Research on Mineral Formation Mechanism of Pulverized Coal Combustion Boiler Co-Generating Q-Phase Cement Clinker

Article Preview

Abstract:

Conduct test of 2CaO•Al2O3•SiO2 transformed into Q-phase mineral with analytical reagent CaO, SiO2, Al2O3 and MgO in library high-temperature furnace. And carry out experimental investigation on the mineral formation rule of co-generation Q-phase cement clinker on two-section multiphase reaction test stand simulating pulverized coal combustion boiler based on the test. It was found that: 2CaO•Al2O3•SiO2 may generate Q-phase mineral with hydration activity together with appreciated amount of CaO and MgO; experimental coal sort in reasonable ratio may co-generate cement clinker with main mineral sort of 2CaO•SiO2 and Q-phase mineral. Thermodynamic analysis on mineral formation reaction shows that, in Yanzhou coal co-generating Q-phase cement clinker, the most probably occurring is the direct synthesis reaction of 2CaO•Al2O3•SiO2, followed by 2CaO•SiO2 direct synthesis reaction and the Q-phase indirect synthesis reaction comes last according to chemical composition of clinkers.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 512-515)

Pages:

1687-1691

Citation:

Online since:

May 2012

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] WANG W L,LUO Z Y,SHI Z L ,et al. Preliminary study on zero solid waste generation from pulverized coal combustion [J].Waste Management and Research, 2003, 21(3): 243-248.

DOI: 10.1177/0734242x0302100308

Google Scholar

[2] WANG Wenlong,SHI Zhenglun,LUO Zhongyang ,et al. The status and perspective of cement generation in coal fired power boilers[J]. Journal of Zhejiang University: Engineering Science, 2003, 37(2):225-230.

Google Scholar

[3] WANG Lijiu, YANG Xinchao, CAO Mingli. Feasibility Study on the technology of joint production of coal-burning electricity generation and cement manufacture[J]. World Sci-tech R & D, 2004,26(5):10-17.

Google Scholar

[4] PARKER T W, RYDER J F. The quaternary phase in high alumina cement [C]// 3rd International Congress on the Chemistry of Cement. London, England: [s.n.], 1954:485-489.

Google Scholar

[5] GLASSER F R, MARR J.Quaternary phase in the system CaO-MgO-Al2O3-SiO2 [J]. Trans Br Ceram Soc, 1975, 74:113-119.

Google Scholar

[6] Thinh T P, et al. Estimation of ideal gas heat capacities of hydrocarbon from Gr oup contribution techniques [J].Ind.Eng.Chem.Process Des. 1976, 10,576-582.

DOI: 10.1021/i260040a026

Google Scholar

[7] Benson S W, et al.Additive rules for the estimation of thermochemical properties [J].Chem. Rev., 1969, 69: 279-324.

Google Scholar

[8] Johack K G.A unified approach to physical property estimation using multivariate statistical techniques [D].Thesis of Massachuetts Institute of technology, Cam bridge, MA, June 1984.

Google Scholar

[9] M H isham.Thermochemisty of inorganic solids.5. Emperical relations among en thalpies of formation of oxides, carhonates, sulfates hydroxides and nitrates [J].J. Chem. Eng. Data, 1987, 32(2):243-247.

DOI: 10.1021/je00048a032

Google Scholar

[10] Golam Moslafa, et al. Prediction of standard heats and Gibbs free energies of for mation of solid inorganic salts from Group contributions [J].Ind. Eng.Chem Res, 1995, 34:4577-4582.

DOI: 10.1021/ie00039a053

Google Scholar

[11] Kuhaschewski C.Unal H.An emprirical of the heat capcities of inorganic com pounds [J].High temperatures-high pressures, 1977, 9(4):1-12.

Google Scholar