2] R.D. Grimm, D. Landolt, Salt films formed during mass transport controlled dissolution of iron-chromium alloys in concentrated chloride media, Corros. Sci. 36 (1994) 1847-1868.

DOI: 10.1016/0010-938x(94)90023-x

Google Scholar

[3] H.S. Isaaca, J.H. Cho, M.L. Rivers, S.R. Sutton, In situ X-Ray microprobe study of salt layers during anodic dissolution of stainless steel in chloride solution, J Electrochem. Soc. 142 (1995) 1111-1118.

DOI: 10.1149/1.2044138

Google Scholar

[4] R.D. Grimm, A. C. West and D. Landolt, AC impedance study of anodically formed salt films on iron in chloride solutions, J Electrochem. Soc. 139 (1992) 1622-1629.

DOI: 10.1149/1.2069467

Google Scholar

[5] J.R. Park, D.D. Macdanald, Impedance studies of the growth of porous magnetite films on carbon steel in high temperature aqueous systems, Corros. Sci. 23 (1983) 295-315.

DOI: 10.1016/0010-938x(83)90063-x

Google Scholar

[6] L.K. Gatzky, R.H. Hausler, "A novel correlation of tubing corrosion rates and gas production rates", in R.H. Hausler, H.P. Godard (Eds). Advanced in CO2 corrosion, Vol. 1, pp.87-90.

Google Scholar

[7] L.G.S. Gray, B.G. Anderson, M.J. Danysh,et al. Mechanism of carbon steel corrosion in brines containing dissolved carbon dioxide at pH4, Corrosion/89, Paper No.464. (Houston, TX: NACE. International, 1989).

Google Scholar

[8] M. Stern, The electrochemical behavior, including hydrogen over-voltage, of iron in acid environments, J.Electrochem.Soc. 102 (1955) 609-616.

DOI: 10.1149/1.2429923

Google Scholar

[9] G. Schmitt, B. Rothman, "Studies on the Corrosion Mechanism of Unalloyed Steel in oxygen-tree carbon dioxide solutions, part II. kinetics of iron dissolution in: R.H. Hausler, H. P. Giddard (Eds), Advances in CO2 Corrosion, Vol. 1, pp.163-172.

Google Scholar

[10] C.N. Cao, J.Q. Zhang, An introduction to electrochemical impedance spectroscopy. Beijing: Science press, 2002.

Google Scholar

[11] Srdjan Nesic, Kun-Lin John Lee and Vukan Ruzic, The effect on CO2 corrosion of mild steel, Corrosion/2002, Paper No.02237. (Houston, TX: NACE. International, 2002).

Google Scholar

[12] C.N. Cao, Corrosion electrochemistry. Beijing: Chemical industry press 1994.

Google Scholar

[13] F.J. Mansfeld, Use of electrochemical impedance spectroscopy for the study of corrosion protection by polymer coatings, Appl. Electrochem. 25 (1995) 187-202.

DOI: 10.1007/bf00262955

Google Scholar

[14] I. Frateur, C. Deslouis, M.E. Orazem, B. Tribollet, Modeling of the cast iron/drinking water system by electrochemical impedance spectroscopy, Electrochem. Acta 44 (1999) 4345-4356.

DOI: 10.1016/s0013-4686(99)00150-4

Google Scholar

[15] K. Juttner, W.J. Lorenz, M.W. Kendig, F.J. Mansfeld, Electrochemical Impedance Spectroscopy on 3-D Inhomogeneous Surfaces, J. Electrochem. Soc. 135 (1988) 332-339.

DOI: 10.1149/1.2095610

Google Scholar

[16] M.C. Li, C.L. Zeng, H.C. Lin, C.N. Cao, Corrosion behavior for 316 stailess steel in dilute hydrochloric acid solutions aerated with hydrogen gas, Acta Metallurgica Sinica 38 (2002) 1287-1291.

Google Scholar