Study on Preparation of 1H,1H,2H-Heptadecafluorodecene

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1H,1H,2H,2H-1Iodide-Perfluorodecane was synthesized use perfluorooctyl iodide and ethylene as materials, then reacted with sodium methoxide /methanol to gain 1H,1H,2H-Heptadecafluorodecene. Influence factors such as kinds of solvents, raw material configuration, concentration and time in the process of dehydrogen iodide were studied mainly. Optimization was using 1,1,2-Trichloro-1,2,2-trifluoroethane as solvent, sodium methoxide /methanol (2mol/L ), 1H,1H,2H,2H-1Iodide-Perfluorodecane( M1 ): sodium methoxide( M2 ) =1:2, reacted 12 hours, the yield of 1H,1H,2H-Heptadecafluorodecene was up to 80%.

Info:

Periodical:

Advanced Materials Research (Volumes 634-638)

Edited by:

Jianmin Zeng, Hongxi Zhu and Jianyi Kong

Pages:

2332-2335

Citation:

X. C. Wang et al., "Study on Preparation of 1H,1H,2H-Heptadecafluorodecene", Advanced Materials Research, Vols. 634-638, pp. 2332-2335, 2013

Online since:

January 2013

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$41.00

[1] B. Ameduri, B. Boutevin et al. Hybrid Organic-inorganic Gels Containing Perfluoro-alkyl Moieties[J], J. Fluorine. Chem. 2000, 104: 185~194.

DOI: https://doi.org/10.1016/s0022-1139(00)00211-6

[2] B. Ameduri, B. Boutevin et al. Synthesis and Properties of Fluorosilicon-containing Polybutadienes by Hydrosilylation of Fluorinated Hydrogenosilanes[J]. J. Fluorine. Chem. 1995, 74: 191~197.

DOI: https://doi.org/10.1016/0022-1139(95)03286-m

[3] Z.V. Belyakova, E.A. Chernyshev, P. A. Storozhenko. et. al. Hydrosilylation of Cyclohexene and Allyl Chloride with Trichloro-, Dichloro(methyl)-, and Chlorodimethylsilanes in the Presence of Pt(0) Complexes[J]. Russian Journal of General Chemistry. 2006. 76(6): 967~972.

DOI: https://doi.org/10.1134/s1070363206060120

[4] Dong Euy Jung, Joon Soo Han, Bok Ryul Yoo. Thermal Hydrosilylation of Olefin with Hydrosilane[J]. J. Organometallic. Chem. 2011. 696: 3687~3692.

DOI: https://doi.org/10.1016/j.jorganchem.2011.08.019