Mangnese Dioxide Nano-Crystal as Catalyst to Remove Formaldehyde

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The purification technology and material of indoor formaldehyde is a hot spot in the field of material at present. In this paper, MnSO4, KMnO4, NaOH and H2O2 etc. are used to make manganese dioxide nanocrystal with the method of liquid precipitation. X-ray diffraction (XRD), scanning electron microscope (SEM) and transmission electron microscopy (TEM) were used to characterize the structure and properties. The results show that the products are nano-crystals of γ- MnO2 and δ-MnO2. The catalyze oxidation of formaldehyde using bothγ- MnO2 and δ-MnO2 as catalysts was investigated; and acetyl acetone method was used to characterize formaldehyde chroma. The catalytic ability ofγ-MnO2 nanocrystal to catalyze formaldehyde oxidation is better than that ofδ-MnO2.

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147-152

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July 2011

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© 2011 Trans Tech Publications Ltd. All Rights Reserved

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[1] Yoshika S, Atsushi N. Removal of formaldehyde from indoor air by passive type air-cleaning materials [J]. Atmos Environ, 2001, 35: 2001-(2007).

DOI: 10.1016/s1352-2310(00)00465-9

Google Scholar

[2] Yoshika S, Oxidative decomposition of formaldehyde by metal oxides at room temperature [J]. Atmos Environ, 2002, 36: 5543-5547.

DOI: 10.1016/s1352-2310(02)00670-2

Google Scholar

[3] LouYingwei. Nano MnO2 preparation and electrochemical properties [D]. Hangzhou, Zhejiang Polytechnic University, (2004).

Google Scholar

[4] Li-qing. The preparation and application research of nanometer manganese dioxide [D]. Changsha: Zhongnan University, (2005).

Google Scholar

[5] WangWenliang, Li Dongsheng, WangJiwu, etc. A new preparation method of nanometerγ-MnO2- ultrasound irradiation oxidation and reduction method [J] Chemistry journal, 2004, 62 (16) : 1557 - 1560.

Google Scholar

[6] Qirihema. The preparation, characterization and performance study of nano oxidation nickel and manganese oxide, [j] Inner Mongolia: Inner Mongolia Industry University, (2006).

Google Scholar

[7] Wang Li. Preparation and characterization of new manganese oxide of [D]. Guangzhou: South China Normal University, (2007).

Google Scholar

[8] Feng Q, Yanagisawa K, Yamasaki N. Synthesis of birnessite-type potassium manganese oxide [J]. J Mater Sci Lett, 1997, 16: 110-112.

Google Scholar

[9] Huang Hangkang. The preparation, structure characterization of manganese dioxide and its electrochemical properties [j]. Xiamen: Xiamen University, (2007).

Google Scholar

[10] Boehm H P. Surface oxides on carbon and their analysis: a critical assessment [J]. Carbon, 2002, 40: 145-149.

DOI: 10.1016/s0008-6223(01)00165-8

Google Scholar

[11] Li Li. The quantum chemistry research on MnO2 catalytic oxygen reduction [j]. Chongqing: Chongqing University, (2004).

Google Scholar

[12] Deng Jingfa. Catalysis Principle Introduction [M]. Jilin: Jilin science &technology press, (1984).

Google Scholar

[13] Sukriti B. Kanungo. Physicochemical properties of MnO2 and MnO2-CuO and their relationship with the catalytic activity for H2O2 decomposition and CO oxidation [J]. J Catal, 1979, 58(3): 419-435.

DOI: 10.1016/0021-9517(79)90280-x

Google Scholar