Preparation of Recyclable Pd(II) Organometal Catalyst with Bicontinuous Cubic Ia3d Mesostructure for Water-Medium Organic Reaction

Di Di Yang; Feng Xia Zhu; He Xing Li

doi:10.4028/www.scientific.net/AMR.356-360.407

Paper Titles

Synthesis of Coal Fly Ash Zeolite with Copper Oxide Load for Acid Red GR Wastewater Treatment
p.391

Preparation of Copper Oxide Loaded Activated Carbon by Waste Sawdust for Acid Red GR Wastewater Treatment
p.395

A Single-Step Synthesis of Rutile TiO₂ Dendrite Crystal with Sonication
p.399

Sonochemical Synthesis of Nitrogen Doped TiO₂ at a Low Temperature
p.403

Preparation of Recyclable Pd(II) Organometal Catalyst with Bicontinuous Cubic Ia3d Mesostructure for Water-Medium Organic Reaction
p.407

Effects of MgO and Calcining Temperature on the Structure of Aluminum Titanate Synthesized from Industrial Waste
p.411

Research on the Application of Photocatalytic Coating Material with Function of Decomposing Vehicle Exhaust on Road Collision Wall
p.415

Removeal of Arsenic(III) from Water by Using a New Class of Zero-Valent Iron Modified Mesoporous Silica Molecular Sieves SBA-15
p.423

Use of Microcrystalline Cellulose Prepared from Cotton Fabric Waste to Prepare Poly(butylene succinate) Composites
p.430

HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 356-360Preparation of Recyclable Pd(II) Organometal...

Preparation of Recyclable Pd(II) Organometal Catalyst with Bicontinuous Cubic Ia3d Mesostructure for Water-Medium Organic Reaction

Abstract:

A heterogenous Pd(II) organometal catalyst with bicontinuous cubic Ia3d mesostructure was synthesized by surfactant-directed co-condensation of Pd[PPh₂(CH₂)₂Si(OCH₂CH₃)₃]₂Cl₂ and (CH₃CH₂O)₃SiPhSi(OCH₂CH₃)₃. In water medium Sonogashira reaction, the as-prepared Pd(II)-PMO-KIT-6 exhibited higher catalytic activity than the corresponding Pd(II)-KIT-6 catalyst and could be used repetitively for more than 4 times, which could reduce the cost and even diminish the environmental pollution from heavy metallic ions, showing a good potential in industrial applications.

You might also be interested in these eBooks

Progress in Environmental Science and Engineering (ICEESD)

View Preview

Info:

Periodical:

Advanced Materials Research (Volumes 356-360)

Pages:

407-410

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.356-360.407

Citation:

Cite this paper

Online since:

October 2011

Authors:

Di Di Yang, Feng Xia Zhu, He Xing Li

Keywords:

Bicontinuous Cubic Mesostructure, Immobilzation of Pd(II) Organometal, Recyclable Catalyst, Water-Medium Organic Reactions

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

References

[1] W.R. Roush: Comprehensive Organic Synthesis; Pergamon Press: New York, 1991.

Google Scholar

[2] S. Narayan, J. Muldoon, M.G. Finn, V.V. Fokin, H.C. Kolb, K.B. Sharpless: Angew. Chem. Int. Ed. Vol. 44 (2005), p.3275.

DOI: 10.1002/anie.200462883

Google Scholar

[3] Z. Lu, E. Lindner, H.A. Mayer: Chem. Rev. Vol. 102 (2002), p.3543.

Google Scholar

[4] W.P. Guo, F. Kleitz, K. Choab, R. Ryoo: J. Mater. Chem. Vol. 20 (2010), p.8257.

Google Scholar

[5] X.H. Tan, B. Shen, W. Deng, H. Zhao, Q.X. Guo: J. Org. Lett. Vol. 5 (2003), p.1833.

Google Scholar

[6] Y. Wan, D.Q. Zhang, C.M. Feng, J. Chen, H.X. Li: Chem. An. Asian J. Vol. 2 (2007), p.875

Google Scholar

[7] H.X. Li, F. Zhang, H. Yin, Y. Wan, Y.F. Lu: Green Chem. Vol. 9 (2007), p.500.

Google Scholar

[8] M. Burleigh, A. Michael, M. Markowitz, S. Spector, B. Gaber: J. Phys. Chem. B Vol. 105 (2001), p.9935.

Google Scholar

[9] S. Inagaki, S. Guan, T. Ohsuna, O. Terasaki: Nature Vol. 416 (2002), p.304.

Google Scholar

[10] P.F.W. Simon, R. Ulrich, H.W. Spiess, U. Wiesner: Chem. Mater. Vol. 13 (2001), p.3464.

Google Scholar