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Preparation and Luminescence Properties of ZnO–SiO2–B2O3–Na2O:Sm3+ Glass

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Abstract:

The 40ZnO-30SiO2-20B2O3-10Na2O:Sm3+ glass was prepared by high-temperature melting method. The structure and composition of the glass matrix was investigated by Infrared spectrum (IR). The absorption, excitation and emission spectra of the samples were tested, and the results showed that the glass can emit orange shade under light excitation. The emission peaks at 565nm, 604nm and 650nm wavelength were corresponding to the 4G5/26H5/2, 4G5/26H7/2 and 4G5/26H9/2 transition emission of Sm3+, while the 4G5/26H7/2 transition emission was the strongest. So the best Sm3+-doping molar concentration was 0.4%. The spectroscopic properties indicated that 40ZnO-30SiO2-20B2O3-10Na2O: Sm3+ was expected to become a new conversion material.

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Periodical:

Advanced Materials Research (Volumes 750-752)

Pages:

914-918

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.750-752.914

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Online since:

August 2013

Authors:

Yong Qiang Zhang, Quan Sheng Liu, Mei Li

Keywords:

Concentration Quenching, Conversion Materials, Sm3+ Ions, Spectroscopy

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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