Synthesis and Characterization of an Experimental Light-Curing Dental Resinous Monomer

Article Preview

Abstract:

2-((phenylcarbamoyl) oxy) ethyl acrylate (Monomer 1) was synthesized based on the raw materials of N-Z-ethanolamine (NSC), acryloyl chloride (AOC), triethylamine (TEA) and dichloromethane (DCM). The chemical structure of Monomer 1 was characterized and confirmed by FTIR and 1H NMR, and the light-curing polymerization behavior was also investigated. Results showed that Monomer 1 had prospective chemical structure. Compared to commercial monomer TEGDMA, Monomer 1 had better reaction speed and conversion rate.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

337-340

Citation:

Online since:

February 2014

Authors:

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Y Xia, FM Zhang, HF Xie, et al. Nanoparticle-reinforced resin-based dental composites. J Dent, 36 (2008) 450-455.

DOI: 10.1016/j.jdent.2008.03.001

Google Scholar

[2] M Atai, M Nekoomanesh, SA Hashemi, et al. Physical and mechanical properties of an experimental dental composite based on a new monomer. Dent Mater, 20 (2004) 663-668.

DOI: 10.1016/j.dental.2003.08.008

Google Scholar

[3] NB Cramer, CP O'Brien, CN Bowman. Mechanisms, polymerization rate scaling, and oxygen inhibition with an ultra-rapid monovinyl urethane acrylate. Polymer, 49 (2008) 4756-4761.

DOI: 10.1016/j.polymer.2008.08.051

Google Scholar

[4] ER Beckel, J Nie, JW Stansbury, Effect of aryl substituents on the reactivity of phenyl carbamate acrylate monomers. Macromolecules, 37 (2004) 4062-4069.

DOI: 10.1021/ma030536f

Google Scholar

[5] NB Cramer, JW Stansbury, C.N. Bowman. Recent advances and developments in composite dental restorative materials. J Dent Res, 90(2011) 402-416.

DOI: 10.1177/0022034510381263

Google Scholar

[6] C Decker, K Moussa. Photopolymerization of Multi-Functional Monomers. V. Polyurethane-Acrylate Resins. Eur Polym J, 27(1991) 881-889.

Google Scholar

[7] B Lu, P Xiao, MZ Sun, et al. Reducing volume shrinkage by low-temperature photopolymerization. J. Appl Polym Sci, 104 (2007) 1126-1130.

DOI: 10.1002/app.25758

Google Scholar