The Feasibility of Fluorine Ammonium Compounds for Sandstone Formation Matrix Acidizing: Laboratory Study and Discussion

Article Preview

Abstract:

As a preferred technology to enhance oilfield energy production, well stimulation has and will continue to have an important role in fulfilling the worlds future energy needs. Mud acid is a conventional acid system that reacts with most injurants and removes damages. However, fast reaction rate with minerals will lead to high leak-off velocity, great possibility of secondary and tertiary precipitation, lower effect of corrosion inhibitor in high temperature as well as short efficient operating range. Therefore, new kinds of acid system are required to cope with these problems above. This paper proposed three acid system with the similarity of fluorine ammonium compounds for sandstone acidizing ammonium hydrogen fluoride (AHF), ammonium fluotitanate (AFT), and ammonium fluoroborate system (AFB). Chemical structures, acidity test and solubility tests have proved the feasibility. Then, performance comparisons are conducted to prove the advantages over mud acid system.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

628-633

Citation:

Online since:

September 2013

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Henry A. Ohen, Faruk Civan. Simulation of Formation Damage in Petroleum Reservoirs,. SPE 19420, (1990).

Google Scholar

[2] Ricardo Aboud, Kern Smith, and Leandro Forero.: Effective Matrix Acidizing in High Temperature Environments,. SPE 109818, (2007).

DOI: 10.2118/109818-ms

Google Scholar

[3] Thomas, R.L. and Crowe, C.W.: Matrix Treatment Employs New Acid System for Stimulation and Control of Fines Migration in Sandstone Formation, paper SPE 7566, (1978).

DOI: 10.2118/7566-pa

Google Scholar

[4] Gdanski, R.D.: AlCl3 Retarded HF Acid for More Effective Stimulation, OGJ, (October 1985) 111-115.

Google Scholar

[5] Lullo, D.G.: A New Acid for True Stimulation of Sandstone Reservoirs, SPE 37015, (1996).

Google Scholar

[6] Nicholas Kume, Robert Van Melsen and Luckie Erhahon.: New HF Acid System Improves Sandstone Matrix Acidizing Success Ratio By 400% Over Conventional Mud Acid System in Niger Delta Basin,. SPE 56527, (1999).

DOI: 10.2118/56527-ms

Google Scholar

[7] Frenier, W.W., Growcock, F.B., Mechanisms of Corrosion Inhibitors Used in Acidizing Wells, SPE Production Engineering, 1988, 3(4).

DOI: 10.2118/14092-pa

Google Scholar

[8] T. Kumar, S. Vishwanatham and Emranuzzaman,: Nitrogen Containing Organic Compounds as Corrosion Inhibitors of Mild Steel Corrosion in Oilfield Acids, SPE 39534, (1998).

DOI: 10.2118/39534-ms

Google Scholar

[9] Cheung, S.K., Van Arsdale: Matrix Acid Stimulation Studies Yield New Results With a Multiple Long-Core Permeameter,. SPE 19737, (1992).

DOI: 10.2118/19737-pa

Google Scholar