Synthesis of New Bio-Based Thermoset Resin from Palm Oil

Article Preview

Abstract:

New bio-based thermosetting resin was synthesized from palm oil. In this study the epoxy groups presented on the epoxidized palm oil (EPO) were first acrylated and then further maleinized. The acrylation reaction was done by introducing acrylic acid into epoxy group of the epoxidized palm oil. Hydroquinone and triethylamine were used as inhibitor and catalyst, respectively. This reaction was confirmed by Fourier Transform Infrared Spectroscopy (FTIR). To render acid groups on the resulting monomer, the acrylated epoxidized palm oil (AEPO) was further reacted with maleic anhydride. The resulting maleinated acrylated epoxidized palm oil (MAEPO) was characterized by FTIR and Nuclear Magnetic Resonance Spectroscopy (1H NMR).

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 931-932)

Pages:

78-82

Citation:

Online since:

May 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] D.P. Pfister, R.C. Larock, Green composites from a conjugated linseed oil-based resin and wheat straw, Composites Part A: Applied Science and Manufacturing, 41 (2010) 1279-1288.

DOI: 10.1016/j.compositesa.2010.05.012

Google Scholar

[2] D. Åkesson, M. Skrifvars, P. Walkenström, Preparation of thermoset composites from natural fibres and acrylate modified soybean oil resins, Journal of Applied Polymer Science, 114 (2009) 2502-2508.

DOI: 10.1002/app.30773

Google Scholar

[3] M. Haq, R. Burgueño, A.K. Mohanty, M. Misra, Hybrid bio-based composites from blends of unsaturated polyester and soybean oil reinforced with nanoclay and natural fibers, Composites Science and Technology, 68 (2008) 3344-3351.

DOI: 10.1016/j.compscitech.2008.09.007

Google Scholar

[4] J. Lu, R.P. Wool, Novel thermosetting resins for SMC applications from linseed oil: Synthesis, characterization, and properties, Journal of applied polymer science, 99 (2006) 2481-2488.

DOI: 10.1002/app.22843

Google Scholar

[5] S. Dutta, N. Karak, Synthesis, characterization of poly (urethane amide) resins from Nahar seed oil for surface coating applications, Progress in organic coatings, 53 (2005) 147-152.

DOI: 10.1016/j.porgcoat.2005.02.003

Google Scholar

[6] G.I. Williams, R.P. Wool, Composites from natural fibers and soy oil resins, Applied Composite Materials, 7 (2000) 421-432.

Google Scholar

[7] J. Lu, S. Khot, R.P. Wool, New sheet molding compound resins from soybean oil. I. Synthesis and characterization, Polymer, 46 (2005) 71-80.

DOI: 10.1016/j.polymer.2004.10.060

Google Scholar