Synthesis of Allyl-Functionalized Polymers via Selective Reversible Addition-Fragmentation Chain Transfer (RAFT) Polymerization

Zhan Jun Liu; Ming Fei Zhao; Zhen Gang Wu; Gang Han

doi:10.4028/www.scientific.net/AMR.924.65

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HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 924Synthesis of Allyl-Functionalized Polymers via...

Synthesis of Allyl-Functionalized Polymers via Selective Reversible Addition-Fragmentation Chain Transfer (RAFT) Polymerization

Abstract:

Allyl-functionalized copolymers with well-defined structure have been successfully prepared via selective reversible addition-fragmentation chain transfer (RAFT) copolymerization of styrene and allyl methacrylate possessing a higher reactive methacrylate and a lower reactive allyl. By employing a fast RAFT equilibrium, the polymerization for AMA completely occurred in methacrylate double bonds, whereas allyl double bonds remained intact and were introduced into the side-chains. GPC and ¹H NMR analyses have confirmed the high chain-end functionality of the resultant copolymer.

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Periodical:

Advanced Materials Research (Volume 924)

Pages:

65-68

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.924.65

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Online since:

April 2014

Authors:

Zhan Jun Liu*, Ming Fei Zhao, Zhen Gang Wu, Gang Han

Keywords:

Allyl Methacrylate, Random Copolymerization, Reversible Addition-Fragmentation Chain Transfer (RAFT), Styrene

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* - Corresponding Author

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