Incorporation of Pd Nanoparticles on Rod and Necklace-Like SBA-15 Supports Materials

Abstract:

Ion-exchange of palladium (Pd) precursor for two different types of well-ordered SBA-15 morphologies, necklace-like and rod-like, was studied. Approximately 3.8 wt% Pd was successfully incorporated into SBA-15 at pH 10.3. Formation of SBA-15 and Pd/SBA-15 were characterized by Scanning Electron Microscope (SEM), Transmission Electron Microscope (TEM), Thermogravimetry with Simultaneous Difference Thermal Spectroscopy coupled with mass spectrometer (TG/SDTA-MS), Thermogravimetry in combination with Simultaneous Difference Thermal Spectroscopy (TG-SDTA), Inductive Coupled Plasma Mass Spectrometer (ICP-MS) and N₂ adsorption-desorption. Reduction of surface area and pore volume of support for Pd/SBA-15 samples may indicate the encapsulation of PdO particles within mesoporous channels of SBA-15.

• Periodical: Advanced Materials Research (Volume 917)
• Pages: 10-17
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.917.10
• Online since: June 2014
• Authors: Siew Pei Lee, Anita Ramli*, Muralithran G. Kutty, Sharifah Bee A. Hamid
• Keywords: Ion-Exchange, Mesoporous SBA-15, Necklace-Like, Pd Nanoparticles, Rod-Like

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