Study on Preparation of 1H,1H,2H-Heptadecafluorodecene
1H,1H,2H,2H-1Iodide-Perfluorodecane was synthesized use perfluorooctyl iodide and ethylene as materials, then reacted with sodium methoxide /methanol to gain 1H,1H,2H-Heptadecafluorodecene. Influence factors such as kinds of solvents, raw material configuration, concentration and time in the process of dehydrogen iodide were studied mainly. Optimization was using 1,1,2-Trichloro-1,2,2-trifluoroethane as solvent, sodium methoxide /methanol (2mol/L ), 1H,1H,2H,2H-1Iodide-Perfluorodecane( M1 ): sodium methoxide( M2 ) =1:2, reacted 12 hours, the yield of 1H,1H,2H-Heptadecafluorodecene was up to 80%.
Jianmin Zeng, Hongxi Zhu and Jianyi Kong
X. C. Wang et al., "Study on Preparation of 1H,1H,2H-Heptadecafluorodecene", Advanced Materials Research, Vols. 634-638, pp. 2332-2335, 2013