Study on the Mechanism of SCR NO by Mn-Ce/CNTs Catalyst at Low-Temperature

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The prepared Mn-Ce/CNTs catalyst was tested with Temperature-Programmed Desorption (TPD) in this experiment. The adsorption – desorption of NO, NH3, O2 on the surface of catalyst were studied and the mechanism of SCR was analyzed. The conclusions were as follows: NH3was easily absorbed on the surface of Mn-Ce/CNTs catalyst for its significant competitive advantage; it can restrain the absorption of NO. The adsorption performance of NH3 on catalyst surface was far greater than NO. When NO, O2 adsorbed on the catalyst at the same time, the desorption amount of NO from catalyst significantly was less than the NO absorbed only. This shows that the O2 can promote the adsorption of NO on the catalyst in SCR system.

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645-648

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September 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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[1] De Jong K.P., Geus J.W. Carbon nanofibers: catalytic synthesis and applications. Catalysis Reviews, 2001, 42(4): 481~510.

DOI: 10.1081/cr-100101954

Google Scholar

[2] Serp P., Corrias M., Kalck P. Carbon nanotubes and nanofibers in catalysis. Applied Catalysis A: General, 2003, 253(2): 337-358.

DOI: 10.1016/s0926-860x(03)00549-0

Google Scholar

[3] Wildgoose G.G., Banks C.E., Compton R.G. Metal nanoparticles and related materials supported on carbon nanotubes: methods and applications. Small, 2006, 2(2): 182-193.

DOI: 10.1002/smll.200500324

Google Scholar

[4] Planeix J.M., Coustel N., Coq B., et al. Application of carbon nanotubes as supports in heterogeneous catalysis. Journal of the American Chemical Society, 1994, 116(17): 7935-7936.

DOI: 10.1021/ja00096a076

Google Scholar

[5] Pan X., Fan Z., Chen W., et al. Enhanced ethanol production inside carbon-nanotube reactors containing catalytic particles. Nature Materials, 2007, 6(7): 507-511.

DOI: 10.1038/nmat1916

Google Scholar

[6] Zhu Z.P., Liu Z.Y., Niu H.X., et al. Mechanism of SO2romotion for NO reduction with NH3overactivated carbon-supported vanadium oxide catalyst. Journal of Catalysis, 2001, 197(1): 6-16.

Google Scholar

[7] De Jong K.P., GeusJ.W. Carbon nanofibers: catalytic synthesis and applications. Catalysis Reviews, 2001, 42(4): 481-510.

Google Scholar

[8] Serp P., Corrias M., Kalck P. Carbon nanotubes and nanofibers in catalysis. Applied Catalysis A: General, 2003, 53(2): 337-358.

DOI: 10.1016/s0926-860x(03)00549-0

Google Scholar