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Syntheses, Crystal Structures and Luminescence of Two Coordination Polymers Based on Isophthalic Acid and 2-(3-Pyridyl)benzimidazole Ligands

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Abstract:

Two new coordination polymers, [Zn(PyHBIm)2(IPA)]•3H2O (1), [Cd(PyHBIm)(IPA)(H2O)2]•2H2O (2), were synthesized under hydrothermal conditions based on 2-(3-pyridyl)benzimidazole (3-PyHBIm) and isophthalic acid (IPA). The complexes were characterized by single crystal X-ray diffraction. They contain simple 1D chains and can be assembled into a 3D network through aromatic π–π stacking interactions and hydrogen bonding interactions. Their luminescent properties were studied in the solid state at room temperature.

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Periodical:

Advanced Materials Research (Volumes 399-401)

Pages:

896-899

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.399-401.896

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Online since:

November 2011

Authors:

Ke Fen Yue, Shuang Zhao, Rui Li Zhao, Yao Yu Wang

Keywords:

Coordination Polymer, Crystal Structure, Luminescent Properties

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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