Surface Morphology of Seeded Nanostructured ZnO on Silicon by Sol-Gel Technique

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Nanostructured ZnO as a seeded was prepared by sol-gel technique on p-type silicon in various low molarities. Zinc acetate, Diethanolamine (DEA), and isopropyl were use as starting material, stabilizer, and solvent respectively. Atomic Force Microscopy (AFM) analysis shows smooth surface and uniform layer were produced in low molarities of precursor. The surface morphology of nanostructured ZnO was analyzed by Field Emission Scanning Electron Microscopic (FESEM). It is found that the nanostructured ZnO were successfully deposited on the silicon substrate with size ~10 nm to ~35 nm. Photoluminescence spectroscopy was employed to study the band gap in room temperature. It shows that very low intensity of PL in 0.05m and 0.1 m. PL intensity become more obvious starting from 0.15 m of precursor concentration.

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265-271

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March 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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[1] S. Baruah, J. Dutta, Effect of seeded substrates on hydrothermally grown ZnO nanorods, Journal of Sol-Gel Science and Technology 50 (2009) 456-464.

DOI: 10.1007/s10971-009-1917-2

Google Scholar

[2] K. Mirabbaszadeh, M. Mehrabian, Synthesis and properties of ZnO nanorods as ethanol gas sensors, Physica Scripta 85 (2012) 035701.

DOI: 10.1088/0031-8949/85/03/035701

Google Scholar

[3] Y. H. Kim, N. S. Baek, K. H. Kim, S. -D. Jung, Simplifying patterning process of ZnO nanowires by one step development and etching process, Journal of Sol-Gel Science and Technology (2012).

DOI: 10.1007/s10971-012-2858-8

Google Scholar

[4] M. H. Mamat, Z. Khusaimi, M. Z. Musa, M. Z. Sahdan, M. Rusop, Novel synthesis of aligned Zinc oxide nanorods on a glass substrate by sonicated sol–gel immersion, Materials Letters. 64 (2010) 1211-1214.

DOI: 10.1016/j.matlet.2010.02.053

Google Scholar

[5] K. L. Foo, M. Kashif, U. Hashim, S. M. U. Ali, M. Willander, Study of ZnO Thin Film on Silicon Substrate by Sol-Gel Spin Coating Method for Bio-Medical Application, presented at the 2012 International Conference on Biomedical Engineering (ICoBE), Penang, (2012).

DOI: 10.1109/icobe.2012.6179009

Google Scholar

[6] Z. Khusaimi, S. Amizam, H. A. Rafaie, F. W. M. Noor, M. H. Mamat, N. A. Ghani, N. Yusoff, N. Abdullah, S. Abdullah, M. Rusop, A Surface Morphology Study On The Effect Of Annealing Temperature To Nanostructured ZnO And Its Reaction Mechanism In Solution Method, AIP Conference Proc. 1136 (2009).

DOI: 10.1063/1.3160258

Google Scholar

[7] S. A. Kamaruddin, K. -Y. Chan, H. -K. Yow, M. Zainizan Sahdan, H. Saim, D. Knipp, Zinc oxide films prepared by sol–gel spin coating technique, Applied Physics A 104 (2010) 263-268.

DOI: 10.1007/s00339-010-6121-2

Google Scholar

[8] C. Shaoqiang, Z. Jian, F. Xiao, W. Xiaohua, L. laiqiang, S. Yanling, X. Qingsong, W. Chang, Z. Jianzhong, and Z. Ziqiang, Nanocrystalline ZnO thin films on porous silicon/silicon substrates obtained by sol–gel technique, Applied Surface Science 241 (2005).

DOI: 10.1016/j.apsusc.2004.07.040

Google Scholar

[9] S. -H. Baek, S. -B. Kim, J. -K. Shin, J. Hyun Kim, Preparation of hybrid silicon wire and planar solar cells having ZnO antireflection coating by all-solution processes, Solar Energy Materials and Solar Cells 96 (2012) 251-256.

