Characterization P-Ca3Co4O9 and N-CaMnO3

Article Preview

Abstract:

We present characterization and thermoelectric properties of oxide thermoelectric materials of P-Ca3Co4O9 and N-CaMnO3 synthesized by solid state reaction method and sintering in air. The crystalline structure was measured by x-ray diffraction (XRD) and confirmed by transmission electron microscope (TEM). The powder size and gran size of P-Ca3Co4O9 and N-CaMnO3 were observed by scanning electron microscope (SEM). The electrical resistivity and Seebeck coefficient are measured. It was found that, the P-Ca3Co4O9shows the point symmetry groups in three dimensions require of monoclinic system and N-CaMnO3 shows cubic system corresponding with TEM results. The powder size and grain size were obtained mean values of 1-3 µm. The electrical resistivity and Seebeck coefficient were obtained for P-Ca3Co4O9and for N-CaMnO3 at 360 K.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

209-212

Citation:

Online since:

September 2013

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] J. Yu andH.Zhao, "A numerical model for thermoelectric generator with the parallel-plate heat exchanger," J. Pow. Sour. vol. 172, p.428, 2007.

DOI: 10.1016/j.jpowsour.2007.07.045

Google Scholar

[2] D.M. Rowe, CRC Handbook of Thermoelectrics, CRC Press, 1995.

Google Scholar

[3] A. Yadav, K.P. Pipe and M. Shtein, "Fiber-based fleexible thermoelectric power generator," J. Pow. Sour. vol. 175, p.909, 2008.

DOI: 10.1016/j.jpowsour.2007.09.096

Google Scholar

[4] C.L. Chen, Y.Y. Chen, S.J. Lin, J. C. Ho, P.C. Lee, C.D. Chen and S. R. Harutyunyan, "Fabrication and Characterization of Electrodeposited Bismuth Telluride Films and Nanowires," J. Phys. Chem. C., vol. 114, p.338, 2010.

DOI: 10.1021/jp909926z

Google Scholar

[5] M. Ohtaki, "Oxide Thermoelectric Materials for Heat-to-Electricity," Kyushu University G-COE program (NOVEL CARBON RESOURCE SCIENCES) Newsletter, vol. 3, Special Issue, 2010.

Google Scholar

[6] F. Delorme, D. Ovono Ovono, P. Marudhaclam, C. Fernandez Martin, O. Fraboulet, "Effect of precursors size on the thermoelectric properties of Ca3Co4O9 ceramics," Material Research Bulletin., vol 47, pp.1169-1175, 2012.

DOI: 10.1016/j.materresbull.2012.02.004

Google Scholar

[7] M. Otaki, H. Koga, T. Tokunaka, K. Uguchi and H. Ari, "Electrical Transport Prpperties ad High Temperature Thermoelectric Performanceof(Ca0.9M0.1)MnO3(M=Y,La,Ce,Sm,In,Sn,Sb,Pb,Bi)," J. Solid State Chemistry., vol. 120, pp.105-111, 1995.

DOI: 10.1006/jssc.1995.1384

Google Scholar

[8] P. H. Xiang, Y. Kinemuchi, H. Kaga and K. Watari, "Fabrication and thermoelectric properties of Ca3Co4O9/Ag composites," J. Alloys and Compod., vol.454, pp.364-369, 2008.

DOI: 10.1016/j.jallcom.2006.12.102

Google Scholar

[9] G. Xu, R. Funahashi, Q. Pu, B. Liu, R. Tao, G. Wang and Z. Ding, "High-temperature transport properties of Nb and Ta substituted CaMnO3 system," Solid State Ionics., vol.171, pp.147-151,2004.

DOI: 10.1016/s0167-2738(03)00108-5

Google Scholar