Characterization and Synthesis of Additive Coated BaTiO3 Nano-Powder

Article Preview

Abstract:

Two different BaTiO3 (160nm) nanopowders coated with Y and with Dy were fabricated by an aqueous chemical coating method, and their dielectric properties and microstructures were investigated with X-ray diffraction, Impedance analyzer, SEM and TEM. Y and Dy were coated on the BaTiO3 powder using nitrates. Coated BaTiO3 powders were pressed in a disk shape and sintered at 1150~1200°C for 2 hours in reduced atmosphere of 10%H2 - 90%N2. Coating layer of the BaTiO3 particle was thin with a thickness of 3 ~ 5nm. Coated BaTiO3 sintered sample exhibited a larger lattice parameter (a, c) and smaller tetragonality (c/a) than pure BaTiO3 one. Y coated BaTiO3 sample sintered at 1200°C showed good dielectric properties with a high dielectric constant of around 2000 and a stable temperature coefficient of capacitance (TCC).

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 881-883)

Pages:

964-967

Citation:

Online since:

January 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Y. Tsur, T. D. Dunbar, and C. A. Randall: J. Electroceram. Vol. 7 (2001), p.25.

Google Scholar

[2] G. V. Lewis, and C. R. A: J. Phys. Chem. Sol. Vol. 47 (1986), p.89.

Google Scholar

[3] R. D. Shannon: Acta Crystallogr. A32 (1976), p.751.

Google Scholar

[4] D. Makovec, Z. Smardzija, and M. Drofenik: J. Am. Ceram. Soc. Vol. 87 (2004), p.1324.

Google Scholar

[5] K. J. Park, C. H. Kim, Y. J. Yoon, S. M. Song, Y. T. Kim, and K. H. Hur: J. Eur. Ceram. Soc. Vol. 29 (2009), p.1735.

Google Scholar

[6] Lee J. K., Hong K. S. and Jang J. W. J. Am. Ceram. Soc. 84, 2001 (2006).

Google Scholar

[7] Lu H. Y. and Lin M. H: Ceram. Int. Vol. 31 (2005), p.989.

Google Scholar

[8] X.R. Cheng, M.R. Shen: Mater. Res. Bull. Vol. 42 (2007), p.1662.

Google Scholar