DOI: 10.1016/j.solmat.2011.10.007

Google Scholar

[10] M. Hafiz Mamat, Z. Khusaimi, and M. Rusop Mahmood, Optical Properties of Nanostructured Zinc Oxides Deposited on Silicon Substrates, Defect and Diffusion Forum 312-315 (2011) 1132-1136.

DOI: 10.4028/www.scientific.net/ddf.312-315.1132

Google Scholar

[11] C. Li, G. Fang, F. Su, G. Li, X. Wu, X. Zhao, Synthesis and photoluminescence properties of vertically aligned ZnO nanorod–nanowall junction arrays on a ZnO-coated silicon substrate, Nanotechnology 17 (2006) 3740-3744.

DOI: 10.1088/0957-4484/17/15/021

Google Scholar

[12] M. S. Kim, G. Nam, J. -S. Son, J. -Y. Leem, Photoluminescence studies of ZnO thin films on porous silicon grown by plasma-assisted molecular beam epitaxy, Current Applied Physics (2012).

DOI: 10.1016/j.cap.2012.05.016

Google Scholar

[13] J. Li, S. Srinivasan, G. N. He, J. Y. Kang, S. T. Wu, and F. A. Ponce, Synthesis and luminescence properties of ZnO nanostructures produced by the sol–gel method, Journal of Crystal Growth 310 (2008) 599-603.

DOI: 10.1016/j.jcrysgro.2007.11.054

Google Scholar

[14] M. H. Mamat, N. I. Ishak, Z. Khusaimi, M. M. Zahidi, M. H. Abdullah, S. Muhamad, N. D. M. Sin, M. R. Mahmood, Thickness-Dependent Characteristics of Aluminium-Doped Zinc Oxide Nanorod-Array-Based, Ultraviolet Photoconductive Sensors, Japanese Journal of Applied Physics 51 (2012).

DOI: 10.7567/jjap.51.06ff03

Google Scholar

[15] M. H. Mamat, Z. Khusaimi, M. M. Zahidi, S. A. Bakar, Y. M. Siran, S. A. M. Rejab, A. J. Asis, S. Tahiruddin, S. Abdullah, and M. R. Mahmood, Controllable Growth of Vertically Aligned Aluminum-Doped Zinc Oxide Nanorod Arrays by Sonicated Sol–Gel Immersion Method depending on Precursor Solution Volumes, Japanese Journal of Applied Physics 50 (2011).

DOI: 10.1143/jjap.50.06gh04

Google Scholar

[16] M. H. Mamat, Z. Khusaimi, M. M. Zahidi, and M. R. Mahmood, Performance of an Ultraviolet Photoconductive Sensor Using Well-Aligned Aluminium-Doped Zinc-Oxide Nanorod Arrays Annealed in an Air and Oxygen Environment, Japanese Journal of Applied Physics 50 (2011).

DOI: 10.1143/jjap.50.06gf05

Google Scholar

[17] S. S. Shariffudin, M. Salina, S. H. Herman, M. Rusop, Effect of Film Thickness on Structural, Electrical, and Optical Properties of Sol-Gel Deposited Layer-by-layer ZnO Nanoparticles, Transactions on Electrical and Electronic Materials 13 (2012).

DOI: 10.4313/teem.2012.13.2.102

Google Scholar

[18] D. Qiu, P. Yu, Y. Jiang, H. Wu, Fabrication of ZnO Nanoneedle/nanocolumn Composite Films and Annealing Induced Improvement in Their Microstructural and Photoluminescene Characteristics, J. Mater. Sci. Technol. 22 (2006) 541-545.

Google Scholar

[19] K. Shin, K. Prabakar, W. -P. Tai, J. -H. Oh, C. Lee, The Structure and Photoluminescene Properties of Al : ZnO/Porous Silicon, Journal of the Korean Physical Society 45 (2004) 1288-1291.

Google Scholar

[20] N. Shakti, P. S. Gupta, Structural and Optical Properties of Sol-gel Prepared ZnO Thin Film, Applied Physics Research 2 (2010) 19-28.

DOI: 10.5539/apr.v2n1p19

Google Scholar