Composition of Hydrogenated Vacuum Gas Oil Analysis by Gas Chromatography Mass Spectrometry

Article Preview

Abstract:

Many attempts are made to obtain the composition of vacuum gas oil (VGO) but the molecular composition of hydrogenated vacuum gas oil (HVGO) has not been studied in detail. HVGO is used as a feed in fluid catalytic cracking (FCC) to produce more environmentally friendly gasoline. This paper reports the presence of linear alkyl cyclohexanes (LACHs) in HVGO. Some LACHs were found in HVGO distillates of boiling point range of 370°C-550°C. Complete molecular composition was analyzed using gas chromatography mass spectrometry (GC-MS). HVGO contains LACHs from C7 to C32 and n-paraffins from C5 to C38. Open chain hydrocarbons are the major constituents of all the six samples of HVGO. Aromatic compounds were also identified but their concentration was very low. Sulfur contents were about 0.26% by weight percentage (wt).The present paper focuses on development of method for qualitative and quantitative determination of LACHs in HVGO samples using GC-MS analysis method.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 455-456)

Pages:

706-710

Citation:

Online since:

January 2012

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] J. M. Arandes, I. Torre, M. J. Azkoiti, J. Erena, M. Olazar, and J. Bilbao Energy Fuels, 2009, 23: 4215-4223.

DOI: 10.1021/ef9002632

Google Scholar

[2] S. Brunet, D. May, G. Perot, C. Bounchy, and F. Diehl, Appl Catal A Gen, 2005, 278: 143-172.

Google Scholar

[3] J. Ancheyta, and S. Rodriguez, Energy Fuels, 2002, 16: 718-723.

Google Scholar

[4] A. Fafet, J. Bonnard, and F. Prigent, Oil Gas Sci Technol, 1999, 54: 453-462.

Google Scholar

[5] A. A. Al-Hajji, H. Muller, and O. R. Koseoglu, Oil Gas Sci Technol, 2008, 63: 115-128.

Google Scholar

[6] C. S. Hsu, Z. Liang, and J. E. Campana, Anal Chem, 1994, 66: 850-855.

Google Scholar

[7] L. A. Stanford, S. Kim, R. P. Rodgers, and A. G. . Marshall, Energy Fuels, 2006, 20: 1664-1673.

Google Scholar

[8] T. Dutriez, et al. J Chromatogr A, 2009, 1216: 2905-2912.

Google Scholar

[9] A. A. Lappas, D. Patiaka, D. Ikonomou, and I. A. Vasalos. Ind Eng Chem Res, 1997, 36: 3110-3115.

DOI: 10.1021/ie960586r

Google Scholar

[10] R. B. Johns, et al, Geochim Cosmochim Acta, 1966, 30: 1191-1222.

Google Scholar

[11] H. I. Rubinstein, O. P. Strausz, Geochim Cosmochim Acta, 1979, 43: 1387-1392.

Google Scholar