Study on Preparation of 1H,1H,2H-Heptadecafluorodecene

Xiang Cheng Wang; Geng Chang; Ai Qing Fu

doi:10.4028/www.scientific.net/AMR.634-638.2332

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 634-638Study on Preparation of...

Study on Preparation of 1H,1H,2H-Heptadecafluorodecene

Abstract:

1H,1H,2H,2H-1Iodide-Perfluorodecane was synthesized use perfluorooctyl iodide and ethylene as materials, then reacted with sodium methoxide /methanol to gain 1H,1H,2H-Heptadecafluorodecene. Influence factors such as kinds of solvents, raw material configuration, concentration and time in the process of dehydrogen iodide were studied mainly. Optimization was using 1,1,2-Trichloro-1,2,2-trifluoroethane as solvent, sodium methoxide /methanol (2mol/L ), 1H,1H,2H,2H-1Iodide-Perfluorodecane( M1 ): sodium methoxide( M2 ) =1:2, reacted 12 hours, the yield of 1H,1H,2H-Heptadecafluorodecene was up to 80%.

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Periodical:

Advanced Materials Research (Volumes 634-638)

Pages:

2332-2335

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.634-638.2332

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Online since:

January 2013

Authors:

Xiang Cheng Wang, Geng Chang, Ai Qing Fu

Keywords:

1H,1H,2H,2H-1Iodide-Perfluorodecane, 1H,1H,2H-Heptadecafluorodecene, Perfluorooctyl Iodide, Synthesis

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References

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